Magnetic Anisotropy in Pentacoordinate NiII and CoII Complexes: Unraveling Electronic and Geometrical Contributions
The magnetic properties of the pentacoordinate [MII(Me4cyclam)N3]+ (Me4cyclam=tetramethylcyclam; N3=azido; M=Ni, Co) complexes were investigated. Magnetization and EPR studies indicate that they have an easy plane of magnetization with axial anisotropy parameters D close to 22 and greater than 30 cm...
Gespeichert in:
| Veröffentlicht in: | Chemistry : a European journal Jg. 23; H. 15; S. 3648 - 3657 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Journal Article |
| Sprache: | Englisch |
| Veröffentlicht: |
Weinheim
Wiley Subscription Services, Inc
13.03.2017
|
| Schlagworte: | |
| ISSN: | 0947-6539, 1521-3765, 1521-3765 |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Abstract | The magnetic properties of the pentacoordinate [MII(Me4cyclam)N3]+ (Me4cyclam=tetramethylcyclam; N3=azido; M=Ni, Co) complexes were investigated. Magnetization and EPR studies indicate that they have an easy plane of magnetization with axial anisotropy parameters D close to 22 and greater than 30 cm−1 for the Ni and Co complexes, respectively. Ab initio calculations reproduced the experimental values of the zero‐field splitting parameters and allowed the orientation of the anisotropy tensor axes with respect to the molecular frame to be determined. For M=Ni, the principal anisotropy axis lies along the Ni−Nazido direction perpendicular to the Ni(Me4cyclam) mean plane, whereas for M=Co it lies in the Co(Me4cyclam) mean plane and thus perpendicular to the Co−Nazido direction. These orientations match one of the possible solutions experimentally provided by single‐crystal cantilever torque magnetometry. To rationalize the geometry and its impact on the orientation of the anisotropy tensor axis, calculations were carried out on model complexes [NiII(NCH)5]2+ and [CoII(NCH)5]2+ by varying the geometry between square pyramidal and trigonal bipyramidal. The geometry of the complexes was found to be the result of a compromise between the electronic configuration of the metal ion and the structure‐orienting effect of the Me4cyclam macrocycle. Moreover, the orientation of the anisotropy axes is mainly dependent on the geometry of the complexes.
Nature and magnitude of the magnetic anisotropy of pentacoordinate NiII and CoII complexes [MII(Me4cyclam)N3]+ were studied by complementary magnetic measurements, high‐field EPR spectroscopy, single‐crystal torque magnetometry studies, and ab initio calculations, which unraveled the synergic effect of the electronic configuration of the metal ion and the structure‐orienting influence of the Me4cyclam tetradentate ligand (see figure). |
|---|---|
| AbstractList | The magnetic properties of the pentacoordinate [MII (Me4 cyclam)N3 ]+ (Me4 cyclam=tetramethylcyclam; N3 =azido; M=Ni, Co) complexes were investigated. Magnetization and EPR studies indicate that they have an easy plane of magnetization with axial anisotropy parameters D close to 22 and greater than 30 cm-1 for the Ni and Co complexes, respectively. Ab initio calculations reproduced the experimental values of the zero-field splitting parameters and allowed the orientation of the anisotropy tensor axes with respect to the molecular frame to be determined. For M=Ni, the principal anisotropy axis lies along the Ni-Nazido direction perpendicular to the Ni(Me4 cyclam) mean plane, whereas for