High-Resolution Single-Turnover Mapping Reveals Intraparticle Diffusion Limitation in Ti-MCM-41-Catalyzed Epoxidation
Katalyse in neuem Licht: Mithilfe hochauflösender Fluoreszenzmikroskopie gelang es erstmals, Transportphänomene und deren Rolle in der Katalyse auf Einzelpartikelebene zu kartieren. Der Thiele‐Modul konnte partikelweise in nur einem einzigen Experiment gemessen werden, und er beweist das Vorliegen v...
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| Published in: | Angewandte Chemie Vol. 122; no. 5; pp. 920 - 923 |
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| Main Authors: | , , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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Weinheim
WILEY-VCH Verlag
25.01.2010
WILEY‐VCH Verlag |
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| ISSN: | 0044-8249, 1521-3757 |
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| Abstract | Katalyse in neuem Licht: Mithilfe hochauflösender Fluoreszenzmikroskopie gelang es erstmals, Transportphänomene und deren Rolle in der Katalyse auf Einzelpartikelebene zu kartieren. Der Thiele‐Modul konnte partikelweise in nur einem einzigen Experiment gemessen werden, und er beweist das Vorliegen von Diffusionsbeschränkungen bei der Ti‐MCM‐41‐katalysierten Epoxidierung eines fluoreszierenden Reportermoleküls (siehe Bild; TBHP=tert‐Butylhydroperoxid). |
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| AbstractList | Katalyse in neuem Licht: Mithilfe hochauflösender Fluoreszenzmikroskopie gelang es erstmals, Transportphänomene und deren Rolle in der Katalyse auf Einzelpartikelebene zu kartieren. Der Thiele‐Modul konnte partikelweise in nur einem einzigen Experiment gemessen werden, und er beweist das Vorliegen von Diffusionsbeschränkungen bei der Ti‐MCM‐41‐katalysierten Epoxidierung eines fluoreszierenden Reportermoleküls (siehe Bild; TBHP=tert‐Butylhydroperoxid). |
| Author | Roeffaers, Maarten B. J. Sels, Bert F. Bartholomeeusen, Evelyne Lin, Kaifeng Hofkens, Johan Pescarmona, Paolo P. Dedecker, Peter De Cremer, Gert Jacobs, Pierre A. De Vos, Dirk E. |
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| Copyright | Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | ark:/67375/WNG-JQVZ7GV0-C FWO (Fonds voor Wetenschappelijk Onderzoek) G.D.C., P.D., and M.B.J.R. thank the FWO (Fonds voor Wetenschappelijk Onderzoek) for two doctoral fellowships and a postdoctoral fellowship, respectively. This work was performed within the framework of the IAP-VI program "Supramolecular Chemistry and Catalysis" of the Belgian Federal government and of GOA-2/01. We also gratefully acknowledge financial support from a long-term structural funding "Methusalem" by the Flemish government and from K.U. Leuven in the framework of the Centre of Excellence CECAT. istex:B3C0295A572AA22D26B13B0145112A46D07876F9 ArticleID:ANGE200905039 G.D.C., P.D., and M.B.J.R. thank the FWO (Fonds voor Wetenschappelijk Onderzoek) for two doctoral fellowships and a postdoctoral fellowship, respectively. This work was performed within the framework of the IAP‐VI program “Supramolecular Chemistry and Catalysis” of the Belgian Federal government and of GOA‐2/01. We also gratefully acknowledge financial support from a long‐term structural funding “Methusalem” by the Flemish government and from K.U. Leuven in the framework of the Centre of Excellence CECAT. |
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| PublicationDate | 2010-01-25 January 25, 2010 |
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| Publisher | WILEY-VCH Verlag WILEY‐VCH Verlag |
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| SubjectTerms | Diffusion Einzelmoleküluntersuchungen Epoxidierungen Fluoreszenzsonden Heterogene Katalyse |
| Title | High-Resolution Single-Turnover Mapping Reveals Intraparticle Diffusion Limitation in Ti-MCM-41-Catalyzed Epoxidation |
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