A Flexible Photoactive Titanium Metal-Organic Framework Based on a [TiIV3(μ3-O)(O)2(COO)6] Cluster

The synthesis of titanium–carboxylate metal–organic frameworks (MOFs) is hampered by the high reactivity of the commonly employed alkoxide precursors. Herein, we present an innovative approach to titanium‐based MOFs by the use of titanocene dichloride to synthesize COK‐69, the first breathing Ti MOF...

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Vydané v:	Angewandte Chemie International Edition Ročník 54; číslo 47; s. 13912 - 13917
Hlavní autori:	Bueken, Bart, Vermoortele, Frederik, Vanpoucke, Danny E. P., Reinsch, Helge, Tsou, Chih-Chin, Valvekens, Pieterjan, De Baerdemaeker, Trees, Ameloot, Rob, Kirschhock, Christine E. A., Van Speybroeck, Veronique, Mayer, James M., De Vos, Dirk
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Weinheim WILEY-VCH Verlag 16.11.2015 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Vydanie:	International ed. in English
Predmet:	metal-organic frameworks metallocenes molecular modeling photochemistry Titanium molecular modeling photochemistry titanium metal-organic frameworks metallocenes
ISSN:	1433-7851, 1521-3773
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