M=Co it lies in the Co(Me4 cyclam) mean plane and thus perpendicular to the Co-Nazido direction. These orientations match one of the possible solutions experimentally provided by single-crystal cantilever torque magnetometry. To rationalize the geometry and its impact on the orientation of the anisotropy tensor axis, calculations were carried out on model complexes [NiII (NCH)5 ]2+ and [CoII (NCH)5 ]2+ by varying the geometry between square pyramidal and trigonal bipyramidal. The geometry of the complexes was found to be the result of a compromise between the electronic configuration of the metal ion and the structure-orienting effect of the Me4 cyclam macrocycle. Moreover, the orientation of the anisotropy axes is mainly dependent on the geometry of the complexes.The magnetic properties of the pentacoordinate [MII (Me4 cyclam)N3 ]+ (Me4 cyclam=tetramethylcyclam; N3 =azido; M=Ni, Co) complexes were investigated. Magnetization and EPR studies indicate that they have an easy plane of magnetization with axial anisotropy parameters D close to 22 and greater than 30 cm-1 for the Ni and Co complexes, respectively. Ab initio calculations reproduced the experimental values of the zero-field splitting parameters and allowed the orientation of the anisotropy tensor axes with respect to the molecular frame to be determined. For M=Ni, the principal anisotropy axis lies along the Ni-Nazido direction perpendicular to the Ni(Me4 cyclam) mean plane, whereas for M=Co it lies in the Co(Me4 cyclam) mean plane and thus perpendicular to the Co-Nazido direction. These orientations match one of the possible solutions experimentally provided by single-crystal cantilever torque magnetometry. To rationalize the geometry and its impact on the orientation of the anisotropy tensor axis, calculations were carried out on model complexes [NiII (NCH)5 ]2+ and [CoII (NCH)5 ]2+ by varying the geometry between square pyramidal and trigonal bipyramidal. The geometry of the complexes was found to be the result of a compromise between the electronic configuration of the metal ion and the structure-orienting effect of the Me4 cyclam macrocycle. Moreover, the orientation of the anisotropy axes is mainly dependent on the geometry of the complexes. The magnetic properties of the pentacoordinate [MII(Me4cyclam)N3]+ (Me4cyclam=tetramethylcyclam; N3=azido; M=Ni, Co) complexes were investigated. Magnetization and EPR studies indicate that they have an easy plane of magnetization with axial anisotropy parameters D close to 22 and greater than 30 cm−1 for the Ni and Co complexes, respectively. Ab initio calculations reproduced the experimental values of the zero‐field splitting parameters and allowed the orientation of the anisotropy tensor axes with respect to the molecular frame to be determined. For M=Ni, the principal anisotropy axis lies along the Ni−Nazido direction perpendicular to the Ni(Me4cyclam) mean plane, whereas for M=Co it lies in the Co(Me4cyclam) mean plane and thus perpendicular to the Co−Nazido direction. These orientations match one of the possible solutions experimentally provided by single‐crystal cantilever torque magnetometry. To rationalize the geometry and its impact on the orientation of the anisotropy tensor axis, calculations were carried out on model complexes [NiII(NCH)5]2+ and [CoII(NCH)5]2+ by varying the geometry between square pyramidal and trigonal bipyramidal. The geometry of the