MOFs as Multifunctional Catalysts: Synthesis of Secondary Arylamines, Quinolines, Pyrroles, and Arylpyrrolidines over Bifunctional MIL-101

Bifunctional MIL‐101 MOFs containing Lewis acid Cr3+ sites and Pd or Pt hydrogenation/reduction centers, either as isolated metal complexes or in the form of encapsulated metal nanoparticles, have shown to be highly active catalysts for the one‐pot nitroarene reduction and reductive amination of car...

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Vydané v:ChemCatChem Ročník 5; číslo 2; s. 538 - 549
Hlavní autori: Cirujano, Francisco G., Leyva-Pérez, Antonio, Corma, Avelino, Llabrés i Xamena, Francesc X.
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Weinheim WILEY-VCH Verlag 01.02.2013
WILEY‐VCH Verlag
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Predmet:
amination
carbonyl compounds
Catalysts
heterocycle synthesis
hydrogenation
metal-organic frameworks
ISSN:1867-3880, 1867-3899
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Shrnutí:Bifunctional MIL‐101 MOFs containing Lewis acid Cr3+ sites and Pd or Pt hydrogenation/reduction centers, either as isolated metal complexes or in the form of encapsulated metal nanoparticles, have shown to be highly active catalysts for the one‐pot nitroarene reduction and reductive amination of carbonyl compounds. This preparation procedure has been successfully applied to the synthesis of secondary arylamines, quinolines, pyrrols, and 3‐arylpyrrolidines. In all the cases, the MOFs have shown superior performances with respect to commercially available Pd and Pt metal catalysts under the same conditions. Site‐seeing with MOFs: Bifunctional MIL‐101 MOFs containing Lewis acid Cr3+ sites and Pd or Pt hydrogenation/reduction centers are highly active catalysts for the one‐pot conversion of nitro compounds into valuable nitrogen containing chemicals.
Bibliografia:CSIC - No. 201080I020
ArticleID:CCTC201200878
Ministerio de Educación y Ciencia e Innovación - No. MAT2011-29020-C02-01; No. CSD2009-00050
ark:/67375/WNG-9Q4L5VM8-9
Ministerio de Economía y Competitividad - No. SEV 2012 0267
istex:AEC5707CF6044CCF0C4E9834DEC68964CB5C2151
ObjectType-Article-1
SourceType-Scholarly Journals-1
content type line 14
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201200878