Unravelling the role of iron and manganese oxides in colouring Late Antique glass by micro-XANES and micro-XRF spectroscopies
This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn) ratios and oxidation states with colour. Despite having a similar matrix chemical composition and concentrations of Fe and Mn oxides, these...
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| Vydáno v: | JPhys photonics Ročník 6; číslo 2; s. 25001 - 25019 |
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| Hlavní autoři: | , , , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
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Bristol
IOP Publishing
01.04.2024
IOP Science |
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| ISSN: | 2515-7647, 2515-7647 |
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| Abstract | This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn) ratios and oxidation states with colour. Despite having a similar matrix chemical composition and concentrations of Fe and Mn oxides, these vessels display different colours (from green to yellow/amber, sometimes with purple streaks). Colour changes can be induced by controlling the reduction-oxidation reactions that occur during glass production, which are influenced by the raw materials, furnace and melt atmosphere, and recycling. To evaluate these parameters, reference glasses were prepared, following the composition of Late Antique archaeological glass recovered from Tintagel (UK) and Whithorn (UK). A corpus of archaeological and experimental glass samples was analysed using bulk Fe and Mn K-edge x-ray absorption near edge structure (XANES) spectroscopy, micro-XANES and micro x-ray fluorescence (
μ
-XRF) at beamline ID21, at the European Synchrotron Radiation Facility. Fe and Mn XANES spectra of the archaeological glass indicate that Fe and Mn are in a similar oxidation state in all the yellow samples, predominantly Fe
3+
and Mn
2+
. No detectable difference in Mn and Fe oxidation state occurs in the purple streaks compared to the yellow glass bulk but
μ
-XRF maps of the distribution of Fe and Mn show that Mn is more concentrated in the purple streaks. This indicates that the purple colour of the streaks is mainly due to a higher Mn/Fe ratio and persistence of more oxidised manganese in the purple areas, even though it is difficult to detect. Many archaeological fragments appear pale green in transmitted light but amber in reflected light. XANES studies detected the presence of surface layers where manganese is more oxidised. This layer is believed to scatter transmitted and reflected light differently and might be responsible for the optical features of the archaeological glass. |
|---|---|
| AbstractList | Abstract This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn) ratios and oxidation states with colour. Despite having a similar matrix chemical composition and concentrations of Fe and Mn oxides, these vessels display different colours (from green to yellow/amber, sometimes with purple streaks). Colour changes can be induced by controlling the reduction-oxidation reactions that occur during glass production, which are influenced by the raw materials, furnace and melt atmosphere, and recycling. To evaluate these parameters, reference glasses were prepared, following the composition of Late Antique archaeological glass recovered from Tintagel (UK) and Whithorn (UK). A corpus of archaeological and experimental glass samples was analysed using bulk Fe and Mn K-edge x-ray absorption near edge structure (XANES) spectroscopy, micro-XANES and micro x-ray fluorescence ( μ -XRF) at beamline ID21, at the European Synchrotron Radiation Facility. Fe and Mn XANES spectra of the archaeological glass indicate that Fe and Mn are in a similar oxidation state in all the yellow samples, predominantly Fe 3+ and Mn 2+ . No detectable difference in Mn and Fe oxidation state occurs in the purple streaks compared to the yellow glass bulk but μ -XRF maps of the distribution of Fe and Mn show that Mn is more concentrated in the purple streaks. This indicates that the purple colour of the streaks is mainly due to a higher Mn/Fe ratio and persistence of more oxidised manganese in the purple areas, even