NIR‐Emissive Chromium(0), Molybdenum(0), and Tungsten(0) Complexes in the Solid State at Room Temperature

The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl‐mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit du...

Full description

Saved in:

Bibliographic Details
Published in:	Chemistry : a European journal Vol. 27; no. 51; pp. 12959 - 12964
Main Authors:	Boden, Pit, Di Martino‐Fumo, Patrick, Bens, Tobias, Steiger, Sophie, Albold, Uta, Niedner‐Schatteburg, Gereon, Gerhards, Markus, Sarkar, Biprajit
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 09.09.2021 John Wiley and Sons Inc
Subjects:	Atomic energy levels Carbonyl compounds carbonyl ligands Carbonyls Chemistry Chromium Communication Communications Density functional theory Emissions Emissivity Emitters mesoionic carbenes Molybdenum NIR II emitters Room temperature step-scan FTIR spectroscopy Triplet state Tungsten X-ray diffraction mesoionic carbenes X-ray diffraction step-scan FTIR spectroscopy NIR II emitters carbonyl ligands
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Abstract	The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl‐mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit dual emissions in the VIS and in the NIR region. The emissive excited states are assigned to two distinct triplet states by time‐resolved emission and step‐scan FTIR spectroscopy at variable temperature, supported by density functional theory. In particular, the NIR emissive triplet state exhibits unprecedented lifetimes of up to 600±10 ns and quantum yields reaching 1.7 ⋅ 10−4 at room temperature. These are the first examples of Cr(0), Mo(0) and W(0) complexes that emit in the NIR II region. This work presents emissive Cr(0), Mo(0), and W(0) complexes that contain a bidentate pyridyl‐mesoionic carbene ligand and CO coligands. These systems exhibit dual vis and NIR II emissions at room temperature. The emissive excited triplet states were characterized by temperature‐dependent luminescence and step‐san FTIR spectroscopy in combination with density functional theory. The NIR quantum yield increases from Cr(0) over Mo(0) to W(0), reaching a very high value of 1.4 ⋅ 10−3 at room temperature.
AbstractList	The development of NIR emitters based on earth-abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl-mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit dual emissions in the VIS and in the NIR region. The emissive excited states are assigned to two distinct triplet states by time-resolved emission and step-scan FTIR spectroscopy at variable temperature, supported by density functional theory. In particular, the NIR emissive triplet state exhibits unprecedented lifetimes of up to 600±10 ns and quantum yields reaching 1.7 ⋅ 10 at room temperature. These are the first examples of Cr(0), Mo(0) and W(0) complexes that emit in the NIR II region. The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl‐mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit dual emissions in the VIS and in the NIR region. The emissive excited states are assigned to two distinct triplet states by time‐resolved emission and step‐scan FTIR spectroscopy at variable temperature, supported by density functional theory. In particular, the NIR emissive triplet state exhibits unprecedented lifetimes of up to 600±10 ns and quantum yields reaching 1.7 ⋅ 10−4 at room temperature. These are the first examples of Cr(0), Mo(0) and W(0) complexes that emit in the NIR II region. This work presents emissive Cr(0), Mo(0), and W(0) complexes that contain a bidentate pyridyl‐mesoionic carbene ligand and CO coligands. These systems exhibit dual vis and NIR II emissions at room temperature. The emissive excited triplet states were characterized by temperature‐dependent luminescence and step‐san FTIR spectroscopy in combination with density functional theory. The NIR quantum yield increases from Cr(0) over Mo(0) to W(0), reaching a very high value of 1.4 ⋅ 10−3 at room temperature. The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl‐mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit dual emissions in the VIS and in the NIR region. The emissive excited states are assigned to two distinct triplet states by time‐resolved emission and step‐scan FTIR spectroscopy at variable temperature, supported by density functional theory. In particular, the NIR emissive triplet state exhibits unprecedented lifetimes of up to 600±10 ns and quantum yields reaching 1.7 ⋅ 10−4 at room temperature. These are the first examples of Cr(0), Mo(0) and W(0) complexes that emit in the NIR II region. The development of NIR emitters based on earth-abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl-mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit dual emissions in the VIS and in the NIR region. The emissive excited states are assigned to two distinct triplet states by time-resolved emission and step-scan FTIR spectroscopy at variable temperature, supported by density functional theory. In particular, the NIR emissive triplet state exhibits unprecedented lifetimes of up to 600±10 ns and quantum yields reaching 1.7 ⋅ 10-4 at room temperature. These are the first examples of Cr(0), Mo(0) and W(0) complexes that emit in the NIR II region.The development of NIR emitters based on earth-abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl-mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit dual emissions in the VIS and in the NIR region. The emissive excited states are assigned to two distinct triplet states by time-resolved emission and step-scan FTIR spectroscopy at variable temperature, supported by density functional theory. In particular, the NIR emissive triplet state exhibits unprecedented lifetimes of up to 600±10 ns and quantum yields reaching 1.7 ⋅ 10-4 at room temperature. These are the first examples of Cr(0), Mo(0) and W(0) complexes that emit in the NIR II region. The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl complexes with a pyridyl‐mesoionic carbene (MIC) based ligand. A detailed photophysical investigation shows that all the complexes exhibit dual emissions in the VIS and in the NIR region. The emissive excited states are assigned to two distinct triplet states by time‐resolved emission and step‐scan FTIR spectroscopy at variable temperature, supported by density functional theory. In particular, the NIR emissive triplet state exhibits unprecedented lifetimes of up to 600±10 ns and quantum yields reaching 1.7 ⋅ 10 −4 at room temperature. These are the first examples of Cr(0), Mo(0) and W(0) complexes that emit in the NIR II region.
