Annulated Radical Cations with a C4E2‐Core (E = P, As, Sb): Stable Pnictogen Analogs of Elusive Aryl Radical Anions of Birch Reduction Reactions

The benzene radical anion (C6H6)●−, possessing a 7π‐electron count, is a crucial intermediate in the Birch reduction and has been extensively studied both experimentally and theoretically. Herein, we report the tricyclic pnictogen radical cations [(ADC)E]2[B], [2‐E][B] (ADC = PhC{N(Dipp)C}2; Dipp = ...

Celý popis

Podrobná bibliografia

Vydané v:	Angewandte Chemie International Edition Ročník 64; číslo 25; s. e202505142 - n/a
Hlavní autori:	Steffenfauseweh, Henric, Vishnevskiy, Yury V., Neumann, Beate, Stammler, Hans‐Georg, Snabilié, Demi D., Bruin, Bas, Ghadwal, Rajendra S.
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Weinheim Wiley Subscription Services, Inc 17.06.2025 John Wiley and Sons Inc
Vydanie:	International ed. in English
Predmet:	Anions Benzene Birch‐reduction Cations Chemical reduction Heavy benzenes Imidazole Pnictogen Radical cation
ISSN:	1433-7851, 1521-3773, 1521-3773
On-line prístup:	Získať plný text
Tagy:	Pridať tag Žiadne tagy, Buďte prvý, kto otaguje tento záznam!