Synthesis of a copper-supported triplet nitrene complex pertinent to copper-catalyzed amination

Terminal copper-nitrenoid complexes have inspired interest in their fundamental bonding structures as well as their putative intermediacy in catalytic nitrene-transfer reactions. Here, we report that aryl azides react with a copper(I) dinitrogen complex bearing a sterically encumbered dipyrrin ligan...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) Jg. 365; H. 6458; S. 1138
Hauptverfasser:	Carsch, Kurtis M, DiMucci, Ida M, Iovan, Diana A, Li, Alex, Zheng, Shao-Liang, Titus, Charles J, Lee, Sang Jun, Irwin, Kent D, Nordlund, Dennis, Lancaster, Kyle M, Betley, Theodore A
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	United States 13.09.2019
ISSN:	1095-9203, 1095-9203
Online-Zugang:	Weitere Angaben
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