Kinetics and Chemorheological Analysis of Cross-Linking Reactions in Humins
Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a thorough study concerning the crosslinking kinetics of humins by chemorheological analysis and model-free kinetics under isothermal and non-iso...
Uloženo v:
| Vydáno v: | Polymers Ročník 11; číslo 11; s. 1804 |
|---|---|
| Hlavní autoři: | , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
| Vydáno: |
Switzerland
MDPI AG
02.11.2019
MDPI |
| Edice: | Special issue: Sustainable Bio-Based Polymers: Towards a Circular Bioeconomy |
| Témata: | |
| ISSN: | 2073-4360, 2073-4360 |
| On-line přístup: | Získat plný text |
| Tagy: |
Přidat tag
Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!
|
| Abstract | Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a thorough study concerning the crosslinking kinetics of humins by chemorheological analysis and model-free kinetics under isothermal and non-isothermal curing. Humins can auto-crosslink under the effect of temperature, and the reaction can be fastener when adding an acidic initiator. Thus, the effect of P-Toluenesulfonic acid monohydrate (pTSA) on the crosslinking kinetics was also studied. The dependencies of the effective activation energy (Eα-dependencies) were determined by an advanced isoconversional method and correlated with the variation of complex viscosity during curing. It is shown that humins curing involves multi-step complex reactions and that the use of an acidic initiator allows faster crosslinking at lower temperatures, involving lower Eα. The shift from chemical to diffusion control was also estimated. |
|---|---|
| AbstractList | Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a thorough study concerning the crosslinking kinetics of humins by chemorheological analysis and model-free kinetics under isothermal and non-isothermal curing. Humins can auto-crosslink under the effect of temperature, and the reaction can be fastener when adding an acidic initiator. Thus, the effect of P-Toluenesulfonic acid monohydrate (pTSA) on the crosslinking kinetics was also studied. The dependencies of the effective activation energy (Eα-dependencies) were determined by an advanced isoconversional method and correlated with the variation of complex viscosity during curing. It is shown that humins curing involves multi-step complex reactions and that the use of an acidic initiator allows faster crosslinking at lower temperatures, involving lower Eα. The shift from chemical to diffusion control was also estimated. Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a thorough study concerning the crosslinking kinetics of humins by chemorheological analysis and model-free kinetics under isothermal and non-isothermal curing. Humins can auto-crosslink under the effect of temperature, and the reaction can be fastener when adding an acidic initiator. Thus, the effect of P-Toluenesulfonic acid monohydrate (pTSA) on the crosslinking kinetics was also studied. The dependencies of the effective activation energy ( -dependencies) were determined by an advanced isoconversional method and correlated with the variation of complex viscosity during curing. It is shown that humins curing involves multi-step complex reactions and that the use of an acidic initiator allows faster crosslinking at lower temperatures, involving lower . The shift from chemical to diffusion control was also estimated. Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a thorough study concerning the crosslinking kinetics of humins by chemorheological analysis and model-free kinetics under isothermal and non-isothermal curing. Humins can auto-crosslink under the effect of temperature, and the reaction can be fastener when adding an acidic initiator. Thus, the effect of P-Toluenesulfonic acid monohydrate (pTSA) on the crosslinking kinetics was also studied. The dependencies of the effective activation energy (Eα-dependencies) were determined by an advanced isoconversional method and correlated with the variation of complex viscosity during curing. It is shown that humins curing involves multi-step complex reactions and that the use of an acidic initiator allows faster crosslinking at lower temperatures, involving lower Eα. The shift from chemical to diffusion control was also estimated.Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a thorough study concerning the crosslinking kinetics of humins by chemorheological analysis and model-free kinetics under isothermal and non-isothermal curing. Humins can auto-crosslink under the effect of temperature, and the reaction can be fastener when adding an acidic initiator. Thus, the effect of P-Toluenesulfonic acid monohydrate (pTSA) on the crosslinking kinetics was also studied. The dependencies of the effective activation energy (Eα-dependencies) were determined by an advanced isoconversional method and correlated with the variation of complex viscosity during curing. It is shown that humins curing involves multi-step complex reactions and that the use of an acidic initiator allows faster crosslinking at lower temperatures, involving lower Eα. The shift from chemical to diffusion control was also estimated. Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a thorough study concerning the crosslinking kinetics of humins by chemorheological analysis and model-free kinetics under isothermal and non-isothermal curing. Humins can auto-crosslink under the effect of temperature, and the reaction can be fastener when adding an acidic initiator. Thus, the effect of P-Toluenesulfonic acid monohydrate (pTSA) on the crosslinking kinetics was also studied. The dependencies of the effective activation energy (E-alpha-dependencies) were determined by an advanced isoconversional method and correlated with the variation of complex viscosity during curing. It is shown that humins curing involves multi-step complex reactions and that the use of an acidic initiator allows faster crosslinking at lower temperatures, involving lower E-alpha. The shift from chemical to diffusion control was also estimated. |
| Author | Sbirrazzuoli, Nicolas Sangregorio, Anna Jong, Ed de Guigo, Nathanaël |
| AuthorAffiliation | 1 Avantium Chemicals B.V., Zekeringstraat 29, 1014 BV Amsterdam, The Netherlands; anna.sangregorio@avantium.com (A.S.); ed.dejong@avantium.com (E.d.J.) 2 Institut de Chimie de Nice, Université Côte d’Azur, CNRS, UMR 7272, 06108 Nice, France; nathanael.guigo@univ-cotedazur.fr |
| AuthorAffiliation_xml | – name: 2 Institut de Chimie de Nice, Université Côte d’Azur, CNRS, UMR 7272, 06108 Nice, France; nathanael.guigo@univ-cotedazur.fr – name: 1 Avantium Chemicals B.V., Zekeringstraat 29, 1014 BV Amsterdam, The Netherlands; anna.sangregorio@avantium.com (A.S.); ed.dejong@avantium.com (E.d.J.) |
| Author_xml | – sequence: 1 givenname: Anna surname: Sangregorio fullname: Sangregorio, Anna – sequence: 2 givenname: Nathanaël surname: Guigo fullname: Guigo, Nathanaël – sequence: 3 givenname: Ed de orcidid: 0000-0001-5300-4230 surname: Jong fullname: Jong, Ed de – sequence: 4 givenname: Nicolas orcidid: 0000-0002-6031-5448 surname: Sbirrazzuoli fullname: Sbirrazzuoli, Nicolas |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31684112$$D View this record in MEDLINE/PubMed https://hal.science/hal-02460099$$DView record in HAL |
| BookMark | eNptUU1r3DAUFCWh-WiOvRZDL83BydOnrUthWdpuyUKgtGchy_KuUlnaWnZg_31lNinJ0neReJqZ9zRzgU5CDBah9xhuKJVwu4t-3-O5amBv0DmBipaMCjh5cT9DVyk9QC7GhcDVW3RGsagZxuQc3d25YEdnUqFDWyy3to_D1kYfN85oXyyC9vvkUhG7YjnElMq1C79d2BQ_rDajiyEVLhSrqXchvUOnnfbJXj2dl-jX1y8_l6tyff_t-3KxLg1jciy11RW0Vja4gqbmXVu31oqKGMIb0wlgUovGGi7M3G64ZrQh0HENsgUBlF6izwfd3dT0tjU2jIP2aje4Xg97FbVTr1-C26pNfFRC4poxlgWuDwLbI9pqsVZzDwgTAFI-4oz99DRsiH8mm0bVu2Ss9zrYOCVFKCakkljMsh-PoA9xGrKDGcV51uSA5-0_vNz-3_znTDKAHgBmNnywnTJu1LPX-TPOKwxqDl-9Cj-zyiPWs_D_8X8Bwp-w9Q |