though it is difficult to detect. Many archaeological fragments appear pale green in transmitted light but amber in reflected light. XANES studies detected the presence of surface layers where manganese is more oxidised. This layer is believed to scatter transmitted and reflected light differently and might be responsible for the optical features of the archaeological glass. This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn) ratios and oxidation states with colour. Despite having a similar matrix chemical composition and concentrations of Fe and Mn oxides, these vessels display different colours (from green to yellow/amber, sometimes with purple streaks). Colour changes can be induced by controlling the reduction-oxidation reactions that occur during glass production, which are influenced by the raw materials, furnace and melt atmosphere, and recycling. To evaluate these parameters, reference glasses were prepared, following the composition of Late Antique archaeological glass recovered from Tintagel (UK) and Whithorn (UK). A corpus of archaeological and experimental glass samples was analysed using bulk Fe and Mn K-edge x-ray absorption near edge structure (XANES) spectroscopy, micro-XANES and micro x-ray fluorescence ( μ -XRF) at beamline ID21, at the European Synchrotron Radiation Facility. Fe and Mn XANES spectra of the archaeological glass indicate that Fe and Mn are in a similar oxidation state in all the yellow samples, predominantly Fe ^3+ and Mn ^2+ . No detectable difference in Mn and Fe oxidation state occurs in the purple streaks compared to the yellow glass bulk but μ -XRF maps of the distribution of Fe and Mn show that Mn is more concentrated in the purple streaks. This indicates that the purple colour of the streaks is mainly due to a higher Mn/Fe ratio and persistence of more oxidised manganese in the purple areas, even though it is difficult to detect. Many archaeological fragments appear pale green in transmitted light but amber in reflected light. XANES studies detected the presence of surface layers where manganese is more oxidised. This layer is believed to scatter transmitted and reflected light differently and might be responsible for the optical features of the archaeological glass. This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn) ratios and oxidation states with colour. Despite having a similar matrix chemical composition and concentrations of Fe and Mn oxides, these vessels display different colours (from green to yellow/amber, sometimes with purple streaks). Colour changes can be induced by controlling the reduction-oxidation reactions that occur during glass production, which are influenced by the raw materials, furnace and melt atmosphere, and recycling. To evaluate these parameters, reference glasses were prepared, following the composition of Late Antique archaeological glass recovered from Tintagel (UK) and Whithorn (UK). A corpus of archaeological and experimental glass samples was analysed using bulk Fe and Mn K-edge x-ray absorption near edge structure (XANES) spectroscopy, micro-XANES and micro x-ray fluorescence ( μ -XRF) at beamline ID21, at the European Synchrotron Radiation Facility. Fe and Mn XANES spectra of the archaeological glass indicate that Fe and Mn are in a similar oxidation state in all the yellow samples, predominantly Fe 3+ and Mn 2+ . No detectable difference in Mn and Fe oxidation state occurs in the purple streaks compared to the yellow glass bulk but μ -XRF maps of the distribution of Fe and Mn show that Mn is more concentrated in the purple streaks. This indicates that the purple colour of the streaks is mainly due to a higher Mn/Fe ratio and persistence of more oxidised manganese in the purple areas, even though it is difficult to detect. Many archaeological fragments appear pale green in transmitted light but amber in reflected light. XANES studies detected the presence of surface layers where manganese is more oxidised. This layer is believed to scatter transmitted and reflected light differently and might be responsible for the optical features of the archaeological glass. This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn) ratios and oxidation states with colour. Despite