Noble Metals in Polyoxometalates

Polyoxometalates containing noble metal ions, such as ruthenium, osmium, rhodium, palladium, platinum, silver and gold, are a structurally diverse class of compounds. They include both classical heteropolyanions (vanadates, molybdates, tungstates) in which noble metals are present as heteroatoms, as...

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Published in:Angewandte Chemie International Edition Vol. 51; no. 38; pp. 9492 - 9510
Main Authors: Izarova, Natalya V., Pope, Michael T., Kortz, Ulrich
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 17.09.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Edition:International ed. in English
Subjects:
addenda atoms
Catalysis
cluster compounds
Gold
heteropolyanions
Metals
Molybdates
Nanotechnology
Noble metals
Osmium
Palladium
Platinum
polyoxometalates
Rhodium
Ruthenium
Silver
Tungstates
Vanadates
ISSN:1433-7851, 1521-3773, 1521-3773
Online Access:Get full text
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Summary:Polyoxometalates containing noble metal ions, such as ruthenium, osmium, rhodium, palladium, platinum, silver and gold, are a structurally diverse class of compounds. They include both classical heteropolyanions (vanadates, molybdates, tungstates) in which noble metals are present as heteroatoms, as well as the recently discovered class of polyoxometalates with noble metal “addenda” atoms. The focus of this Review is on complexes that should, in principle, exist as discrete molecular species in solution, and which are therefore of interest for their reactivity, their future synthetic utility and potential applications, for example, in catalysis or nanoscience. Polyoxometalates strike it rich: Discrete polyoxometalates containing noble metals (ruthenium, osmium, rhodium, palladium, platinum, silver, and gold, see picture) form a rich class of compounds. It includes both classical heteropolyanions (vanadates, molybdates, tungstates) where noble metals are present as heteroatoms, as well as the recently discovered novel subclass of polyoxometalates constructed of noble‐metal addenda atoms.
Bibliography:Jacobs University
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ark:/67375/WNG-T8ZMFVN7-F
ArticleID:ANIE201202750
Georgetown University
German Science Foundation - No. DFG-IZ-60/1-1; No. DFG-KO-2288/9-1
ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201202750