complexes was found to be the result of a compromise between the electronic configuration of the metal ion and the structure‐orienting effect of the Me4cyclam macrocycle. Moreover, the orientation of the anisotropy axes is mainly dependent on the geometry of the complexes. Nature and magnitude of the magnetic anisotropy of pentacoordinate NiII and CoII complexes [MII(Me4cyclam)N3]+ were studied by complementary magnetic measurements, high‐field EPR spectroscopy, single‐crystal torque magnetometry studies, and ab initio calculations, which unraveled the synergic effect of the electronic configuration of the metal ion and the structure‐orienting influence of the Me4cyclam tetradentate ligand (see figure). The magnetic properties of the pentacoordinate [MII(Me4cyclam)N3]+ (Me4cyclam=tetramethylcyclam; N3=azido; M=Ni, Co) complexes were investigated. Magnetization and EPR studies indicate that they have an easy plane of magnetization with axial anisotropy parameters D close to 22 and greater than 30cm-1 for the Ni and Co complexes, respectively. Ab initio calculations reproduced the experimental values of the zero-field splitting parameters and allowed the orientation of the anisotropy tensor axes with respect to the molecular frame to be determined. For M=Ni, the principal anisotropy axis lies along the Ni-Nazido direction perpendicular to the Ni(Me4cyclam) mean plane, whereas for M=Co it lies in the Co(Me4cyclam) mean plane and thus perpendicular to the Co-Nazido direction. These orientations match one of the possible solutions experimentally provided by single-crystal cantilever torque magnetometry. To rationalize the geometry and its impact on the orientation of the anisotropy tensor axis, calculations were carried out on model complexes [NiII(NCH)5]2+ and [CoII(NCH)5]2+ by varying the geometry between square pyramidal and trigonal bipyramidal. The geometry of the complexes was found to be the result of a compromise between the electronic configuration of the metal ion and the structure-orienting effect of the Me4cyclam macrocycle. Moreover, the orientation of the anisotropy axes is mainly dependent on the geometry of the complexes. |
| Author | Sessoli, Roberta Barra, Anne‐Laure Guihéry, Nathalie Perfetti, Mauro Mallah, Talal Naoufal, Daoud Rivière, Eric Cahier, Benjamin Zakhia, Georges El‐Khatib, Fatima Guillot, Régis |
| Author_xml | – sequence: 1 givenname: Benjamin surname: Cahier fullname: Cahier, Benjamin organization: Université Paris Sud 11, Université Paris Saclay – sequence: 2 givenname: Mauro surname: Perfetti fullname: Perfetti, Mauro organization: Universität Stuttgart – sequence: 3 givenname: Georges surname: Zakhia fullname: Zakhia, Georges organization: Université Paris Sud 11, Université Paris Saclay – sequence: 4 givenname: Daoud surname: Naoufal fullname: Naoufal, Daoud organization: Université Libanaise, Faculté des Sciences I – sequence: 5 givenname: Fatima surname: El‐Khatib fullname: El‐Khatib, Fatima organization: Université Paris Sud 11, Université Paris Saclay – sequence: 6 givenname: Régis surname: Guillot fullname: Guillot, Régis organization: Université Paris Sud 11, Université Paris Saclay – sequence: 7 givenname: Eric surname: Rivière fullname: Rivière, Eric organization: Université Paris Sud 11, Université Paris Saclay – sequence: 8 givenname: Roberta surname: Sessoli fullname: Sessoli, Roberta organization: Università degli studi di Firenze & INSTM