having a similar matrix chemical composition and concentrations of Fe and Mn oxides, these vessels display different colours (from green to yellow/amber, sometimes with purple streaks). Colour changes can be induced by controlling the reduction-oxidation reactions that occur during glass production, which are influenced by the raw materials, furnace and melt atmosphere, and recycling. To evaluate these parameters, reference glasses were prepared, following the composition of Late Antique archaeological glass recovered from Tintagel (UK) and Whithorn (UK). A corpus of archaeological and experimental glass samples was analysed using bulk Fe and Mn K-edge x-ray absorption near edge structure (XANES) spectroscopy, micro-XANES and micro x-ray fluorescence (μ-XRF) at beamline ID21, at the European Synchrotron Radiation Facility. Fe and Mn XANES spectra of the archaeological glass indicate that Fe and Mn are in a similar oxidation state in all the yellow samples, predominantly Fe3+ and Mn2+. No detectable difference in Mn and Fe oxidation state occurs in the purple streaks compared to the yellow glass bulk but μ-XRF maps of the distribution of Fe and Mn show that Mn is more concentrated in the purple streaks. This indicates that the purple colour of the streaks is mainly due to a higher Mn/Fe ratio and persistence of more oxidised manganese in the purple areas, even though it is difficult to detect. Many archaeological fragments appear pale green in transmitted light but amber in reflected light. XANES studies detected the presence of surface layers where manganese is more oxidised. This layer is believed to scatter transmitted and reflected light differently and might be responsible for the optical features of the archaeological glass. |
| Author | Gherardi, Francesca Cotte, Marine Tyson, Rachel Hole, Clément Paynter, Sarah Campbell, Ewan |
| Author_xml | – sequence: 1 givenname: Francesca orcidid: 0000-0003-0469-8154 surname: Gherardi fullname: Gherardi, Francesca organization: Investigative Science, Historic England , Portsmouth, United Kingdom – sequence: 2 givenname: Clément surname: Hole fullname: Hole, Clément organization: European Synchrotron Radiation Facility (ESRF) , Grenoble, France – sequence: 3 givenname: Ewan surname: Campbell fullname: Campbell, Ewan organization: School of Humanities, University of Glasgow , Glasgow, United Kingdom – sequence: 4 givenname: Marine surname: Cotte fullname: Cotte, Marine organization: LAMS, CNRS UMR 8220, Sorbonne Université , UPMC Univ Paris 06, Paris, France – sequence: 5 givenname: Rachel surname: Tyson fullname: Tyson, Rachel organization: Consultant glass specialist , Stroud, United Kingdom – sequence: 6 givenname: Sarah surname: Paynter fullname: Paynter, Sarah organization: Investigative Science, Historic England , Portsmouth, United Kingdom |
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| CitedBy_id | crossref_primary_10_1016_j_ceramint_2024_09_019 crossref_primary_10_3390_ma17235699 crossref_primary_10_1016_j_bsecv_2025_100457 |
| Cites_doi | 10.1039/C6JA00356G doi:10.1016/j.jasrep.2015.08.009 10.1127/0935-1221/2002/0014-0749 doi:10.1016/j.chemgeo.2005.03.004 10.1111/j.1475-4754.2010.00534.x doi:10.1016/S0022-3093(98)00728-5 doi:10.1016/j.jas.2008.08.008 doi:10.1016/j.jnoncrysol.2022.121710 doi:10.1111/j.1475-4754.2000.tb00887.x 10.2138/am-2001-5-612 10.2138/am.2012.3903 10.1127/0935-1221/2011/0023-2125 doi:10.1016/j.corsci.2018.08.012 10.1088/1742-6596/430/1/012007 10.1179/sic.2008.53.Supplement-2.47 10.1111/j.1468-0092.1990.tb00218.x doi:10.1016/j.jasrep.2019.101975 10.1371/journal.pone.0168289 doi:10.1016/j.jas.2015.06.009 10.1007/s00410-008-0323-z 10.1007/s12520-020-01050-0 10.1007/s12520-016-0447-4 10.1111/arcm.12158 doi:10.1016/S0009-2541(00)00322-3 10.1238/Physica.Topical.115a01007 10.1007/s00339-012-7341-4 doi:10.1016/j.jnoncrysol.2005.06.046 doi:10.1016/j.jasrep.2021.103082 doi:10.1016/j.sab.2006.12.002 10.1111/j.1475-4754.2011.00632.x 10.3390/heritage5010021 |
