Transition‐Metal‐Free Cleavage of CO

Tertiary silane 1H, 2‐[(diphenylsilyl)methyl]‐6‐methylpyridine, reacts with tris(pentafluorophenyl)borane (BCF) to form the intramolecular pyridine‐stabilized silylium 1+‐HBCF. The corresponding 2‐[(diphenylsilyl)methyl]pyridine, lacking the methyl‐group on the pyridine ring, forms classic N(py)→B a...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 23; no. 55; pp. 13628 - 13632
Main Authors:	Devillard, Marc, de Bruin, Bas, Siegler, Maxime A., van der Vlugt, J. I.
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 04.10.2017 Wiley Subscription Services, Inc Wiley-VCH Verlag John Wiley and Sons Inc
Subjects:	Aromatic compounds boron Carbon monoxide Chemical bonds Chemical Sciences Chemistry Chemistry, Multidisciplinary Cleavage Communication Communications C−C bond formation Deoxygenation Ductile-brittle transition Fracture mechanics Physical Sciences Pyridines Science & Technology silicon small molecule activation INSERTION SMALL MOLECULES FRUSTRATED LEWIS-PAIR COMPLEXES COORDINATION CO BORANE H BOND ACTIVATION silicon C-C bond formation REDUCTION CARBON-MONOXIDE SI-H small molecule activation boron C−C bond formation
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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