Author	Boden, Pit Bens, Tobias Sarkar, Biprajit Steiger, Sophie Gerhards, Markus Niedner‐Schatteburg, Gereon Albold, Uta Di Martino‐Fumo, Patrick
AuthorAffiliation	3 Institute of Chemistry and Biochemistry Freie Universität Berlin Fabeckstraße 34–36 14195 Berlin Germany 2 Chair of Inorganic Coordination Chemistry Institute of Inorganic Chemistry University of Stuttgart Pfaffenwaldring 55 70569 Stuttgart Germany 1 Department of Chemistry and Research Center Optimas TU Kaiserslautern Erwin-Schrödinger-Straße 52 67663 Kaiserslautern Germany
AuthorAffiliation_xml	– name: 3 Institute of Chemistry and Biochemistry Freie Universität Berlin Fabeckstraße 34–36 14195 Berlin Germany – name: 1 Department of Chemistry and Research Center Optimas TU Kaiserslautern Erwin-Schrödinger-Straße 52 67663 Kaiserslautern Germany – name: 2 Chair of Inorganic Coordination Chemistry Institute of Inorganic Chemistry University of Stuttgart Pfaffenwaldring 55 70569 Stuttgart Germany
Author_xml	– sequence: 1 givenname: Pit surname: Boden fullname: Boden, Pit organization: TU Kaiserslautern – sequence: 2 givenname: Patrick surname: Di Martino‐Fumo fullname: Di Martino‐Fumo, Patrick organization: TU Kaiserslautern – sequence: 3 givenname: Tobias surname: Bens fullname: Bens, Tobias organization: University of Stuttgart – sequence: 4 givenname: Sophie surname: Steiger fullname: Steiger, Sophie organization: TU Kaiserslautern – sequence: 5 givenname: Uta surname: Albold fullname: Albold, Uta organization: Freie Universität Berlin – sequence: 6 givenname: Gereon surname: Niedner‐Schatteburg fullname: Niedner‐Schatteburg, Gereon organization: TU Kaiserslautern – sequence: 7 givenname: Markus surname: Gerhards fullname: Gerhards, Markus organization: TU Kaiserslautern – sequence: 8 givenname: Biprajit orcidid: 0000-0003-4887-7277 surname: Sarkar fullname: Sarkar, Biprajit email: biprajit.sarkar@iac.uni-stuttgart.de organization: University of Stuttgart
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/34237175$$D View this record in MEDLINE/PubMed
BookMark	eNqFkctuEzEYhS3UiqaBLUtkiU2RmODrXDZIaBTaSi1IbVhbnpl_GpcZO9gzhex4hD4jT1JHCQEqIVaW7fP9l3OO0YF1FhB6QcmMEsLe1kvoZ4wwShgj-RM0oZLRhGepPEATUogsSSUvjtBxCLeEkCLl_Ck64oLxjGZygr58PL_6-eN-3psQzB3gculdb8b-hLx-gy9dt64asLurtg1ejPYmDGDjAy5dv-rgOwRsLB6WgK9dZxp8PegBsB7wlXM9XkC_Aq-H0cMzdNjqLsDz3TlFnz_MF-VZcvHp9Lx8f5HUkos8aQumC5o1qc6pqCgF0QgtmwrSVreiIlTQppVtUzGdVXkLMhU1rXgRAVppUfMperetuxqrHpoa7OB1p1be9NqvldNG_f1jzVLduDuVS1oQIWOBk10B776OEAYV7amh67QFNwbFpCQspSllUfrqkfTWjd7G9aIqIzzPSLR8il7-OdF-lF85RMFsK6i9C8FDu5dQojZBq03Qah90BMQjoDbRd-M2G5nu31ixxb6ZDtb_aaLKs_nlb_YBQwq9yQ
CitedBy_id	crossref_primary_10_1021_jacs_3c03832 crossref_primary_10_1002_anie_202422702 crossref_primary_10_1016_j_ccr_2025_216454 crossref_primary_10_1002_chem_202301205 crossref_primary_10_1002_chem_202500365 crossref_primary_10_1039_D5CP00333D crossref_primary_10_1002_ange_202200653 crossref_primary_10_1002_anie_202314475 crossref_primary_10_1002_ejic_202100870 crossref_primary_10_1021_acs_inorgchem_4c05383 crossref_primary_10_1002_adsu_202401059 crossref_primary_10_1002_chem_202400730 crossref_primary_10_1021_jacs_2c04976 crossref_primary_10_1002_chem_202201038 crossref_primary_10_3390_inorganics12020046 crossref_primary_10_1039_D4QI02392G crossref_primary_10_1007_s41061_022_00386_6 crossref_primary_10_1016_j_ccr_2024_215878 crossref_primary_10_1002_ange_202422702 crossref_primary_10_1002_ange_202314475 crossref_primary_10_1002_cctc_202400024 crossref_primary_10_1002_anie_202200653 crossref_primary_10_1002_ceur_202400066 crossref_primary_10_1016_j_measurement_2025_118224 crossref_primary_10_1016_j_dyepig_2023_111087 crossref_primary_10_1002_cptc_202100296 crossref_primary_10_1007_s11696_024_03513_3