UdR Firenze – sequence: 9 givenname: Anne‐Laure surname: Barra fullname: Barra, Anne‐Laure email: anne-laure.barra@lncmi.cnrs.fr organization: Université J. Fourier – sequence: 10 givenname: Nathalie surname: Guihéry fullname: Guihéry, Nathalie email: nathalie.guihery@irsamc.ups-tlse.fr organization: Université de Toulouse III – sequence: 11 givenname: Talal orcidid: 0000-0002-9311-3463 surname: Mallah fullname: Mallah, Talal email: talal.mallah@u-psud.fr organization: Université Paris Sud 11, Université Paris Saclay |
| BookMark | eNpdkTFPwzAQhS1UJEphZY7EwpJiO7ETs1VRaSu1wEDnyHEuxVVihzgB-u9xVdSB6d5J33u607tGI2MNIHRH8JRgTB_VBzRTignHcZrQCzQmjJIwSjgboTEWcRJyFokrdO3cHmMseBSNkdvInYFeq2BmtLN9Z9tDoE3wBqaXytqu1Eb2ELzo1SqQpgwy60Vmm7aGH3BPwdZ08gtqbXbBvAblA4wPO5ILsA30nVay9gbjVTH02hp3gy4rWTu4_ZsTtH2ev2fLcP26WGWzdbijQtCwokJJBqJgKqVCiqJKcFKxMmasIhQn0n9ACqEKEpcYZClTxSEt09J7YiZ5NEEPp9y2s58DuD5vtFNQ19KAHVxO0phHPI1J5NH7f-jeDp3x13kq4UlMKEs9JU7Ut67hkLedbmR3yAnOjwXkxwLycwF5tpxvzlv0C2Ywfyk |
| CODEN | CEUJED |
| ContentType | Journal Article |
| Copyright | 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| Copyright_xml | – notice: 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim – notice: 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim – notice: 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| DBID | 7SR 8BQ 8FD JG9 K9. 7X8 |
| DOI | 10.1002/chem.201604872 |
| DatabaseName | Engineered Materials Abstracts METADEX Technology Research Database Materials Research Database ProQuest Health & Medical Complete (Alumni) MEDLINE - Academic |
| DatabaseTitle | Materials Research Database ProQuest Health & Medical Complete (Alumni) Engineered Materials Abstracts Technology Research Database METADEX MEDLINE - Academic |
| DatabaseTitleList | MEDLINE - Academic Materials Research Database |
| Database_xml | – sequence: 1 dbid: 7X8 name: MEDLINE - Academic url: https://search.proquest.com/medline sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1521-3765 |
| EndPage | 3657 |
| ExternalDocumentID | 4320496011 CHEM201604872 |
| Genre | article |
| GrantInformation_xml | – fundername: European Research Council funderid: 267746 – fundername: Agence Nationale de la Recherche funderid: ANR-13-BS10-0001-03 |
| GroupedDBID | --- -DZ -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 29B 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5VS 66C 6J9 702 77Q 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AAHQN AAMNL AANLZ AAONW AASGY AAXRX AAYCA AAZKR ABCQN ABCUV ABDBF ABIJN ABJNI ABLJU ABPVW ACAHQ ACCFJ ACCZN ACGFS ACIWK ACNCT ACPOU ACUHS ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN ADZOD AEEZP AEGXH AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFRAH AFWVQ AFZJQ AHBTC AHMBA AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALVPJ AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BY8 CS3 D-E D-F DCZOG DPXWK DR2 DRFUL DRSTM EBD EBS EJD F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HBH HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2W P2X P4D PQQKQ Q.N Q11 QB0 QRW R.K RGC RNS ROL RWI RX1 RYL SUPJJ TN5 TWZ UB1 UPT V2E V8K W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XPP XV2 YZZ ZZTAW ~IA ~WT 7SR 8BQ 8FD AEYWJ AGHNM AGYGG JG9 K9. O8X 7X8 |
| ID | FETCH-LOGICAL-g2992-f29ca5e9b5c829a9bf707f5d455f1207a9631b9cb14d0eada8c6e8d8d5e945a63 |
| IEDL.DBID | DRFUL |
