Magnetic Anisotropy in Pentacoordinate NiII and CoII Complexes: Unraveling Electronic and Geometrical Contributions

The magnetic properties of the pentacoordinate [MII(Me4cyclam)N3]+ (Me4cyclam=tetramethylcyclam; N3=azido; M=Ni, Co) complexes were investigated. Magnetization and EPR studies indicate that they have an easy plane of magnetization with axial anisotropy parameters D close to 22 and greater than 30 cm...

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Bibliographic Details

Published in:	Chemistry : a European journal Vol. 23; no. 15; pp. 3648 - 3657
Main Authors:	Cahier, Benjamin, Perfetti, Mauro, Zakhia, Georges, Naoufal, Daoud, El‐Khatib, Fatima, Guillot, Régis, Rivière, Eric, Sessoli, Roberta, Barra, Anne‐Laure, Guihéry, Nathalie, Mallah, Talal
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 13.03.2017
Subjects:	ab initio calculations Anisotropy Chemistry cobalt EPR spectroscopy Geometry Magnetic properties nickel
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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