A Hydrogen‐Deficient Nickel–Cobalt Double Hydroxide for Photocatalytic Overall Water Splitting

Developing highly efficient and low‐cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel–cobalt double hydroxide can achieve overall water splitting by itself upon solar l...

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Veröffentlicht in:	Angewandte Chemie International Edition Jg. 59; H. 28; S. 11510 - 11515
Hauptverfasser:	Wang, Min, Wang, Jia‐Qi, Xi, Cong, Cheng, Chuan‐Qi, Zou, Cheng‐Qin, Zhang, Rui, Xie, Ya‐Meng, Guo, Zhong‐Lu, Tang, Cheng‐Chun, Dong, Cun‐Ku, Chen, Yong‐Jun, Du, Xi‐Wen
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Germany Wiley Subscription Services, Inc 06.07.2020
Ausgabe:	International ed. in English
Schlagworte:	Ablation Catalysts Chemical evolution Clean energy Cobalt Composition Hydrogen Hydrogen evolution Hydrogen-based energy Intermetallic compounds Ions Irradiation laser ablation Light irradiation Nickel Photocatalysis Photocatalysts Solar energy Solar power Splitting Water splitting nickel laser ablation cobalt water splitting photocatalysis
ISSN:	1433-7851, 1521-3773, 1521-3773
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Abstract	Developing highly efficient and low‐cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel–cobalt double hydroxide can achieve overall water splitting by itself upon solar light irradiation, avoiding the consumption of noble‐metal co‐catalysts. We employed an intensive laser to ablate a NiCo alloy target immersed in alkaline solution, and produced so‐called L‐NiCo nanosheets with a nonstoichiometric composition and O2−/Co3+ ions exposed on the surface. The nonstoichiometric composition broadens the band gap, while O2− and Co3+ ions boost hydrogen and oxygen evolution, respectively. As such, the photocatalyst achieves a H2 evolution rate of 1.7 μmol h−1 under AM 1.5G sunlight irradiation and an apparent quantum yield (AQE) of 1.38 % at 380 nm. A single‐phase photocatalyst, a hydrogen‐deficient nickel–cobalt double hydroxide, was generated by laser ablation. This photocatalyst can drive overall water splitting under solar light irradiation in the absence of sacrificial agents and noble metal co‐catalysts because of its unique composition and structure, with partially removed hydrogen atoms as well as O2− and Co3+ ions exposed on the surface.
AbstractList	Developing highly efficient and low‐cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel–cobalt double hydroxide can achieve overall water splitting by itself upon solar light irradiation, avoiding the consumption of noble‐metal co‐catalysts. We employed an intensive laser to ablate a NiCo alloy target immersed in alkaline solution, and produced so‐called L‐NiCo nanosheets with a nonstoichiometric composition and O2−/Co3+ ions exposed on the surface. The nonstoichiometric composition broadens the band gap, while O2− and Co3+ ions boost hydrogen and oxygen evolution, respectively. As such, the photocatalyst achieves a H2 evolution rate of 1.7 μmol h−1 under AM 1.5G sunlight irradiation and an apparent quantum yield (AQE) of 1.38 % at 380 nm. A single‐phase photocatalyst, a hydrogen‐deficient nickel–cobalt double hydroxide, was generated by laser ablation. This photocatalyst can drive overall water splitting under solar light irradiation in the absence of sacrificial agents and noble metal co‐catalysts because of its unique composition and structure, with partially removed hydrogen atoms as well as O2− and Co3+ ions exposed on the surface. Developing highly efficient and low-cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel-cobalt double hydroxide can achieve overall water splitting by itself upon solar light irradiation, avoiding the consumption of noble-metal co-catalysts. We employed an intensive laser to ablate a NiCo alloy target immersed in alkaline solution, and produced so-called L-NiCo nanosheets with a nonstoichiometric composition and O /Co ions exposed on the surface. The nonstoichiometric composition broadens the band gap, while O and Co ions boost hydrogen and oxygen evolution, respectively. As such, the photocatalyst achieves a H evolution rate of 