Catalytic Enantioselective Aminopalladation–Heck Cascade

Domino processes initiated by intramolecular nucleopalladation of alkynes have been developed into powerful synthetic tools for the synthesis of functionalized heterocycles. However, a catalytic enantioselective version of this class of reactions remains scarce. We report herein that reaction of 2‐a...

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Veröffentlicht in:	Angewandte Chemie International Edition Jg. 60; H. 13; S. 7093 - 7097
Hauptverfasser:	He, Yu‐Ping, Cao, Jian, Wu, Hua, Wang, Qian, Zhu, Jieping
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	WEINHEIM Wiley 22.03.2021 Wiley Subscription Services, Inc
Ausgabe:	International ed. in English
Schlagworte:	Alkynes asymmetric synthesis Chemical synthesis Chemistry Chemistry, Multidisciplinary Cyclopentene domino reactions Enantiomers homogeneous catalysis Indoles nucleopalladation Oxidants oxidative Heck reactions Oxidizing agents Physical Sciences Science & Technology ROUTE COMPLEXES ALKYNES oxidative Heck reactions INDOLES FUNCTIONALIZATION asymmetric synthesis homogeneous catalysis domino reactions TANDEM REACTION ISOCYANIDE INSERTION nucleopalladation CYCLIZATION
ISSN:	1433-7851, 1521-3773, 1521-3773
Online-Zugang:	Volltext
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