Cites_doi	10.1038/s41377-020-0314-z 10.1039/C9CS00573K 10.1002/chem.202000726 10.1016/S0020-1693(01)00308-5 10.1016/j.ccr.2018.11.014 10.1021/ja510973h 10.1021/ic400347r 10.1021/acs.jpca.8b05376 10.1002/chem.201900489 10.1021/acs.inorgchem.9b02591 10.1021/jacs.0c12805 10.1021/ic00229a012 10.1021/acs.inorgchem.8b01806 10.1002/chem.201601060 10.1021/acsomega.8b03668 10.1021/ja00443a083 10.1039/D0DT00192A 10.1021/jacs.8b12397 10.1021/acs.inorgchem.7b00958 10.1038/nature21430 10.1038/s41467-020-15998-z 10.1016/j.mencom.2020.11.009 10.1002/ange.201504894 10.1080/02603599508032711 10.1021/acs.organomet.8b00637 10.1021/jacs.9b07373 10.1002/ejic.201700056 10.1021/jacs.0c02122 10.1002/chem.201405184 10.1016/S0010-8545(02)00047-4 10.1002/ange.201701210 10.1039/C3DT53126K 10.1039/C4TC00410H 10.1039/C7DT02397A 10.1021/jacs.8b08822 10.1002/anie.201504894 10.1021/ic00283a001 10.1016/j.mencom.2019.03.002 10.1039/b924242b 10.1021/cr00080a003 10.1021/ja00378a005 10.1021/acs.inorgchem.0c02537 10.1002/ange.201605571 10.1021/ic300979c 10.1002/chem.201100045 10.1021/acs.chemmater.7b02049 10.1002/cptc.201900083 10.1021/acs.jpcc.0c04126 10.1021/ja00371a048 10.1039/C5DT04770F 10.1016/S0277-5387(00)83914-5 10.1002/chem.201801161 10.1021/acs.inorgchem.6b00869 10.1021/ja00811a008 10.1007/s00604-014-1204-y 10.1021/acs.inorgchem.0c02912 10.1002/anie.201701210 10.1021/acs.inorgchem.8b02551 10.1002/adfm.201807623 10.1002/chem.202004106 10.1039/C6DT04287B 10.1021/ic402702z 10.1039/C8DT02778A 10.1126/science.aav2865 10.1039/C5DT03609G 10.1021/acs.inorgchem.9b00334 10.1002/anie.201605571 10.1038/s41557-020-0430-7 10.1039/C5DT01261A 10.1021/ic970955r 10.1021/acs.chemmater.0c02683 10.1021/ja3039536 10.1039/C9DT01362H 10.1021/jacs.6b11803 10.1002/chem.201705738
ContentType	Journal Article
Copyright	2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH. 2021. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
Copyright_xml	– notice: 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH – notice: 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH. – notice: 2021. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.
DBID	24P AAYXX CITATION NPM 7SR 8BQ 8FD JG9 K9. 7X8 5PM
DOI	10.1002/chem.202102208
DatabaseName	Open Access: Wiley-Blackwell Open Access Journals CrossRef PubMed Engineered Materials Abstracts METADEX Technology Research Database Materials Research Database ProQuest Health & Medical Complete (Alumni) MEDLINE - Academic PubMed Central (Full Participant titles)
DatabaseTitle	CrossRef PubMed Materials Research Database ProQuest Health & Medical Complete (Alumni) Engineered Materials Abstracts Technology Research Database METADEX MEDLINE - Academic
DatabaseTitleList	PubMed Materials Research Database MEDLINE - Academic CrossRef
Database_xml	– sequence: 1 dbid: 24P name: Wiley Online Library Open Access url: https://authorservices.wiley.com/open-science/open-access/browse-journals.html sourceTypes: Publisher – sequence: 2 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 3 dbid: 7X8 name: MEDLINE - Academic url: https://search.proquest.com/medline sourceTypes: Aggregation Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	1521-3765
EndPage	12964
ExternalDocumentID	PMC8519045 34237175 10_1002_chem_202102208 CHEM202102208
Genre	shortCommunication Journal Article
GrantInformation_xml	– fundername: Deutsche Forschungsgemeinschaft funderid: SA 1840/7-1; GE 961/10-01 – fundername: Deutsche Forschungsgemeinschaft grantid: SA 1840/7-1 – fundername: Deutsche Forschungsgemeinschaft grantid: GE 961/10-01 – fundername: ; grantid: SA 1840/7-1; GE 961/10-01
GroupedDBID	--- -DZ -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 24P 29B 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5VS 66C 6J9 702 77Q 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AAHQN AAMNL AANLZ AAONW AAXRX AAYCA AAZKR ABCQN ABCUV ABDBF ABIJN ABJNI ABLJU ABPVW ACAHQ ACCFJ ACCZN ACGFS ACIWK ACNCT ACPOU ACUHS ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN ADZOD AEEZP AEGXH AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFRAH AFWVQ AFZJQ AHBTC AHMBA AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALVPJ AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BY8 CS3 D-E D-F DCZOG DPXWK DR2 DRFUL DRSTM EBD EBS F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HBH HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2W P2X P4D PQQKQ Q.N Q11 QB0 QRW R.K RGC RNS ROL RWI RX1 RYL SUPJJ TN5 TWZ UB1 UPT V2E V8K W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XPP XV2 YZZ ZZTAW ~IA ~WT AAYXX AEYWJ AGHNM AGYGG CITATION O8X NPM 7SR 8BQ 8FD JG9 K9. 7X8 5PM