| ISICitedReferencesCount | 55 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000397502900017&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 0947-6539 1521-3765 |
| IngestDate | Thu Oct 02 06:15:27 EDT 2025 Sat Nov 29 14:24:50 EST 2025 Wed Jan 22 16:50:52 EST 2025 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 15 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-g2992-f29ca5e9b5c829a9bf707f5d455f1207a9631b9cb14d0eada8c6e8d8d5e945a63 |
| Notes | These authors contributed equally. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| ORCID | 0000-0002-9311-3463 |
| PQID | 1876741258 |
| PQPubID | 986340 |
| PageCount | 10 |
| ParticipantIDs | proquest_miscellaneous_1846368413 proquest_journals_1876741258 wiley_primary_10_1002_chem_201604872_CHEM201604872 |
| PublicationCentury | 2000 |
| PublicationDate | March 13, 2017 |
| PublicationDateYYYYMMDD | 2017-03-13 |
| PublicationDate_xml | – month: 03 year: 2017 text: March 13, 2017 day: 13 |
| PublicationDecade | 2010 |
| PublicationPlace | Weinheim |
| PublicationPlace_xml | – name: Weinheim |
| PublicationSubtitle | A European Journal |
| PublicationTitle | Chemistry : a European journal |
| PublicationYear | 2017 |
| Publisher | Wiley Subscription Services, Inc |
| Publisher_xml | – name: Wiley Subscription Services, Inc |
| References | 2015; 6 2006; 30 1989; 45 2016; 308 2015; 51 2015; 289 1989; 155 2015; 54 2008; 14 1996; 247 2013; 5 2016; 37 2007; 13 2014; 136 2003; 373 1992; 96 2014; 20 2013; 19 1998; 37 2016; 7 2014; 5 2016; 2 1960; 20 2015; 137 1997; 36 2013; 52 2010; 132 2014; 16 2010; 254 2005 2005; 44 117 2013; 135 1984 2016; 138 2009; 5 2012; 137 2016; 28 2001; 219 2008; 130 1958; 6 2016; 22 2014; 53 1990; 94 |
| References_xml | – volume: 373 start-page: 402 year: 2003 end-page: 410 publication-title: Chem. Phys. Lett. – volume: 5 start-page: 3418 year: 2014 end-page: 3424 publication-title: Chem. Sci. – volume: 16 start-page: 17220 year: 2014 end-page: 17230 publication-title: Phys, Chem. Chem. Phys. – volume: 7 start-page: 4347 year: 2016 end-page: 4354 publication-title: Chem. Sci. – volume: 53 start-page: 4508 year: 2014 end-page: 4516 publication-title: Inorg. Chem. – volume: 130 start-page: 12445 year: 2008 end-page: 12455 publication-title: J. Am. Chem. Soc. – volume: 2 start-page: 31 year: 2016 publication-title: Magnetochemistry – volume: 137 start-page: 12923 year: 2015 end-page: 12928 publication-title: J. Am. Chem. Soc. – volume: 132 start-page: 1224 year: 2010 publication-title: J. Am. Chem. Soc. – volume: 22 start-page: 925 year: 2016 end-page: 933 publication-title: Chem. Eur. J. – volume: 135 start-page: 7010 year: 2013 end-page: 7018 publication-title: J. Am. Chem. Soc. – volume: 19 start-page: 950 year: 2013 end-page: 956 publication-title: Chem. Eur. J. – volume: 7 start-page: 10467 year: 2016 publication-title: Nat. Commun. – start-page: 1349 year: 1984 end-page: 1356 publication-title: J. Chem. Soc. Dalton Trans. – volume: 37 start-page: 6568 year: 1998 end-page: 6582 publication-title: Inorg. Chem. – volume: 289 start-page: 379 year: 2015 end-page: 392 publication-title: Coord. Chem. Rev. – volume: 289 start-page: 177 year: 2015 end-page: 214 publication-title: Coord. Chem. Rev. – volume: 5 start-page: 2977 year: 2009 end-page: 2984 publication-title: J. Chem. Theory Comput. – volume: 45 start-page: 1694 year: 1989 end-page: 1697 publication-title: Acta Crystallogr. Sect. C – volume: 36 start-page: 2816 year: 1997 end-page: 2819 publication-title: