General and Highly Efficient Iron-Catalyzed Hydrogenation of Aldehydes, Ketones, and α,β-Unsaturated Aldehydes

EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpen...

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Vydáno v:Angewandte Chemie International Edition Ročník 52; číslo 19; s. 5120 - 5124
Hlavní autoři: Fleischer, Steffen, Zhou, Shaolin, Junge, Kathrin, Beller, Matthias
Médium: Journal Article
Jazyk:angličtina
Vydáno: Weinheim WILEY-VCH Verlag 03.05.2013
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Vydání:International ed. in English
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ISSN:1433-7851, 1521-3773, 1521-3773
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Abstract EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpensively prepared, and is also stable to air, water, and column chromatography.
AbstractList EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary, secondary, and allylic alcohols were obtained in good to excellent yields under mild reaction conditions. The catalyst is easily and inexpensively prepared, and is also stable to air, water, and column chromatography.
Author Zhou, Shaolin
Beller, Matthias
Fleischer, Steffen
Junge, Kathrin
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  surname: Fleischer
  fullname: Fleischer, Steffen
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  givenname: Shaolin
  surname: Zhou
  fullname: Zhou, Shaolin
  organization: College of Chemistry, Central China Normal University, Luoyu Road, No. 152, 430079 Wuhan (P.R. China)
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  givenname: Kathrin
  surname: Junge
  fullname: Junge, Kathrin
  organization: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany) http://www.catalysis.de
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  givenname: Matthias
  surname: Beller
  fullname: Beller, Matthias
  email: matthias.beller@catalysis.de
  organization: Leibniz-Institut für Katalyse an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock (Germany) http://www.catalysis.de
BackLink https://www.ncbi.nlm.nih.gov/pubmed/23564682$$D View this record in MEDLINE/PubMed
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Notes BMBF
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This work has been funded by the State of Mecklenburg-Western Pomerania, the BMBF, and the DFG. We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Koch, and S. Rossmeisl (all at the LIKAT) for their excellent technical and analytical support. S.F. thanks the Evonik Stiftung for providing a scholarship.
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This work has been funded by the State of Mecklenburg‐Western Pomerania, the BMBF, and the DFG. We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Koch, and S. Rossmeisl (all at the LIKAT) for their excellent technical and analytical support. S.F. thanks the Evonik Stiftung for providing a scholarship.
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2011; 47
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2008 2008; 120 47
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Snippet EnvIRONmentally friendly: The title hydrogenation of aldehydes, ketones, and α,β‐unsaturated aldehydes is reported. In the presence of the catalyst 1, primary,...
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SubjectTerms Alcohols
Aldehydes
Catalysts
Column chromatography
Hydrogenation
iron
Ketones
reduction
synthetic methods
Title General and Highly Efficient Iron-Catalyzed Hydrogenation of Aldehydes, Ketones, and α,β-Unsaturated Aldehydes
URI https://api.istex.fr/ark:/67375/WNG-79RWPT8F-K/fulltext.pdf
https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201301239
https://www.ncbi.nlm.nih.gov/pubmed/23564682
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Volume 52
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