Defect-Engineered Metal-Organic Frameworks

Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and catalysis, but also in controlling more challenging physical characteristics such as band gap as well as magnetic and electrical...

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Vydáno v:Angewandte Chemie International Edition Ročník 54; číslo 25; s. 7234 - 7254
Hlavní autoři: Fang, Zhenlan, Bueken, Bart, De Vos, Dirk E., Fischer, Roland A.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Weinheim WILEY-VCH Verlag 15.06.2015
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Vydání:International ed. in English
Témata:
Catalysis
Classification
Computer numerical control
coordination chemistry
Crystal defects
Crystal structure
Defects
defects engineering
Electrically conductive
heterogeneity
Metal-organic frameworks
Networks
Physical properties
porous materials
Review
Zeolites
porous materials
coordination chemistry
heterogeneity
defects engineering
metal-organic frameworks
ISSN:1433-7851, 1521-3773, 1521-3773
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Popis
Shrnutí:Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring material properties, which opens up novel opportunities not only in sorption and catalysis, but also in controlling more challenging physical characteristics such as band gap as well as magnetic and electrical/conductive properties. It is challenging to structurally characterize the inherent or intentionally created defects of various types, and there have so far been few efforts to comprehensively discuss these issues. Based on selected reports spanning the last decades, this Review closes that gap by providing both a concise overview of defects in MOFs, or more broadly coordination network compounds (CNCs), including their classification and characterization, together with the (potential) applications of defective CNCs/MOFs. Moreover, we will highlight important aspects of “defect‐engineering” concepts applied for CNCs, also in comparison with relevant solid materials such as zeolites or COFs. Finally, we discuss the future potential of defect‐engineered CNCs. Designer defects: Defects in coordination network compounds (CNCs) are defined as “sites that locally break the regular periodic arrangement of atoms or ions of the static crystalline parent framework due to missing or incorrectly dislocated atoms or ions”. This Review provides both a concise overview of defects in CNCs (including their classification and characterizations) and applications of defective CNCs/MOFs.
Bibliografie:SBO
Funded Access
ArticleID:ANIE201411540
Natural Science Foundation of Jiangsu Province, China - No. BM2012010
ark:/67375/WNG-6GXMSJMZ-P
IAP
National Basic Research Program of China - No. 2015CB932200
National Natural Science Foundation of China - No. 61136003; No. 51173081
KULeuven
istex:2A2F5071F096BDD5399014547601F25FEFC027B7
FWO
These two authors are the main authors of the manuscript and contributed equally in composing it.
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201411540