Improved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference?

The superior capabilities of structured microreactors over batch reactors are demonstrated for reversible addition–fragmentation chain transfer (RAFT) solution polymerization of n‐butyl acrylate with the aid of simulations, explicitly accounting for the chain length distribution of all macrospecies...

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Bibliographic Details
Published in:	Macromolecular rapid communications. Vol. 36; no. 24; pp. 2149 - 2155
Main Authors:	Derboven, Pieter, Van Steenberge, Paul H. M., Vandenbergh, Joke, Reyniers, Marie-Francoise, Junkers, Thomas, D'hooge, Dagmar R., Marin, Guy B.
Format:	Journal Article
Language:	English
Published:	Germany Blackwell Publishing Ltd 01.12.2015 Wiley Subscription Services, Inc
Subjects:	Acrylates Acrylic Resins - chemical synthesis Acrylic Resins - chemistry Acrylics Addition polymerization Batch reactors branching Chain transfer Chemical industry Chemical synthesis Cleavage Dilution Microreactors polymer kinetics Polymerization RAFT Rafts Reactors Reagents reversible addition-fragmentation chain transfer reversible addition–fragmentation chain transfer, RAFT Solution polymerization reversible addition-fragmentation chain transfer, RAFT branching acrylates microreactors polymer kinetics
ISSN:	1022-1336, 1521-3927, 1521-3927
Online Access:	Get full text
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