Pt/H-ZSM-22 hydroisomerization catalysts optimization guided by Single-Event MicroKinetic modeling

[Display omitted] ► Zeolite shape selectivity can be exploited to boost hydroisomerization yields by 10%. ► Contribution analyses guide development of improved ZSM-22 crystals. ► Gentle synthesis template removal avoids crystal restructuring and acidity variations. A Single-Event MicroKinetic (SEMK)...

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Vydáno v:	Journal of catalysis Ročník 290; s. 165 - 176
Hlavní autoři:	Choudhury, Indranil R., Hayasaka, Kazuaki, Thybaut, Joris W., Laxmi Narasimhan, C.S., Denayer, Joeri F., Martens, Johan A., Marin, Guy B.
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Amsterdam Elsevier Inc 01.06.2012 Elsevier Elsevier BV
Témata:	1,6-hexanediamine acidity Acids Catalysis Catalysts cation exchange Chemistry Colloidal state and disperse state crystallization Crystals decane enthalpy Exact sciences and technology General and physical chemistry Hydroisomerization Ion-exchange isomerization Kinetics micropores Porous materials Rational catalyst design Shape selectivity Single-Event MicroKinetics Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry zeolites Zeolites: preparations and properties Hydroisomerization Shape selectivity Rational catalyst design Single-Event MicroKinetics Shape Micropore Enthalpy Acidic site Selectivity Porous material Modeling Physisorption Molecular sieve Optimization Template Design Cation exchange Isomerization Crystallization Acidity Zeolite Strong acid Heterogeneous catalysis Decane Microporosity Protonation Models Thermodynamic properties Catalyst
ISSN:	0021-9517, 1090-2694
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