| CitedBy_id | crossref_primary_10_1039_D2RE00098A crossref_primary_10_3390_polym12061280 crossref_primary_10_3390_polym14010022 crossref_primary_10_3390_polym14091657 crossref_primary_10_1016_j_polymer_2021_124128 crossref_primary_10_1016_j_biombioe_2025_107840 crossref_primary_10_1016_j_jaap_2023_106275 crossref_primary_10_1007_s13399_024_05677_0 crossref_primary_10_1016_j_carbpol_2023_120733 crossref_primary_10_3390_polym14050943 crossref_primary_10_1007_s00226_025_01688_w crossref_primary_10_3390_polym14051019 crossref_primary_10_1002_mame_202100323 crossref_primary_10_1080_00194506_2024_2449104 crossref_primary_10_3390_polym12112732 crossref_primary_10_1039_D4GC06244B crossref_primary_10_1080_00218464_2023_2300453 crossref_primary_10_1007_s12155_022_10412_6 crossref_primary_10_1016_j_jaap_2022_105605 crossref_primary_10_1515_hf_2024_0006 crossref_primary_10_1016_j_biombioe_2024_107171 crossref_primary_10_1070_RCR5018 crossref_primary_10_3390_polym13030372 |
| Cites_doi | 10.1021/cr300182k 10.1039/C7GC01405H 10.1016/0263-8223(94)90074-4 10.1002/pen.760191503 10.20944/preprints201804.0270.v1 10.3390/su10061795 10.1201/9780203908402 10.1016/j.tca.2013.04.015 10.21914/anziamj.v45i0.924 10.1016/j.tca.2013.08.011 10.1016/S0040-6031(97)00023-3 10.1039/C5GC01938A 10.1039/C7GC03054A 10.1021/ef3007454 10.1002/polc.5070060121 10.3390/molecules24091683 10.1039/C9GC03620B 10.1002/cssc.201802066 10.1021/ma00009a072 10.1002/(SICI)1521-3927(19990701)20:7<387::AID-MARC387>3.0.CO;2-S 10.1039/C4GC01324G 10.1002/app.11378 10.1134/S1070427210020266 10.1016/j.tca.2018.07.019 10.1016/j.tca.2005.09.001 10.1016/j.carbpol.2011.11.088 10.1016/j.cattod.2017.03.008 10.1002/polb.1990.090280107 10.1021/acssuschemeng.8b03971 10.1002/cssc.201801535 10.1021/ma951162w 10.1002/andp.18541670203 10.1002/cssc.201800778 10.1016/j.tca.2011.11.018 10.1016/j.tca.2011.03.034 10.1016/j.compscitech.2018.12.008 10.1002/recl.19380570402 10.1007/BF01975082 10.1021/ef2010157 10.1016/S0169-7439(00)00103-9 10.1002/(SICI)1521-3935(20000201)201:2<199::AID-MACP199>3.0.CO;2-N 10.1002/macp.200700100 10.1021/acssuschemeng.5b00473 10.1002/cssc.201300332 10.1007/978-3-319-14175-6 10.1021/sc500176z 10.1039/tf9373301225 10.1023/A:1010158223347 10.1002/1096-987X(20010130)22:2<178::AID-JCC5>3.0.CO;2-# 10.1023/A:1011082309058 10.1002/cssc.201300446 10.1016/j.tca.2009.01.005 10.1007/BF01983708 10.1002/marc.200600404 10.1039/tf9706600080 10.1016/j.cej.2006.06.008 10.1002/cssc.201801757 10.1002/macp.200350051 |
| ContentType | Journal Article |
| Copyright | 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. licence_http://creativecommons.org/publicdomain/zero 2019 by the authors. 2019 |
| Copyright_xml | – notice: 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. – notice: licence_http://creativecommons.org/publicdomain/zero – notice: 2019 by the authors. 2019 |
| DBID | AAYXX CITATION NPM 7SR 8FD 8FE 8FG ABJCF ABUWG AFKRA AZQEC BENPR BGLVJ CCPQU D1I DWQXO HCIFZ JG9 KB. PDBOC PHGZM PHGZT PIMPY PKEHL PQEST PQGLB PQQKQ PQUKI PRINS 7X8 1XC 5PM |
| DOI | 10.3390/polym11111804 |
| DatabaseName | CrossRef PubMed Engineered Materials Abstracts Technology Research Database ProQuest SciTech Collection ProQuest Technology Collection Materials Science & Engineering Collection ProQuest Central (Alumni) ProQuest Central UK/Ireland ProQuest Central Essentials ProQuest Central Technology collection ProQuest One Community College ProQuest Materials Science Collection ProQuest Central SciTech Premium Collection Materials Research Database Materials Science Database Materials Science Collection ProQuest Central Premium ProQuest One Academic (New) Publicly Available Content Database ProQuest One Academic Middle East (New) ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Applied & Life Sciences ProQuest One Academic (retired) ProQuest One Academic UKI Edition ProQuest Central China MEDLINE - Academic Hyper Article en Ligne (HAL) PubMed Central (Full Participant titles) |
