Insight in the activity and diastereoselectivity of various Lewis acid catalysts for the citronellal cyclization

Both experiment and theory predict ATPH as most active and selective Lewis acid catalyst in the citronellal cyclization. [Display omitted] •Combined experimental and theoretical study on citronellal cyclization toward isopulegol stereoisomers.•Lewis acid homogeneous catalysts (ZnBr2 and ATPH) versus...

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Vydáno v:	Journal of catalysis Ročník 305; s. 118 - 129
Hlavní autoři:	Vandichel, Matthias, Vermoortele, Frederik, Cottenie, Stijn, De Vos, Dirk E., Waroquier, Michel, Van Speybroeck, Veronique
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Amsterdam Elsevier Inc 01.09.2013 Elsevier Elsevier BV
Témata:	Acids Activity aluminum ATPH Catalysis Catalysts Chemical kinetics Chemistry citronellal Citronellal cyclization Cu-BTC Diastereoselective catalysis energy Exact sciences and technology General and physical chemistry Heterogeneous catalysis hydrogen Hydrogenation Lewis acids ligands nitrogen dioxide Selectivity stereoisomers temperature Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ZnBr2 Heterogeneous catalysis Citronellal cyclization ATPH Chemical kinetics Lewis acids Diastereoselective catalysis Activity ZnBr2 Selectivity Cu-BTC Lewis acid Citronellal Catalytic reaction Diastereoselectivity ZnBr Cyclization Kinetics Catalyst
ISSN:	0021-9517, 1090-2694
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