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| References | Capobianco (jpphotonad2259bib28) 2021; 38 Manceau (jpphotonad2259bib32) 2012; 97 Jackson (jpphotonad2259bib8) 2016; 58 Rodrigues (jpphotonad2259bib45) 2018; 143 Bidegaray (jpphotonad2259bib25) 2019; 27 Long (jpphotonad2259bib47) 1998; 239 Cholakova (jpphotonad2259bib22) 2016; 7 Evison (jpphotonad2259bib2) 2008 Campbell (jpphotonad2259bib14) Wedepohl (jpphotonad2259bib16) 1997; 197 Gherardi (jpphotonad2259bib46) 2022; 5 Freestone (jpphotonad2259bib3) 1999; 41 Foy (jpphotonad2259bib18) 2003 Freestone (jpphotonad2259bib19) 2008 Bidegaray (jpphotonad2259bib43) 2020; 12 Nenna (jpphotonad2259bib5) 2015 Ceglia (jpphotonad2259bib21) 2015; 61 Galoisy (jpphotonad2259bib29) 2001; 174 Freestone (jpphotonad2259bib6) 2000 Arletti (jpphotonad2259bib24) 2013; 111 Jackson (jpphotonad2259bib44) 2012; 54 Campbell (jpphotonad2259bib11) 2000 Galili (jpphotonad2259bib4) 2015; vol 127 Schalm (jpphotonad2259bib34) 2011; 53 Chalmin (jpphotonad2259bib31) 2009; 157 Schibille (jpphotonad2259bib10) 2016; 11 Demšar (jpphotonad2259bib39) 2013; 14 Campbell (jpphotonad2259bib13) 2007; 157 Paynter (jpphotonad2259bib9) 2016; 6 Kunicki-Goldfinger (jpphotonad2259bib48) 2008; 53 Wilke (jpphotonad2259bib30) 2001; 86 Campbell (jpphotonad2259bib36) 1997 de Ferri (jpphotonad2259bib23) 2011; 23 Quartieri (jpphotonad2259bib27) 2005; 351 Wilke (jpphotonad2259bib40) 2005; 220 Biron (jpphotonad2259bib49) 2013 Campbell (jpphotonad2259bib12) 2007; vol 74 Velde (jpphotonad2259bib15) 1990; 9 Tyson (jpphotonad2259bib35) Quartieri (jpphotonad2259bib26) 2002; 14 Solé (jpphotonad2259bib42) 2007; 62 Ravel (jpphotonad2259bib38) 2005; 2005 Rossano (jpphotonad2259bib33) 2022; 594 Mirti (jpphotonad2259bib17) 2000; 42 Jackson (jpphotonad2259bib7) 2018; 10 Cotte (jpphotonad2259bib37) 2017; 32 Newville (jpphotonad2259bib41) 2013; 430 Evison (jpphotonad2259bib1) 2000; vol 127 Foster (jpphotonad2259bib20) 2009; 36 |
| References_xml | – volume: 32 start-page: 477 year: 2017 ident: jpphotonad2259bib37 article-title: The ID21 x-ray and infrared microscopy beamline at the ESRF: status and recent applications to artistic materials publication-title: J. Anal. At. Spectrom. doi: 10.1039/C6JA00356G – start-page: 29 year: 2008 ident: jpphotonad2259bib19 article-title: The composition and production of Anglo-Saxon glass – volume: 7 start-page: 625 year: 2016 ident: jpphotonad2259bib22 article-title: Compositional identification of 6th c. AD glass from the Lower Danube publication-title: J. Archaeol. Sci. doi: doi:10.1016/j.jasrep.2015.08.009 – volume: 14 start-page: 749 year: 2002 ident: jpphotonad2259bib26 article-title: Fe and Mn K-edge XANES study of ancient Roman glasses publication-title: Eur. J. Mineral. doi: 10.1127/0935-1221/2002/0014-0749 – volume: 220 start-page: 143 year: 2005 ident: jpphotonad2259bib40 article-title: Determination of the iron oxidation state in basaltic glasses using XANES at the K-edge publication-title: Chem. Geol. doi: doi:10.1016/j.chemgeo.2005.03.004 – volume: vol 127 start-page: 47 year: 2000 ident: jpphotonad2259bib1 article-title: Glass VESSELS in England AD 400–1100 – start-page: 297 year: 1997 ident: jpphotonad2259bib36 article-title: The early medieval imports – start-page: 33 year: 2000 ident: jpphotonad2259bib11 article-title: A review of glass vessels in Western Britain and Ireland AD 400–800 – volume: 53 start-page: 103 year: 2011 ident: jpphotonad2259bib34 article-title: Manganese staining of archaeological glass: the characterization of Mn-rich inclusions in leached layers and a hypothesis of its formation publication-title: Archaeometry doi: 10.1111/j.1475-4754.2010.00534.x – volume: 239 start-page: 126 year: 1998 ident: jpphotonad2259bib47 article-title: Solarization of soda–lime–silicate glass containing manganese publication-title: J. Non-Cryst. Solids doi: doi:10.1016/S0022-3093(98)00728-5 – volume: 6 start-page: 31 year: 2016 ident: jpphotonad2259bib9 article-title: Re-used Roman rubbish: a thousand years of recycling glass publication-title: Eur. J. Postclass. Archaeol. – volume: 36 start-page: 189 year: 2009 ident: jpphotonad2259bib20 article-title: The composition of ‘naturally coloured’ late Roman vessel glass from Britain and the implications for models of glass production and supply publication-title: J. Archaeol. Sci. doi: doi:10.1016/j.jas.2008.08.008 – volume: 594 year: 2022 ident: jpphotonad2259bib33 article-title: Glass colourations caused by