Inorg. Chem. – volume: 20 start-page: 14051 year: 2014 end-page: 14056 publication-title: Chem. Eur. J. – volume: 137 start-page: 9792 year: 2015 end-page: 9795 publication-title: J. Am. Chem. Soc. – volume: 6 start-page: 6823 year: 2015 end-page: 6828 publication-title: Chem. Sci. – volume: 132 start-page: 18115 year: 2010 end-page: 18126 publication-title: J. Am. Chem. Soc. – volume: 20 start-page: 321 year: 1960 end-page: 346 publication-title: Nucl. Phys. – volume: 52 start-page: 6880 year: 2013 end-page: 6892 publication-title: Inorg. Chem. – volume: 51 start-page: 3739 year: 2015 end-page: 3742 publication-title: Chem. Commun. – volume: 6 start-page: 329 year: 1958 end-page: 347 publication-title: Nucl. Phys. – volume: 219 start-page: 573 year: 2001 end-page: 604 publication-title: Coord. Chem. Rev. – volume: 137 start-page: 064112 year: 2012 publication-title: J. Chem. Phys. – volume: 254 start-page: 1607 year: 2010 end-page: 1627 publication-title: Coord. Chem. Rev. – volume: 247 start-page: 85 year: 1996 end-page: 91 publication-title: Inorg. Chim. Acta – volume: 51 start-page: 16475 year: 2015 end-page: 16478 publication-title: Chem. Commun. – volume: 94 start-page: 5483 year: 1990 end-page: 5488 publication-title: J. Phys. Chem. – volume: 135 start-page: 3017 year: 2013 end-page: 3026 publication-title: J. Am. Chem. Soc. – volume: 136 start-page: 7623 year: 2014 end-page: 7626 publication-title: J. Am. Chem. Soc. – volume: 308 start-page: 346 year: 2016 end-page: 380 publication-title: Coord. Chem. Rev. – volume: 137 start-page: 1993 year: 2015 end-page: 2005 publication-title: J. Am. Chem. Soc. – volume: 28 start-page: 6946 year: 2016 end-page: 6951 publication-title: Adv. Mater. – volume: 22 start-page: 13705 year: 2016 end-page: 13714 publication-title: Chem. Eur. J. – volume: 5 start-page: 577 year: 2013 end-page: 581 publication-title: Nat. Chem. – volume: 54 start-page: 3090 year: 2015 end-page: 3092 publication-title: Inorg. Chem. – volume: 14 start-page: 1169 year: 2008 end-page: 1177 publication-title: Chem. Eur. J. – volume: 155 start-page: 189 year: 1989 end-page: 194 publication-title: Chem. Phys. Lett. – volume: 138 start-page: 1344 year: 2016 end-page: 1348 publication-title: J. Am. Chem. Soc. – volume: 13 start-page: 2774 year: 2007 end-page: 2782 publication-title: Chem. Eur. J. – volume: 37 start-page: 506 year: 2016 end-page: 541 publication-title: J. Comput. Chem. – volume: 96 start-page: 1218 year: 1992 end-page: 1226 publication-title: J. Chem. Phys. – volume: 30 start-page: 385 year: 2006 end-page: 397 publication-title: Appl. Magn. Reson. – volume: 44 117 start-page: 1876 1910 year: 2005 2005 end-page: 1879 1913 publication-title: Angew. Chem. Int. Ed. Angew. Chem. |
| SSID | ssj0009633 |
| Score | 2.4468162 |
| Snippet | The magnetic properties of the pentacoordinate [MII(Me4cyclam)N3]+ (Me4cyclam=tetramethylcyclam; N3=azido; M=Ni, Co) complexes were investigated. Magnetization... The magnetic properties of the pentacoordinate [MII (Me4 cyclam)N3 ]+ (Me4 cyclam=tetramethylcyclam; N3 =azido; M=Ni, Co) complexes were investigated.... |
| SourceID | proquest wiley |
| SourceType | Aggregation Database Publisher |
| StartPage | 3648 |
| SubjectTerms | ab initio calculations Anisotropy Chemistry cobalt EPR spectroscopy Geometry Magnetic properties nickel |
