A Flexible Photoactive Titanium Metal-Organic Framework Based on a [TiIV3(μ3-O)(O)2(COO)6] Cluster

The synthesis of titanium–carboxylate metal–organic frameworks (MOFs) is hampered by the high reactivity of the commonly employed alkoxide precursors. Herein, we present an innovative approach to titanium‐based MOFs by the use of titanocene dichloride to synthesize COK‐69, the first breathing Ti MOF...

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Bibliographic Details

Published in:	Angewandte Chemie International Edition Vol. 54; no. 47; pp. 13912 - 13917
Main Authors:	Bueken, Bart, Vermoortele, Frederik, Vanpoucke, Danny E. P., Reinsch, Helge, Tsou, Chih-Chin, Valvekens, Pieterjan, De Baerdemaeker, Trees, Ameloot, Rob, Kirschhock, Christine E. A., Van Speybroeck, Veronique, Mayer, James M., De Vos, Dirk
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 16.11.2015 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	metal-organic frameworks metallocenes molecular modeling photochemistry Titanium molecular modeling photochemistry titanium metal-organic frameworks metallocenes
ISSN:	1433-7851, 1521-3773
Online Access:	Get full text
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