General and Highly Efficient Iron-Catalyzed Hydrogenation of Aldehydes, Ketones, and α,β-Unsaturated Aldehydes

EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpen...

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Published in:Angewandte Chemie International Edition Vol. 52; no. 19; pp. 5120 - 5124
Main Authors: Fleischer, Steffen, Zhou, Shaolin, Junge, Kathrin, Beller, Matthias
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 03.05.2013
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Edition:International ed. in English
Subjects:
Alcohols
Aldehydes
Catalysts
Column chromatography
Hydrogenation
iron
Ketones
reduction
synthetic methods
ISSN:1433-7851, 1521-3773, 1521-3773
Online Access:Get full text
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Summary:EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpensively prepared, and is also stable to air, water, and column chromatography.
Bibliography:BMBF
State of Mecklenburg-Western Pomerania
DFG
This work has been funded by the State of Mecklenburg-Western Pomerania, the BMBF, and the DFG. We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Koch, and S. Rossmeisl (all at the LIKAT) for their excellent technical and analytical support. S.F. thanks the Evonik Stiftung for providing a scholarship.
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istex:BC4E4F15AC0B02E78770A0AAA3D8CD0C8B536657
ArticleID:ANIE201301239
This work has been funded by the State of Mecklenburg‐Western Pomerania, the BMBF, and the DFG. We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Koch, and S. Rossmeisl (all at the LIKAT) for their excellent technical and analytical support. S.F. thanks the Evonik Stiftung for providing a scholarship.
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201301239