| Title | Magnetic Anisotropy in Pentacoordinate NiII and CoII Complexes: Unraveling Electronic and Geometrical Contributions |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201604872 https://www.proquest.com/docview/1876741258 https://www.proquest.com/docview/1846368413 |
| Volume | 23 |
| WOSCitedRecordID | wos000397502900017&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVWIB databaseName: Wiley Online Library Full Collection 2020 customDbUrl: eissn: 1521-3765 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0009633 issn: 0947-6539 databaseCode: DRFUL dateStart: 19980101 isFulltext: true titleUrlDefault: https://onlinelibrary.wiley.com providerName: Wiley-Blackwell |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LT-MwEB5BWQkuwL5Eeckr7TUicfOwuaFCAQkqtNpKvUV-BUVinaopCP49M2ka4LrcEsWOEs945nPi-T6A3zxFEJxg9MNkoYNYahcIbqLAoUVsbI3SyjZiE9l4LKZTefeuin_JD9F9cKOZ0cRrmuBK1ydvpKH4TlRJHqXogxkG4Q2Ozpv0YOP8z2hy80a8m7Zy8nEWEA3rirgx5Ccf7_ABYr4Hqk2mGe18_hl3YbtFmexs6RZfYc35b7A5XIm7fYf6Vt17ql9kZ76sq8W8mr2w0rM72kpuKlyRlh5RKBuX19dMecuGFR5Q8Hhwz64-ZRNPukVUy84uOiWdpuWlq_6RTBcanxH31UpRq_4Bk9HF3-FV0OovBPecNqUWXBqVOKkTI7hUUhdZmBWJjZOkiHiYKRzbSEujo9iG6JFKmNQJKyz2iROVDn5Cz1fe7QFDWCW0CVMjDS6RCi0K64qBdk5mDjGY68PhavDzdhLVeSSIaQgRmOjDr-4yDhT901DeVY_UhhjPBKbiPvDGFPlsSdORLwmZeU5GyDsj5EQ10Z3t_0-nA9jilNxpV9_gEHqL-aM7gi_maVHW82NYz6biuHXDVy4Z3_Q |
| linkProvider | Wiley-Blackwell |
| linkToHtml | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1LS8NAEF5EBb34FqtVV_AaTLZ57Hor1WqxFhEL3sK-IgHdSFNF_70zaRr1Kt4SsgnJzuzst5uZ7yPklMUAgiOIfjBZKC8Uynqc6cCzYBETGi2VNJXYRDIa8cdHcVdnE2ItzIwfotlww5FRxWsc4LghffbNGgofhaXkQQxOmEAUXgrBl8DJly7u--PhN_NuXOvJh4mHPKxz5kafnf1-wi-M-ROpVlNNf_0fXnKDrNU4k3ZnjrFJFqzbIiu9ubzbNilv5ZPDCkbadXlZTCfF6yfNHb3DZHJdwJo0d4BD6SgfDKh0hvYKOMDw8Ww_bHlOxw6Vi7CanV42WjpVyytbvKBQF5ifIvvVXFOr3CHj_uVD79qrFRi8J4ZpqRkTWkZWqEhzJqRQWeInWWTCKMoC5icSOjdQQqsgND74pOQ6ttxwA_eEkYw7u2TRFc7uEQrAiivtx1poWCRlimfGZh1lrUgsoDDbIu1576f1MCrTgCPXEGAw3iInzWXoKPyrIZ0t3rANcp5xmIxbhFW2SF9nRB3pjJKZpWiEtDFCimQTzdn-X246JivXD7fDdDgY3RyQVYZTPeb4ddpkcTp5s4dkWb9P83JyVHvjF1aU4vw |
| linkToPdf | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1Lb9NAEB6hFAEX3ohAgUXiatXe-LHLrUobiChRhIjUm7WPcWWprKM4rcq_Z8ZxXHpF3Gx517J3Zme_tWe-D-CTzAkEZxT9aLGwUaotRkq6JEKyiE-9M9b4TmyiWCzU-ble9tmEXAuz44cYPrjxzOjiNU9wXPvq6JY1lF6KS8mTnJywoCh8kLKSzAgOTn7MVme3zLt5ryefFhHzsO6ZG2N5dPcOdzDm30i1W2pmT_7DQz6Fxz3OFMc7x3gG9zA8h4fTvbzbC2i_m4vAFYziONRts90069-iDmLJyeSuoT1pHQiHikU9nwsTvJg2dMDh4xJvsP0sVoGVi7iaXZwOWjpdyy_Y_GKhLjK_YParvaZW-xJWs9Of069Rr8AQXUhOS62kdiZDbTOnpDbaVkVcVJlPs6xKZFwYGtzEameT1Mfkk0a5HJVXnvqkmcknr2AUmoCvQRCwUtbFudOONkmVVZXHamIRdYGEwnAMh_vRL_tp1JaJYq4hwmBqDB-HyzRQ_FfDBGyuuA1znilajMcgO1uU6x1RR7mjZJYlG6EcjFAy2cRw9uZfOn2AB8uTWXk2X3x7C48kr_Sc4jc5hNF2c4Xv4L673tbt5n3vjH8AC8zidw |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Magnetic+Anisotropy+in+Pentacoordinate+NiII+and+CoII+Complexes%3A+Unraveling+Electronic+and+Geometrical+Contributions&rft.jtitle=Chemistry+%3A+a+European+journal&rft.au=Cahier%2C+Benjamin&rft.au=Perfetti%2C+Mauro&rft.au=Zakhia%2C+Georges&rft.au=Naoufal%2C+Daoud&rft.date=2017-03-13&rft.pub=Wiley+Subscription+Services%2C+Inc&rft.issn=0947-6539&rft.eissn=1521-3765&rft.volume=23&rft.issue=15&rft.spage=3648&rft_id=info:doi/10.1002%2Fchem.201604872&rft.externalDBID=NO_FULL_TEXT&rft.externalDocID=4320496011 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0947-6539&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0947-6539&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0947-6539&client=summon |