X-ray Spectroscopic Verification of the Active Species in Iron-Catalyzed Cross-Coupling Reactions
X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reac...
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| Veröffentlicht in: | Chemistry : a European journal Jg. 19; H. 47; S. 15816 - 15821 |
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Weinheim
WILEY-VCH Verlag
18.11.2013
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| Abstract | X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reaction seems to proceed by an FeI/FeIII mechanism (see figure). |
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| AbstractList | X-ray absorption: The activation of the pre-catalyst as well as the catalytically active species and reaction mechanism of Fe-catalyzed cross-couplings were investigated by X-ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four Fe(I) centers. The reaction seems to proceed by an Fe(I) /Fe(III) mechanism. X‐ray absorption: The activation of the pre‐catalyst as well as the catalytically active species and reaction mechanism of Fe‐catalyzed cross‐couplings were investigated by X‐ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four FeI centers. The reaction seems to proceed by an FeI/FeIII mechanism (see figure). X-ray absorption: The activation of the pre-catalyst as well as the catalytically active species and reaction mechanism of Fe-catalyzed cross-couplings were investigated by X-ray absorption spectroscopy. The active catalytic components are small iron clusters with three to four Fe super(I) centers. The reaction seems to proceed by an Fe super(I)/Fe super(III) mechanism (see figure). |
| Author | Desens, Willi Bauer, Matthias Schoch, Roland Werner, Thomas |
| Author_xml | – sequence: 1 givenname: Roland surname: Schoch fullname: Schoch, Roland organization: Fachbereich Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-4676 – sequence: 2 givenname: Willi surname: Desens fullname: Desens, Willi organization: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51326 – sequence: 3 givenname: Thomas surname: Werner fullname: Werner, Thomas email: thomas.werner@catalysis.de organization: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock (Germany), Fax: (+49) 381-1281-51326 – sequence: 4 givenname: Matthias surname: Bauer fullname: Bauer, Matthias email: bauer@chemie.uni-kl.de organization: Fachbereich Chemie, TU Kaiserslautern, Erwin-Schrödinger-Str. 54, 67663 Kaiserslautern (Germany), Fax: (+49) 631-205-4676 |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/24150913$$D View this record in MEDLINE/PubMed |
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| SubjectTerms | Absorption spectroscopy Activation Activation analysis Catalysis Chemical reactions Chemistry Clusters cross-coupling EXAFS homogeneous catalysis Iron reaction mechanisms X-rays XANES |
| Title | X-ray Spectroscopic Verification of the Active Species in Iron-Catalyzed Cross-Coupling Reactions |
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