Metal-Oxide-Based Nucleation Process under Confined Conditions: Two Mixed-Valence V6-Type Aggregates Closing the W48 Wheel-Type Cluster Cavities

Getting together helps: The wheel‐shaped {P8W48} polyoxotungstate (see picture) provides a reaction chamber for the directed assembly of two unprecedented mixed‐valence vanadium oxide cavity‐capping groups based on linked octahedra and tetrahedra with VIV and VV centers, respectively. The magnetic a...

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Published in:Angewandte Chemie International Edition Vol. 46; no. 24; pp. 4477 - 4480
Main Authors: Müller, Achim, Pope, Michael T., Todea, Ana Maria, Bögge, Hartmut, van Slageren, Joris, Dressel, Martin, Gouzerh, Pierre, Thouvenot, René, Tsukerblat, Boris, Bell, Aidan
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 2007
WILEY‐VCH Verlag
Subjects:
confined geometries
directed‒assembly
electronic structure
mixed‒valent compounds
polyoxometalates
ISSN:1433-7851, 1521-3773
Online Access:Get full text
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Summary:Getting together helps: The wheel‐shaped {P8W48} polyoxotungstate (see picture) provides a reaction chamber for the directed assembly of two unprecedented mixed‐valence vanadium oxide cavity‐capping groups based on linked octahedra and tetrahedra with VIV and VV centers, respectively. The magnetic and electronic properties are controlled by the confined conditions.
Bibliography:istex:0C8942EE4BBC9EA01E1131F25BAE956E3833B564
German-Israeli Foundation
Volkswagenstiftung
Deutsche Forschungsgemeinschaft
European Union - No. MRTN-CT-2003-504880
Fonds der Chemischen Industrie
Petroleum Research Fund
A.M., J.S., and M.D. gratefully acknowledge the financial support of the Deutsche Forschungsgemeinschaft. A.M. further acknowledges the financial support of the Fonds der Chemischen Industrie, the Volkswagenstiftung, and the European Union (together with A.B.) (MRTN-CT-2003-504880). A.M. and B.T. gratefully acknowledge the financial support of the German-Israeli Foundation for Scientific Research and Development (GIF). M.T.P. acknowledges support from the Alexander von Humboldt Foundation and the Petroleum Research Fund administered by the American Chemical Society.
ark:/67375/WNG-D1KPB07T-8
Alexander von Humboldt Foundation
ArticleID:ANIE200700441
A.M., J.S., and M.D. gratefully acknowledge the financial support of the Deutsche Forschungsgemeinschaft. A.M. further acknowledges the financial support of the Fonds der Chemischen Industrie, the Volkswagenstiftung, and the European Union (together with A.B.) (MRTN‐CT‐2003‐504880). A.M. and B.T. gratefully acknowledge the financial support of the German–Israeli Foundation for Scientific Research and Development (GIF). M.T.P. acknowledges support from the Alexander von Humboldt Foundation and the Petroleum Research Fund administered by the American Chemical Society.
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200700441