General and Highly Efficient Iron-Catalyzed Hydrogenation of Aldehydes, Ketones, and α,β-Unsaturated Aldehydes

EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpen...

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Veröffentlicht in:	Angewandte Chemie International Edition Jg. 52; H. 19; S. 5120 - 5124
Hauptverfasser:	Fleischer, Steffen, Zhou, Shaolin, Junge, Kathrin, Beller, Matthias
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Weinheim WILEY-VCH Verlag 03.05.2013 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Ausgabe:	International ed. in English
Schlagworte:	Alcohols Aldehydes Catalysts Column chromatography Hydrogenation iron Ketones reduction synthetic methods
ISSN:	1433-7851, 1521-3773, 1521-3773
Online-Zugang:	Volltext
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Abstract	EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpensively prepared, and is also stable to air, water, and column chromatography.
AbstractList	EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpensively prepared, and is also stable to air, water, and column chromatography.
Author	Zhou, Shaolin Beller, Matthias Fleischer, Steffen Junge, Kathrin
Author_xml	– sequence: 1 givenname: Steffen surname: Fleischer fullname: Fleischer, Steffen organization: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany) http://www.catalysis.de – sequence: 2 givenname: Shaolin surname: Zhou fullname: Zhou, Shaolin organization: College of Chemistry, Central China Normal University, Luoyu Road, No. 152, 430079 Wuhan (P.R. China) – sequence: 3 givenname: Kathrin surname: Junge fullname: Junge, Kathrin organization: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany) http://www.catalysis.de – sequence: 4 givenname: Matthias surname: Beller fullname: Beller, Matthias email: matthias.beller@catalysis.de organization: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany) http://www.catalysis.de
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/23564682$$D View this record in MEDLINE/PubMed
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Notes	BMBF State of Mecklenburg-Western Pomerania DFG This work has been funded by the State of Mecklenburg-Western Pomerania, the BMBF, and the DFG. We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Koch, and S. Rossmeisl (all at the LIKAT) for their excellent technical and analytical support. S.F. thanks the Evonik Stiftung for providing a scholarship. ark:/67375/WNG-79RWPT8F-K istex:BC4E4F15AC0B02E78770A0AAA3D8CD0C8B536657 ArticleID:ANIE201301239 This work has been funded by the State of Mecklenburg‐Western Pomerania, the BMBF, and the DFG. We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Koch, and S. Rossmeisl (all at the LIKAT) for their excellent technical and analytical support. S.F. thanks the Evonik Stiftung for providing a scholarship. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
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Snippet	EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary,...
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SubjectTerms	Alcohols Aldehydes Catalysts Column chromatography Hydrogenation iron Ketones reduction synthetic methods
Title	General and Highly Efficient Iron-Catalyzed Hydrogenation of Aldehydes, Ketones, and α,β-Unsaturated Aldehydes
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