Noble Metals in Polyoxometalates

Polyoxometalates containing noble metal ions, such as ruthenium, osmium, rhodium, palladium, platinum, silver and gold, are a structurally diverse class of compounds. They include both classical heteropolyanions (vanadates, molybdates, tungstates) in which noble metals are present as heteroatoms, as...

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Vydané v:	Angewandte Chemie International Edition Ročník 51; číslo 38; s. 9492 - 9510
Hlavní autori:	Izarova, Natalya V., Pope, Michael T., Kortz, Ulrich
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Weinheim WILEY-VCH Verlag 17.09.2012 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Vydanie:	International ed. in English
Predmet:	addenda atoms Catalysis cluster compounds Gold heteropolyanions Metals Molybdates Nanotechnology Noble metals Osmium Palladium Platinum polyoxometalates Rhodium Ruthenium Silver Tungstates Vanadates
ISSN:	1433-7851, 1521-3773, 1521-3773
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Popis
Shrnutí:	Polyoxometalates containing noble metal ions, such as ruthenium, osmium, rhodium, palladium, platinum, silver and gold, are a structurally diverse class of compounds. They include both classical heteropolyanions (vanadates, molybdates, tungstates) in which noble metals are present as heteroatoms, as well as the recently discovered class of polyoxometalates with noble metal “addenda” atoms. The focus of this Review is on complexes that should, in principle, exist as discrete molecular species in solution, and which are therefore of interest for their reactivity, their future synthetic utility and potential applications, for example, in catalysis or nanoscience. Polyoxometalates strike it rich: Discrete polyoxometalates containing noble metals (ruthenium, osmium, rhodium, palladium, platinum, silver, and gold, see picture) form a rich class of compounds. It includes both classical heteropolyanions (vanadates, molybdates, tungstates) where noble metals are present as heteroatoms, as well as the recently discovered novel subclass of polyoxometalates constructed of noble‐metal addenda atoms.
Bibliografia:	Jacobs University istex:7F92982AD9188EA8E1E571C8F0BFB9BF4BD1E560 ark:/67375/WNG-T8ZMFVN7-F ArticleID:ANIE201202750 Georgetown University German Science Foundation - No. DFG-IZ-60/1-1; No. DFG-KO-2288/9-1 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
ISSN:	1433-7851 1521-3773 1521-3773
DOI:	10.1002/anie.201202750