ID	FETCH-LOGICAL-c5348-f92a917d6a814b11e4d4a5dbe6faf4b0141df5fdb2a7b8fe564c1b39d6a1ba4c3
IEDL.DBID	24P
ISICitedReferencesCount	32
ISICitedReferencesURI	http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000680946900001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
ISSN	0947-6539 1521-3765
IngestDate	Tue Sep 30 16:30:50 EDT 2025 Wed Oct 01 13:19:40 EDT 2025 Tue Oct 07 06:51:54 EDT 2025 Mon Jul 21 05:51:27 EDT 2025 Tue Nov 18 21:49:58 EST 2025 Sat Nov 29 07:11:19 EST 2025 Wed Jan 22 16:27:50 EST 2025
IsDoiOpenAccess	true
IsOpenAccess	true
IsPeerReviewed	true
IsScholarly	true
Issue	51
Keywords	mesoionic carbenes X-ray diffraction step-scan FTIR spectroscopy NIR II emitters carbonyl ligands
Language	English
License	Attribution 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-c5348-f92a917d6a814b11e4d4a5dbe6faf4b0141df5fdb2a7b8fe564c1b39d6a1ba4c3
Notes	In memory of Markus Gerhards. Deceased. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
ORCID	0000-0003-4887-7277
OpenAccessLink	https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.202102208
PMID	34237175
PQID	2570387063
PQPubID	986340
PageCount	6
ParticipantIDs	pubmedcentral_primary_oai_pubmedcentral_nih_gov_8519045 proquest_miscellaneous_2550261612 proquest_journals_2570387063 pubmed_primary_34237175 crossref_primary_10_1002_chem_202102208 crossref_citationtrail_10_1002_chem_202102208 wiley_primary_10_1002_chem_202102208_CHEM202102208
PublicationCentury	2000
PublicationDate	September 9, 2021
PublicationDateYYYYMMDD	2021-09-09
PublicationDate_xml	– month: 09 year: 2021 text: September 9, 2021 day: 09
PublicationDecade	2020
PublicationPlace	Germany
PublicationPlace_xml	– name: Germany – name: Weinheim – name: Hoboken
PublicationSubtitle	A European Journal
PublicationTitle	Chemistry : a European journal
PublicationTitleAlternate	Chemistry
PublicationYear	2021
Publisher	Wiley Subscription Services, Inc John Wiley and Sons Inc
Publisher_xml	– name: Wiley Subscription Services, Inc – name: John Wiley and Sons Inc
References	2018; 122 2002; 230 1983; 2 1974; 96 2017; 46 2019; 58 2020; 59 1982; 104 2020; 12 2020; 124 2020; 11 2011; 17 2018; 47 2019; 363 1987; 87 2012; 134 2014; 2 2015; 137 2015; 44 2013; 52 2020; 9 2019; 25 2020; 49 2015 2015; 54 127 2019; 29 2018; 37 2016; 45 2014; 53 2019; 4 2019; 3 2018; 140 2017; 2017 1995; 17 2020; 142 2010; 39 2017; 29 2020; 32 2017 2017; 56 129 2021; 143 2019; 141 2019; 381 2017; 139 2014; 43 2018; 24 2016; 55 1998; 37 2016 2016; 55 128 2020; 30 1986; 25 1988; 27 2019; 48 2017; 56 2015; 21 2020; 26 1977; 99 2014; 181 2021; 60 2017; 543 2001; 315 2018; 57 2016; 22 e_1_2_2_4_1 e_1_2_2_24_1 e_1_2_2_22_2 e_1_2_2_49_2 e_1_2_2_6_2 e_1_2_2_20_2 e_1_2_2_2_2 e_1_2_2_62_1 e_1_2_2_41_2 e_1_2_2_64_2 e_1_2_2_43_1 e_1_2_2_85_1 e_1_2_2_8_2 e_1_2_2_28_2 e_1_2_2_66_2 e_1_2_2_45_1 e_1_2_2_68_2 e_1_2_2_26_1 e_1_2_2_47_1 e_1_2_2_81_2 e_1_2_2_83_1 e_1_2_2_60_1 e_1_2_2_13_2 e_1_2_2_36_2 e_1_2_2_36_3 e_1_2_2_38_1 e_1_2_2_59_1 e_1_2_2_11_2 e_1_2_2_74_2 e_1_2_2_19_3 e_1_2_2_30_1 e_1_2_2_51_1 e_1_2_2_72_2 e_1_2_2_19_2 e_1_2_2_32_1 e_1_2_2_53_1 e_1_2_2_17_2 e_1_2_2_55_2 e_1_2_2_15_2 e_1_2_2_34_2 e_1_2_2_57_2 e_1_2_2_76_2 e_1_2_2_34_3 e_1_2_2_78_1 e_1_2_2_70_2 e_1_2_2_3_2 e_1_2_2_25_1 e_1_2_2_48_1 e_1_2_2_5_2 e_1_2_2_23_1 e_1_2_2_21_2 e_1_2_2_1_1 e_1_2_2_40_2 e_1_2_2_42_1 e_1_2_2_84_1 e_1_2_2_29_2 e_1_2_2_63_2 e_1_2_2_7_2 e_1_2_2_44_1 e_1_2_2_65_2 e_1_2_2_27_1 e_1_2_2_46_1 e_1_2_2_69_1 e_1_2_2_9_2 e_1_2_2_67_2 e_1_2_2_82_1 e_1_2_2_61_1 e_1_2_2_80_2 e_1_2_2_37_1 e_1_2_2_58_2 e_1_2_2_12_1 e_1_2_2_39_1 e_1_2_2_10_2 e_1_2_2_52_1 e_1_2_2_75_1 e_1_2_2_50_2 e_1_2_2_31_1 e_1_2_2_18_2 e_1_2_2_73_2 e_1_2_2_33_1 e_1_2_2_79_1 e_1_2_2_54_2 e_1_2_2_16_1 e_1_2_2_14_2 e_1_2_2_35_2 e_1_2_2_56_2 e_1_2_2_77_2 e_1_2_2_71_2 37341277 - Chemistry. 2023 Jun 21;:e202301532
