Direct spectroscopic characterization of a transitory dirhodium donor-acceptor carbene complex

A multitude of organic transformations catalyzed by dirhodium(II) (Rh2) complexes are thought to proceed via the intermediacy of highly reactive, electrophilic carbenoid intermediates that have eluded direct observation. Herein, we report the generation of a metastable Rh2-carbenoid intermediate sup...

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Vydané v:	Science (American Association for the Advancement of Science) Ročník 342; číslo 6156; s. 351
Hlavní autori:	Kornecki, Katherine P, Briones, John F, Boyarskikh, Vyacheslav, Fullilove, Felicia, Autschbach, Jochen, Schrote, Kaitlin E, Lancaster, Kyle M, Davies, Huw M L, Berry, John F
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	United States 18.10.2013
ISSN:	1095-9203, 1095-9203
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