1.7 μmol h under AM 1.5G sunlight irradiation and an apparent quantum yield (AQE) of 1.38 % at 380 nm. Developing highly efficient and low‐cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel–cobalt double hydroxide can achieve overall water splitting by itself upon solar light irradiation, avoiding the consumption of noble‐metal co‐catalysts. We employed an intensive laser to ablate a NiCo alloy target immersed in alkaline solution, and produced so‐called L‐NiCo nanosheets with a nonstoichiometric composition and O 2− /Co 3+ ions exposed on the surface. The nonstoichiometric composition broadens the band gap, while O 2− and Co 3+ ions boost hydrogen and oxygen evolution, respectively. As such, the photocatalyst achieves a H 2 evolution rate of 1.7 μmol h −1 under AM 1.5G sunlight irradiation and an apparent quantum yield (AQE) of 1.38 % at 380 nm. Developing highly efficient and low-cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel-cobalt double hydroxide can achieve overall water splitting by itself upon solar light irradiation, avoiding the consumption of noble-metal co-catalysts. We employed an intensive laser to ablate a NiCo alloy target immersed in alkaline solution, and produced so-called L-NiCo nanosheets with a nonstoichiometric composition and O2- /Co3+ ions exposed on the surface. The nonstoichiometric composition broadens the band gap, while O2- and Co3+ ions boost hydrogen and oxygen evolution, respectively. As such, the photocatalyst achieves a H2 evolution rate of 1.7 μmol h-1 under AM 1.5G sunlight irradiation and an apparent quantum yield (AQE) of 1.38 % at 380 nm.Developing highly efficient and low-cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel-cobalt double hydroxide can achieve overall water splitting by itself upon solar light irradiation, avoiding the consumption of noble-metal co-catalysts. We employed an intensive laser to ablate a NiCo alloy target immersed in alkaline solution, and produced so-called L-NiCo nanosheets with a nonstoichiometric composition and O2- /Co3+ ions exposed on the surface. The nonstoichiometric composition broadens the band gap, while O2- and Co3+ ions boost hydrogen and oxygen evolution, respectively. As such, the photocatalyst achieves a H2 evolution rate of 1.7 μmol h-1 under AM 1.5G sunlight irradiation and an apparent quantum yield (AQE) of 1.38 % at 380 nm. Developing highly efficient and low‐cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen energy. Herein, we demonstrate that a nonstoichiometric nickel–cobalt double hydroxide can achieve overall water splitting by itself upon solar light irradiation, avoiding the consumption of noble‐metal co‐catalysts. We employed an intensive laser to ablate a NiCo alloy target immersed in alkaline solution, and produced so‐called L‐NiCo nanosheets with a nonstoichiometric composition and O2−/Co3+ ions exposed on the surface. The nonstoichiometric composition broadens the band gap, while O2− and Co3+ ions boost hydrogen and oxygen evolution, respectively. As such, the photocatalyst achieves a H2 evolution rate of 1.7 μmol h−1 under AM 1.5G sunlight irradiation and an apparent quantum yield (AQE) of 1.38 % at 380 nm.
Author	Wang, Jia‐Qi Xi, Cong Cheng, Chuan‐Qi Xie, Ya‐Meng Zou, Cheng‐Qin Wang, Min Zhang, Rui Guo, Zhong‐Lu Chen, Yong‐Jun Du, Xi‐Wen Dong, Cun‐Ku Tang, Cheng‐Chun
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Snippet	Developing highly efficient and low‐cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen... Developing highly efficient and low-cost photocatalysts for overall water splitting has long been a pursuit for converting solar power into clean hydrogen...
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SubjectTerms	Ablation Catalysts Chemical evolution Clean energy Cobalt Composition Hydrogen Hydrogen evolution Hydrogen-based energy Intermetallic compounds Ions Irradiation laser ablation Light irradiation Nickel Photocatalysis Photocatalysts Solar energy Solar power Splitting Water splitting
Title	A Hydrogen‐Deficient Nickel–Cobalt Double Hydroxide for Photocatalytic Overall Water Splitting
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