Mn-Fe redox pair: application to ancient glass technology publication-title: J. Non-Cryst. Solids doi: doi:10.1016/j.jnoncrysol.2022.121710 – volume: 42 start-page: 359 year: 2000 ident: jpphotonad2259bib17 article-title: Scientific analysis of seventh-century glass fragments from the Crypta Balbi in Rome publication-title: Archaeometry doi: doi:10.1111/j.1475-4754.2000.tb00887.x – volume: 86 start-page: 714 year: 2001 ident: jpphotonad2259bib30 article-title: Oxidation state and coordination of Fe in minerals: an Fe K-XANES spectroscopic study publication-title: Am. Mineral. doi: 10.2138/am-2001-5-612 – ident: jpphotonad2259bib35 article-title: Glass – volume: 97 start-page: 816 year: 2012 ident: jpphotonad2259bib32 article-title: Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy publication-title: Am. Mineral. doi: 10.2138/am.2012.3903 – year: 2008 ident: jpphotonad2259bib2 – volume: 23 start-page: 969 year: 2011 ident: jpphotonad2259bib23 article-title: XANES, UV-VIS and luminescence spectroscopic study of chromophores in ancient HIMT glass publication-title: Eur. J. Mineral. doi: 10.1127/0935-1221/2011/0023-2125 – volume: 143 start-page: 362 year: 2018 ident: jpphotonad2259bib45 article-title: Early stages of surface alteration of soda-rich-silicate glasses in the museum environment publication-title: Corros. Sci. doi: doi:10.1016/j.corsci.2018.08.012 – volume: 430 year: 2013 ident: jpphotonad2259bib41 article-title: Larch: an analysis package for XAFS and related spectroscopies publication-title: J. Phys.: Conf. Ser. doi: 10.1088/1742-6596/430/1/012007 – volume: 53 start-page: 47 year: 2008 ident: jpphotonad2259bib48 article-title: Unstable historic glass: symptoms, causes, mechanisms and conservation publication-title: Stud. Conserv. doi: 10.1179/sic.2008.53.Supplement-2.47 – volume: 157 year: 2007 ident: jpphotonad2259bib13 article-title: Continental and Mediterranean imports to Atlantic Britain and Ireland, AD 400¬-800 publication-title: Counc. Br. Archaeol. Res. Rep. – volume: 9 start-page: 105 year: 1990 ident: jpphotonad2259bib15 article-title: Alumina and calcium oxide content of glass found in Western and Northern Europe, first to ninth centuries publication-title: Oxford J. Archaeol. doi: 10.1111/j.1468-0092.1990.tb00218.x – volume: 27 year: 2019 ident: jpphotonad2259bib25 article-title: To be purple or not to be purple? How different production parameters influence colour and redox in manganese containing glass publication-title: J. Archaeol. Sci. doi: doi:10.1016/j.jasrep.2019.101975 – volume: 11 year: 2016 ident: jpphotonad2259bib10 article-title: Comprehensive chemical characterisation of byzantine glass weights publication-title: PLoS One doi: 10.1371/journal.pone.0168289 – start-page: 49 year: 2013 ident: jpphotonad2259bib49 article-title: Colouring, decolouring and opacifying of glass – ident: jpphotonad2259bib14 article-title: Glass unpublished complete glass report from 20th-century excavations at Tintagel Castle – start-page: 1 year: 2015 ident: jpphotonad2259bib5 article-title: Primary glass workshops in Graeco-Roman Egypt: preliminary report on the excavations of the site of Beni-Salama, Wadi Natrun (2003, 2005–2009) – volume: 197 start-page: 177 year: 1997 ident: jpphotonad2259bib16 article-title: Römische und fränkische Gläser aus dem Gräberfeld von Krefeld-Gellep publication-title: Bonner Jahrbücher – volume: 14 start-page: 2349 year: 2013 ident: jpphotonad2259bib39 article-title: Orange: data mining toolbox in python publication-title: J. Mach. Learn. Res. – volume: 61 start-page: 213 year: 2015 ident: jpphotonad2259bib21 article-title: Late antique glass distribution and consumption in Cyprus: a chemical study publication-title: J. Archaeol. Sci. doi: doi:10.1016/j.jas.2015.06.009 – volume: 157 start-page: 111 year: 2009 ident: jpphotonad2259bib31 article-title: A pre-edge analysis of Mn K-edge XANES spectra to help determine the speciation of manganese in minerals and glasses publication-title: Contrib. Mineral. Petrol. doi: 10.1007/s00410-008-0323-z – volume: 12 start-page: 109 year: 2020 ident: jpphotonad2259bib43 article-title: 50 shades of colour: how thickness, iron redox and manganese/antimony contents influence perceived