X-ray Spectroscopic Verification of the Active Species in Iron-Catalyzed Cross-Coupling Reactions

X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reac...

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Bibliographic Details
Published in:Chemistry : a European journal Vol. 19; no. 47; pp. 15816 - 15821
Main Authors: Schoch, Roland, Desens, Willi, Werner, Thomas, Bauer, Matthias
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 18.11.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects:
Absorption spectroscopy
Activation
Activation analysis
Catalysis
Chemical reactions
Chemistry
Clusters
cross-coupling
EXAFS
homogeneous catalysis
Iron
reaction mechanisms
X-rays
XANES
cross-coupling
reaction mechanisms
iron
homogeneous catalysis
XANES
EXAFS
ISSN:0947-6539, 1521-3765, 1521-3765
Online Access:Get full text
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Summary:X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reaction seems to proceed by an FeI/FeIII mechanism (see figure).
Bibliography:ark:/67375/WNG-BJV3TM5G-8
Landesforschungsschwerpunkt Rheinland-Pfalz Nanokat
Carl-Zeiss foundation
ArticleID:CHEM201303340
istex:78F595831E2FB81FF1FC29713B28EA4133FF5F0B
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
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ISSN:0947-6539
1521-3765
1521-3765
DOI:10.1002/chem.201303340