X-ray Spectroscopic Verification of the Active Species in Iron-Catalyzed Cross-Coupling Reactions

X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reac...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 19; no. 47; pp. 15816 - 15821
Main Authors:	Schoch, Roland, Desens, Willi, Werner, Thomas, Bauer, Matthias
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 18.11.2013 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects:	Absorption spectroscopy Activation Activation analysis Catalysis Chemical reactions Chemistry Clusters cross-coupling EXAFS homogeneous catalysis Iron reaction mechanisms X-rays XANES cross-coupling reaction mechanisms iron homogeneous catalysis XANES EXAFS
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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