References_xml	– volume: 25 start-page: 1354 year: 1986 end-page: 1359 publication-title: Inorg. Chem. – volume: 24 start-page: 5584 year: 2018 end-page: 5590 publication-title: Chem. Eur. J. – volume: 54 127 start-page: 11572 11735 year: 2015 2015 end-page: 11576 11739 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 46 start-page: 1502 year: 2017 end-page: 1509 publication-title: Dalton Trans. – volume: 32 start-page: 10365 year: 2020 end-page: 10382 publication-title: Chem. Mater. – volume: 37 start-page: 2779 year: 1998 end-page: 2785 publication-title: Inorg. Chem. – volume: 140 start-page: 13522 year: 2018 end-page: 13533 publication-title: J. Am. Chem. Soc. – volume: 24 start-page: 10422 year: 2018 end-page: 10433 publication-title: Chem. Eur. J. – volume: 21 start-page: 3628 year: 2015 end-page: 3639 publication-title: Chem. Eur. J. – volume: 26 start-page: 17222 year: 2020 end-page: 17229 publication-title: Chem. Eur. J. – volume: 45 start-page: 5848 year: 2016 end-page: 5859 publication-title: Dalton Trans. – volume: 17 start-page: 5494 year: 2011 end-page: 5498 publication-title: Chem. Eur. J. – volume: 44 start-page: 10304 year: 2015 end-page: 10314 publication-title: Dalton Trans. – volume: 139 start-page: 985 year: 2017 end-page: 992 publication-title: J. Am. Chem. Soc. – volume: 45 start-page: 2218 year: 2016 end-page: 2226 publication-title: Dalton Trans. – volume: 46 start-page: 11008 year: 2017 end-page: 11012 publication-title: Dalton Trans. – volume: 363 start-page: 601 year: 2019 end-page: 606 publication-title: Science – volume: 122 start-page: 7532 year: 2018 end-page: 7539 publication-title: J. Phys. Chem. A – volume: 48 start-page: 9998 year: 2019 end-page: 10010 publication-title: Dalton Trans. – volume: 11 start-page: 2131 year: 2020 publication-title: Nat. Commun. – volume: 2 start-page: 6333 year: 2014 end-page: 6341 publication-title: J. Mater. Chem. C – volume: 104 start-page: 2038 year: 1982 end-page: 2039 publication-title: J. Am. Chem. Soc. – volume: 58 start-page: 5446 year: 2019 end-page: 5456 publication-title: Inorg. Chem. – volume: 96 start-page: 998 year: 1974 end-page: 1003 publication-title: J. Am. Chem. Soc. – volume: 56 129 start-page: 5676 5770 year: 2017 2017 end-page: 5682 5776 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 4 start-page: 4192 year: 2019 end-page: 4205 publication-title: ACS Omega – volume: 59 start-page: 15504 year: 2020 end-page: 15513 publication-title: Inorg. Chem. – volume: 43 start-page: 6021 year: 2014 end-page: 6025 publication-title: Dalton Trans. – volume: 141 start-page: 3576 year: 2019 end-page: 3588 publication-title: J. Am. Chem. Soc. – volume: 57 start-page: 13973 year: 2018 end-page: 13984 publication-title: Inorg. Chem. – volume: 124 start-page: 21036 year: 2020 end-page: 21046 publication-title: J. Phys. Chem. C – volume: 29 year: 2019 publication-title: Adv. Funct. Mater. – volume: 26 start-page: 6993 year: 2020 end-page: 6998 publication-title: Chem. Eur. J. – volume: 142 start-page: 7947 year: 2020 end-page: 7955 publication-title: J. Am. Chem. Soc. – volume: 181 start-page: 1485 year: 2014 end-page: 1495 publication-title: Microchim. Acta – volume: 2 start-page: 279 year: 1983 end-page: 284 publication-title: Polyhedron – volume: 134 start-page: 12354 year: 2012 end-page: 12357 publication-title: J. Am. Chem. Soc. – volume: 52 start-page: 5395 year: 2013 end-page: 5402 publication-title: Inorg. Chem. – volume: 55 start-page: 7912 year: 2016 end-page: 7919 publication-title: Inorg. Chem. – volume: 