Molecular Cobalt Clusters as Precursors of Distinct Active Species in Electrochemical, Photochemical, and Photoelectrochemical Water Oxidation Reactions in Phosphate Electrolytes

Three cobalt model molecular compounds, Co‐cubane ([Co4(µ3‐O)4(µ‐OAc)4py4]), Co‐trimer ([Co3(μ3‐O)(µ‐OAc)6py3]PF6), and Co‐dimer ([Co2(μ‐OH)2(µ‐OAc)(OAc)2py4]PF6), are investigated as water oxidation reaction (WOR) catalysts, using electrochemical, photochemical, and photoelectrochemical methodologi...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 21; no. 46; pp. 16578 - 16584
Main Authors:	Li, Xiaobo, Clatworthy, Edwin B., Masters, Anthony F., Maschmeyer, Thomas
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 09.11.2015 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects:	Carbon dioxide Catalysis Catalysts Catalytic activity Chemical reactions Chemistry Cobalt Cobalt compounds cobalt oxide Cubane Dimers Electrochemistry Electrolytes Oxidation oxygen evolution Photochemical Photochemicals Precursors Species Trimers water oxidation cobalt electrochemistry water oxidation oxygen evolution cobalt oxide cubane
ISSN:	0947-6539, 1521-3765
Online Access:	Get full text
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