and intrinsic colour in Roman glass publication-title: Archaeol. Anthropol. Sci. doi: 10.1007/s12520-020-01050-0 – year: 2000 ident: jpphotonad2259bib6 article-title: Primary glass from Israel and the production of glass in late antiquity and the early Islamic period – volume: 10 start-page: 1179 year: 2018 ident: jpphotonad2259bib7 article-title: Glassmaking using natron from el-Barnugi (Egypt); Pliny and the Roman glass industry publication-title: Archaeol. Anthropol. Sci. doi: 10.1007/s12520-016-0447-4 – volume: 58 start-page: 68 year: 2016 ident: jpphotonad2259bib8 article-title: A great big melting pot: exploring patterns of glass supply, consumption and recycling in Roman Coppergate, York* publication-title: Archaeometry doi: 10.1111/arcm.12158 – volume: vol 127 year: 2015 ident: jpphotonad2259bib4 article-title: Mediterranean coasts, cargoes of raw glass – volume: 174 start-page: 307 year: 2001 ident: jpphotonad2259bib29 article-title: High-resolution XANES spectra of iron in minerals and glasses: structural information from the pre-edge region publication-title: Chem. Geol. doi: doi:10.1016/S0009-2541(00)00322-3 – volume: 2005 start-page: 1007 year: 2005 ident: jpphotonad2259bib38 article-title: ATHENA and ARTEMIS: interactive graphical data analysis using IFEFFIT publication-title: Phys. Scr. doi: 10.1238/Physica.Topical.115a01007 – volume: 111 start-page: 99 year: 2013 ident: jpphotonad2259bib24 article-title: A XANES study of chromophores in archaeological glass publication-title: Appl. Phys. A doi: 10.1007/s00339-012-7341-4 – volume: 351 start-page: 3013 year: 2005 ident: jpphotonad2259bib27 article-title: The ancient glass production of the Medieval Val Gargassa glasshouse: Fe and Mn XANES study publication-title: J. Non-Cryst. Solids doi: doi:10.1016/j.jnoncrysol.2005.06.046 – volume: vol 74 start-page: 222 year: 2007 ident: jpphotonad2259bib12 article-title: Glass – volume: 38 year: 2021 ident: jpphotonad2259bib28 article-title: The representation of skin colour in medieval stained glasses: the role of manganese publication-title: J. Archaeol. Sci. doi: doi:10.1016/j.jasrep.2021.103082 – start-page: 41 year: 2003 ident: jpphotonad2259bib18 article-title: Caractérisation des verres de la fin de l’Antiquité en Méditerranée occidentale: l’émergence de nouveaux courants commerciaux – volume: 62 start-page: 63 year: 2007 ident: jpphotonad2259bib42 article-title: A multiplatform code for the analysis of energy-dispersive x-ray fluorescence spectra publication-title: Spectrochim. Acta B doi: doi:10.1016/j.sab.2006.12.002 – volume: 41 start-page: 105 year: 1999 ident: jpphotonad2259bib3 article-title: The great glass slab at Bet She’arim, Israel: an early Islamic glassmaking experiment? publication-title: J. Glass Stud. – volume: 54 start-page: 489 year: 2012 ident: jpphotonad2259bib44 article-title: An assessment of compositional and morphological changes in model archaeological glasses in an acid burial matrix publication-title: Archaeometry doi: 10.1111/j.1475-4754.2011.00632.x – volume: 5 start-page: 362 year: 2022 ident: jpphotonad2259bib46 article-title: Compositional and morphological investigations of Roman glass from cremation deposits at Birdoswald fort on Hadrian’s Wall, UK publication-title: Heritage doi: 10.3390/heritage5010021 |
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| Snippet | This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and manganese (Mn)... Abstract This research aims to understand colouring technologies in 5th–7th centuries glass imported to Atlantic Britain by correlating the iron (Fe) and... |
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| SubjectTerms | Archaeology Chemical composition Chemical Sciences Color Coloring colouring techniques Iron iron redox Late Antique glass Manganese or physical chemistry Oxidation Raw materials Spectrum analysis Surface layers Synchrotron radiation Theoretical and Valence X ray absorption X ray fluorescence analysis XANES XRF |
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| Title | Unravelling the role of iron and manganese oxides in colouring Late Antique glass by micro-XANES and micro-XRF spectroscopies |
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