27 start-page: 1669 year: 1988 end-page: 1670 publication-title: Inorg. Chem. – volume: 9 start-page: 70 year: 2020 publication-title: Light-Sci. Appl. – volume: 381 start-page: 104 year: 2019 end-page: 134 publication-title: Coord. Chem. Rev. – volume: 29 start-page: 128 year: 2019 end-page: 131 publication-title: Mendeleev Commun. – volume: 87 start-page: 711 year: 1987 end-page: 743 publication-title: Chem. Rev. – volume: 47 start-page: 15646 year: 2018 end-page: 15650 publication-title: Dalton Trans. – volume: 143 start-page: 1651 year: 2021 end-page: 1663 publication-title: J. Am. Chem. Soc. – volume: 60 start-page: 3481 year: 2021 end-page: 3491 publication-title: Inorg. Chem. – volume: 3 start-page: 554 year: 2019 end-page: 558 publication-title: ChemPhotoChem – volume: 2017 start-page: 2112 year: 2017 end-page: 2121 publication-title: Eur. J. Inorg. Chem. – volume: 30 start-page: 717 year: 2020 end-page: 718 publication-title: Mendeleev Commun. – volume: 12 start-page: 345 year: 2020 end-page: 352 publication-title: Nat. Chem. – volume: 17 start-page: 319 year: 1995 end-page: 346 publication-title: Comments Inorg. Chem. – volume: 104 start-page: 3804 year: 1982 end-page: 3812 publication-title: J. Am. Chem. Soc. – volume: 55 128 start-page: 11247 11413 year: 2016 2016 end-page: 11250 11417 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 49 start-page: 3155 year: 2020 end-page: 3163 publication-title: Dalton Trans. – volume: 39 start-page: 3695 year: 2010 end-page: 3705 publication-title: Dalton Trans. – volume: 37 start-page: 4619 year: 2018 end-page: 4629 publication-title: Organometallics – volume: 56 start-page: 8996 year: 2017 end-page: 9008 publication-title: Inorg. Chem. – volume: 25 start-page: 6014 year: 2019 end-page: 6025 publication-title: Chem. Eur. J. – volume: 49 start-page: 1057 year: 2020 end-page: 1070 publication-title: Chem. Soc. Rev. – volume: 315 start-page: 44 year: 2001 end-page: 52 publication-title: Inorg. Chim. Acta – volume: 59 start-page: 4215 year: 2020 end-page: 4227 publication-title: Inorg. Chem. – volume: 22 start-page: 9914 year: 2016 end-page: 9918 publication-title: Chem. Eur. J. – volume: 53 start-page: 2083 year: 2014 end-page: 2095 publication-title: Inorg. Chem. – volume: 52 start-page: 2292 year: 2013 end-page: 2305 publication-title: Inorg. Chem. – volume: 29 start-page: 7750 year: 2017 end-page: 7759 publication-title: Chem. Mater. – volume: 230 start-page: 225 year: 2002 end-page: 242 publication-title: Coord. Chem. Rev. – volume: 141 start-page: 14394 year: 2019 end-page: 14402 publication-title: J. Am. Chem. Soc. – volume: 137 start-page: 1198 year: 2015 end-page: 1205 publication-title: J. Am. Chem. Soc. – volume: 57 start-page: 11673 year: 2018 end-page: 11686 publication-title: Inorg. Chem. – volume: 543 start-page: 695 year: 2017 end-page: 699 publication-title: Nature – volume: 99 start-page: 306 year: 1977 end-page: 307 publication-title: J. Am. Chem. Soc. – ident: e_1_2_2_24_1 doi: 10.1038/s41377-020-0314-z – ident: e_1_2_2_2_2 doi: 10.1039/C9CS00573K – ident: e_1_2_2_52_1 doi: 10.1002/chem.202000726 – ident: e_1_2_2_42_1 doi: 10.1016/S0020-1693(01)00308-5 – ident: e_1_2_2_29_2 doi: 10.1016/j.ccr.2018.11.014 – ident: e_1_2_2_31_1 doi: 10.1021/ja510973h – ident: e_1_2_2_57_2 doi: 10.1021/ic400347r – ident: e_1_2_2_64_2 doi: 10.1021/acs.jpca.8b05376 – ident: e_1_2_2_74_2 doi: 10.1002/chem.201900489 – ident: e_1_2_2_62_1 – ident: e_1_2_2_61_1 doi: 10.1021/acs.inorgchem.9b02591 – ident: e_1_2_2_38_1 doi: 10.1021/jacs.0c12805 – ident: e_1_2_2_44_1 doi: 10.1021/ic00229a012 – ident: e_1_2_2_65_2 doi: 10.1021/acs.inorgchem.8b01806 – ident: e_1_2_2_71_2 doi: 10.1002/chem.201601060 – ident: e_1_2_2_77_2 doi: 10.1021/acsomega.8b03668 – ident: e_1_2_2_30_1 doi: 10.1021/ja00443a083 – ident: e_1_2_2_4_1 – ident: e_1_2_2_5_2 doi: 10.1039/D0DT00192A – ident: e_1_2_2_9_2 doi: 10.1021/jacs.8b12397 – ident: e_1_2_2_17_2 doi: 10.1021/acs.inorgchem.7b00958 – ident: e_1_2_2_49_2 doi: 10.1038/nature21430 – ident: e_1_2_2_15_2 doi: 10.1038/s41467-020-15998-z – ident: e_1_2_2_68_2 doi: 10.1016/j.mencom.2020.11.009 – ident: e_1_2_2_19_3 doi: 10.1002/ange.201504894 – ident: e_1_2_2_83_1 doi: 10.1080/02603599508032711 – ident: e_1_2_2_33_1 – ident: e_1_2_2_58_2 doi: 10.1021/acs.organomet.8b00637 – ident: e_1_2_2_37_1 doi: 10.1021/jacs.9b07373 – ident: e_1_2_2_76_2 doi: 10.1002/ejic.201700056 – ident: e_1_2_2_18_2 doi: 10.1021/jacs.0c02122 – ident: e_1_2_2_50_2 doi: 10.1002/chem.201405184 – ident: e_1_2_2_69_1 – ident: e_1_2_2_43_1 doi: 10.1016/S0010-8545(02)00047-4 – ident: e_1_2_2_39_1 – ident: e_1_2_2_36_3 doi: 10.1002/ange.201701210 – ident: e_1_2_2_46_1 doi: 10.1039/C3DT53126K – ident: e_1_2_2_13_2 doi: 10.1039/C4TC00410H – ident: e_1_2_2_45_1 doi: 10.1039/C7DT02397A – ident: e_1_2_2_3_2 doi: 10.1021/jacs.8b08822 – ident: e_1_2_2_1_1 – ident: e_1_2_2_19_2 doi: 10.1002/anie.201504894 – ident: e_1_2_2_47_1 doi: 10.1021/ic00283a001 – ident: e_1_2_2_67_2 doi: 10.1016/j.mencom.2019.03.002 – ident: e_1_2_2_12_1 – ident: e_1_2_2_20_2 doi: 10.1039/b924242b – ident: e_1_2_2_84_1 doi: 10.1021/cr00080a003 – ident: e_1_2_2_27_1 – ident: e_1_2_2_40_2 doi: 10.1021/ja00378a005 – ident: e_1_2_2_78_1 doi: 10.1021/acs.inorgchem.0c02537 – ident: e_1_2_2_79_1 – ident: e_1_2_2_34_3 doi: 10.1002/ange.201605571 – ident: e_1_2_2_11_2 doi: 10.1021/ic300979c – ident: e_1_2_2_56_2 doi: 10.1002/chem.201100045 – ident: e_1_2_2_26_1 doi: 10.1021/acs.chemmater.7b02049 – ident: e_1_2_2_72_2 doi: 10.1002/cptc.201900083 – ident: e_1_2_2_6_2 doi: 10.1021/acs.jpcc.0c04126 – ident: e_1_2_2_48_1 – ident: e_1_2_2_41_2 doi: 10.1021/ja00371a048 – ident: e_1_2_2_73_2 doi: 10.1039/C5DT04770F – ident: e_1_2_2_82_1 doi: 10.1016/S0277-5387(00)83914-5 – ident: e_1_2_2_22_2 doi: 10.1002/chem.201801161 – ident: e_1_2_2_63_2 doi: 10.1021/acs.inorgchem.6b00869 – ident: e_1_2_2_85_1 doi: 10.1021/ja00811a008 – ident: e_1_2_2_28_2 doi: 10.1007/s00604-014-1204-y – ident: e_1_2_2_32_1 doi: 10.1021/acs.inorgchem.0c02912 – ident: e_1_2_2_36_2 doi: 10.1002/anie.201701210 – ident: e_1_2_2_59_1 doi: 10.1021/acs.inorgchem.8b02551 – ident: e_1_2_2_25_1 doi: 10.1002/adfm.201807623 – ident: e_1_2_2_51_1 doi: 10.1002/chem.202004106 – ident: e_1_2_2_53_1 – ident: e_1_2_2_21_2 doi: 10.1039/C6DT04287B – ident: e_1_2_2_54_2 doi: 10.1021/ic402702z – ident: e_1_2_2_60_1 doi: 10.1039/C8DT02778A – ident: e_1_2_2_8_2 doi: 10.1126/science.aav2865 – ident: e_1_2_2_81_2 doi: 10.1039/C5DT03609G – ident: e_1_2_2_75_1 – ident: e_1_2_2_7_2 doi: 10.1021/acs.inorgchem.9b00334 – ident: e_1_2_2_34_2 doi: 10.1002/anie.201605571 – ident: e_1_2_2_10_2 doi: 10.1038/s41557-020-0430-7 – ident: e_1_2_2_80_2 doi: 10.1039/C5DT01261A – ident: e_1_2_2_16_1 – ident: e_1_2_2_23_1 doi: 10.1021/ic970955r – ident: e_1_2_2_14_2 doi: 10.1021/acs.chemmater.0c02683 – ident: e_1_2_2_55_2 doi: 10.1021/ja3039536 – ident: e_1_2_2_66_2 doi: 10.1039/C9DT01362H – ident: e_1_2_2_35_2 doi: 10.1021/jacs.6b11803 – ident: e_1_2_2_70_2 doi: 10.1002/chem.201705738 – reference: 37341277 - Chemistry. 2023 Jun 21;:e202301532
SSID	ssj0009633
Score	2.5085216
Snippet	The development of NIR emitters based on earth‐abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl... The development of NIR emitters based on earth-abundant elements is an important goal in contemporary science. We present here Cr(0), Mo(0), and W(0) carbonyl...
SourceID	pubmedcentral proquest pubmed crossref wiley
SourceType	Open Access Repository Aggregation Database Index Database Enrichment Source Publisher
StartPage	12959
SubjectTerms	Atomic energy levels Carbonyl compounds carbonyl ligands Carbonyls Chemistry Chromium Communication Communications Density functional theory Emissions Emissivity Emitters mesoionic carbenes Molybdenum NIR II emitters Room temperature step-scan FTIR spectroscopy Triplet state Tungsten X-ray diffraction
