X-ray Spectroscopic Verification of the Active Species in Iron-Catalyzed Cross-Coupling Reactions

X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reac...

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Veröffentlicht in:Chemistry : a European journal Jg. 19; H. 47; S. 15816 - 15821
Hauptverfasser: Schoch, Roland, Desens, Willi, Werner, Thomas, Bauer, Matthias
Format: Journal Article
Sprache:Englisch
Veröffentlicht: Weinheim WILEY-VCH Verlag 18.11.2013
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ISSN:0947-6539, 1521-3765, 1521-3765
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Abstract X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reaction seems to proceed by an FeI/FeIII mechanism (see figure).
AbstractList X-ray absorption: The activation of the pre-catalyst as well as the catalytically active species and reaction mechanism of Fe-catalyzed cross-couplings were investigated by X-ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four Fe(I) centers. The reaction seems to proceed by an Fe(I) /Fe(III) mechanism.
X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reaction seems to proceed by an FeI/FeIII mechanism (see figure).
X-ray absorption: The activation of the pre-catalyst as well as the catalytically active species and reaction mechanism of Fe-catalyzed cross-couplings were investigated by X-ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four Fe super(I) centers. The reaction seems to proceed by an Fe super(I)/Fe super(III) mechanism (see figure).
Author Desens, Willi
Bauer, Matthias
Schoch, Roland
Werner, Thomas
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Issue 47
Keywords cross-coupling
reaction mechanisms
iron
homogeneous catalysis
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Snippet X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were...
X-ray absorption: The activation of the pre-catalyst as well as the catalytically active species and reaction mechanism of Fe-catalyzed cross-couplings were...
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StartPage 15816
SubjectTerms Absorption spectroscopy
Activation
Activation analysis
Catalysis
Chemical reactions
Chemistry
Clusters
cross-coupling
EXAFS
homogeneous catalysis
Iron
reaction mechanisms
X-rays
XANES
Title X-ray Spectroscopic Verification of the Active Species in Iron-Catalyzed Cross-Coupling Reactions
URI https://api.istex.fr/ark:/67375/WNG-BJV3TM5G-8/fulltext.pdf
https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201303340
https://www.ncbi.nlm.nih.gov/pubmed/24150913
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Volume 19
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