Annulated Radical Cations with a C4E2‐Core (E = P, As, Sb): Stable Pnictogen Analogs of Elusive Aryl Radical Anions of Birch Reduction Reactions

The benzene radical anion (C6H6)●−, possessing a 7π‐electron count, is a crucial intermediate in the Birch reduction and has been extensively studied both experimentally and theoretically. Herein, we report the tricyclic pnictogen radical cations [(ADC)E]2[B], [2‐E][B] (ADC = PhC{N(Dipp)C}2; Dipp = ...

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Bibliographic Details

Published in:	Angewandte Chemie International Edition Vol. 64; no. 25; pp. e202505142 - n/a
Main Authors:	Steffenfauseweh, Henric, Vishnevskiy, Yury V., Neumann, Beate, Stammler, Hans‐Georg, Snabilié, Demi D., Bruin, Bas, Ghadwal, Rajendra S.
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 17.06.2025 John Wiley and Sons Inc
Edition:	International ed. in English
Subjects:	Anions Benzene Birch‐reduction Cations Chemical reduction Heavy benzenes Imidazole Pnictogen Radical cation
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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