Title	NIR‐Emissive Chromium(0), Molybdenum(0), and Tungsten(0) Complexes in the Solid State at Room Temperature
URI	https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.202102208 https://www.ncbi.nlm.nih.gov/pubmed/34237175 https://www.proquest.com/docview/2570387063 https://www.proquest.com/docview/2550261612 https://pubmed.ncbi.nlm.nih.gov/PMC8519045
Volume	27
WOSCitedRecordID	wos000680946900001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
journalDatabaseRights	– providerCode: PRVWIB databaseName: Wiley Online Library Full Collection 2020 customDbUrl: eissn: 1521-3765 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0009633 issn: 0947-6539 databaseCode: DRFUL dateStart: 19980101 isFulltext: true titleUrlDefault: https://onlinelibrary.wiley.com providerName: Wiley-Blackwell
link	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1fa9swED9GO9he9v-Pt65oMNgGM41sybIfR9ewQRdKlkLejGRJ1Cx1SpOU7W0fYZ9xn2R3suM2lDHYXoxlnbAlnaTfWaffAbwqqsyHGGEDbmVM-7exTmwW-yqXXukqsVVg1z9Uo1E-nRZHV07xt_wQ_Q83GhlhvqYBrs1i75I0FOtEJ8mDyUKnfbc5T3MK3pCIo0va3awLJi9UTCSsa9rGQbK3WX5zWbqGNa-7TF6FsmEtGt79_1rcgzsdDmXvW8W5Dzdc8wBu7a_Dvz2Er6NP418_fh5gmjzcGbHontar0zeDt-_Y5_nsu7HkRR-SurFsgrMGakyDDxhNMjP3zS1Y3TBEmOzLfFZbFoAt00s2RrTOJg4Re8vo_AiOhweT_Y9xF5khrmQq8tgXiUY7z2Y658Jw7oQVWlrjMq-9MOQ8ar301iRamdw7mYmKm7TAAtxoUaWPYauZN-4pMIsQ1GXcZDkKcauMchYVZSBxIrFG2QjidceUVUdbTtEzZmVLuJyU1IRl34QRvO7lz1rCjj9K7qz7uewG7qKkoH4p7f2mEbzss7GpaR9FN26-IhlJlitiwwietGrRv4oIFdFClhGoDYXpBYjOezOnqU8CrTdi3wIBdgRJUJi_fH1JlBl96tm_FHoOt-k-eMwVO7C1PF-5F3CzuljWi_PdMJDwqqb5Lmx_GA-PD38DJQAgwA
linkProvider	Wiley-Blackwell
linkToHtml	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1bSxwxFD6IFeyLrfbitLaNUGgLHdyZSebyWERRui5it-DbkCsdXGfF3S365k_wN_aX9JzM7NhFpFD6mOSEmSQnyXeSk-8AvC906nyMsF5kREj3t6GMTRo6nQuXSR0b7dn1-9lgkJ-eFsetNyG9hWn4IboDN5oZfr2mCU4H0jt3rKHYKHpK7m0Weu77iONWQ6oe8-M73t20jSbPs5BYWOe8jb14Z7H-4r50D2ze95n8E8v6zWj_yX9oxlNYa5Eo-9Kozjos2XoDVnfnAeCewdng8OTXze0epsnHnRGP7nk1O__Y-_SZHY1H18qQH71PytqwIa4bqDM1ZjBaZkb2yk5YVTPEmOzbeFQZ5qEtk1N2gnidDS1i9obT-Tl8398b7h6EbWyGUIuE56ErYomWnkllHnEVRZYbLoVRNnXScUXuo8YJZ1QsM5U7K1KuI5UUWCFSkuvkBSzX49puAjMIQm0aqTRHochkKrMGVaUncCkxKjMBhPORKXVLXE7xM0ZlQ7kcl9SFZdeFAXzo5C8ayo4HJbfmA122U3dSUli_hG5_kwC2u2LsarpJkbUdz0hGkO2K6DCAl41edJ8iSkW0kUUA2YLGdAJE6L1YUlc_PLE3ot8CIXYAsdeYv_x9SaQZXerVv1R6B6sHw6N-2T8cfH0Njynf-88VW7A8vZzZN7Cif06ryeVbP6t-A35dIiM
linkToPdf	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1bb9MwFD5CHQJeuF_CBhgJCZAWrUnsXB7RtoqJUk2lk_YW-SoiunRaWwRv_IT9xv2SneOkGdWEkBCPto-T2D62vxMffwfgTaFT52OE9SMjQjq_DWVs0tDpXLhM6thoz64_zEaj_Pi4OGy9CekuTMMP0f1wo5nh12ua4PbUuJ0r1lBsFF0l9zYLXffd4BRJpgcbe-PB0fCKeTdt48nzLCQe1hVzYz_eWX_C-s50DW5e95r8Hc367Whw7z805D7cbbEo-9AozwO4YeuHcHt3FQLuEXwbHYwvfp3vY5q83Bkx6Z5Uy5N3_ffb7PNs-lMZ8qT3SVkbNsGVA7WmxgxGC83U_rBzVtUMUSb7MptWhnlwy-SCjRGxs4lF1N6wOj-Go8H-ZPdj2EZnCLVIeB66IpZo65lU5hFXUWS54VIYZVMnHVfkQGqccEbFMlO5syLlOlJJgRUiJblOnkCvntX2GTCDMNSmkUpzFIpMpjJrUFn6AhcTozITQLgamVK31OUUQWNaNqTLcUldWHZdGMDbTv60Ie34o-TWaqDLdvLOSwrsl9D5bxLA664Yu5rOUmRtZ0uSEWS9Ij4M4GmjF92riFQRrWQRQLamMZ0AUXqvl9TVV0_tjfi3QJAdQOw15i9fXxJtRpd6_i-VXsGtw71BOTwYfdqEO5TtHeiKLegtzpb2BdzU3xfV_OxlO60uASLoIzk
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=NIR%E2%80%90Emissive+Chromium%280%29%2C+Molybdenum%280%29%2C+and+Tungsten%280%29+Complexes+in+the+Solid+State+at+Room+Temperature&rft.jtitle=Chemistry+%3A+a+European+journal&rft.au=Boden%2C+Pit&rft.au=Patrick+Di+Martino%E2%80%90Fumo&rft.au=Bens%2C+Tobias&rft.au=Steiger%2C+Sophie&rft.date=2021-09-09&rft.pub=Wiley+Subscription+Services%2C+Inc&rft.issn=0947-6539&rft.eissn=1521-3765&rft.volume=27&rft.issue=51&rft.spage=12959&rft.epage=12964&rft_id=info:doi/10.1002%2Fchem.202102208&rft.externalDBID=NO_FULL_TEXT
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0947-6539&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0947-6539&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0947-6539&client=summon