| DatabaseTitle | CrossRef PubMed Publicly Available Content Database Materials Research Database Technology Collection Technology Research Database ProQuest One Academic Middle East (New) ProQuest Central Essentials Materials Science Collection ProQuest Central (Alumni Edition) SciTech Premium Collection ProQuest One Community College ProQuest Central China ProQuest Central ProQuest One Applied & Life Sciences Engineered Materials Abstracts ProQuest Central Korea Materials Science Database ProQuest Central (New) ProQuest Materials Science Collection ProQuest One Academic Eastern Edition ProQuest Technology Collection ProQuest SciTech Collection ProQuest One Academic UKI Edition Materials Science & Engineering Collection ProQuest One Academic ProQuest One Academic (New) MEDLINE - Academic |
| DatabaseTitleList | CrossRef PubMed Publicly Available Content Database MEDLINE - Academic |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: KB. name: Materials Science Database url: http://search.proquest.com/materialsscijournals sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 2073-4360 |
| ExternalDocumentID | PMC6918444 oai:HAL:hal-02460099v1 31684112 10_3390_polym11111804 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: European Commission as part of a H2020 MSCA project named HUGS under the grant agreement #675325. grantid: grant agreement #675325. |
| GroupedDBID | 53G 5VS 8FE 8FG A8Z AADQD AAFWJ AAYXX ABDBF ABJCF ACGFO ACIWK ACUHS ADBBV ADMLS AENEX AFFHD AFKRA AFZYC AIAGR ALMA_UNASSIGNED_HOLDINGS AOIJS BCNDV BENPR BGLVJ CCPQU CITATION CZ9 D1I ESX F5P GX1 HCIFZ HH5 HYE I-F KB. KC. KQ8 ML~ MODMG M~E OK1 PDBOC PGMZT PHGZM PHGZT PIMPY PQGLB PROAC RNS RPM TR2 TUS NPM 7SR 8FD ABUWG AZQEC DWQXO JG9 PKEHL PQEST PQQKQ PQUKI PRINS 7X8 ESTFP PUEGO 1XC C1A IAO IPNFZ ITC RIG 5PM |
| ID | FETCH-LOGICAL-c449t-aea70de9b170b85fd8dee672c25bcf6049a6bec56cee67b5a43b20f5a09d06033 |
| IEDL.DBID | BENPR |
| ISICitedReferencesCount | 29 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000503279200077&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 2073-4360 |
| IngestDate | Tue Nov 04 01:49:38 EST 2025 Wed Nov 19 06:46:32 EST 2025 Fri Sep 05 11:19:09 EDT 2025 Fri Jul 25 11:51:08 EDT 2025 Thu Apr 03 06:55:51 EDT 2025 Tue Nov 18 22:29:48 EST 2025 Sat Nov 29 07:19:12 EST 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 11 |
| Keywords | isoconversional method biobased thermoset kinetics humins lignocellulosic biomass valorization |
| Language | English |
| License | licence_http://creativecommons.org/publicdomain/zero/: http://creativecommons.org/publicdomain/zero Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c449t-aea70de9b170b85fd8dee672c25bcf6049a6bec56cee67b5a43b20f5a09d06033 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 PMCID: PMC6918444 |
| ORCID | 0000-0002-6031-5448 0000-0001-5300-4230 |
| OpenAccessLink | https://www.proquest.com/docview/2550245013?pq-origsite=%requestingapplication% |
| PMID | 31684112 |
| PQID | 2550245013 |
| PQPubID | 2032345 |
| ParticipantIDs | pubmedcentral_primary_oai_pubmedcentral_nih_gov_6918444 hal_primary_oai_HAL_hal_02460099v1 proquest_miscellaneous_2312279164 proquest_journals_2550245013 pubmed_primary_31684112 crossref_citationtrail_10_3390_polym11111804 crossref_primary_10_3390_polym11111804 |
| PublicationCentury | 2000 |
| PublicationDate | 20191102 |
| PublicationDateYYYYMMDD | 2019-11-02 |
| PublicationDate_xml | – month: 11 year: 2019 text: 20191102 day: 2 |
| PublicationDecade | 2010 |
| PublicationPlace | Switzerland |
| PublicationPlace_xml | – name: Switzerland – name: Basel |
| PublicationSeriesTitle | Special issue: Sustainable Bio-Based Polymers: Towards a Circular Bioeconomy |
| PublicationTitle | Polymers |
| PublicationTitleAlternate | Polymers (Basel) |
| PublicationYear | 2019 |
| Publisher | MDPI AG MDPI |
| Publisher_xml | – name: MDPI AG – name: MDPI |
| References | Sbirrazzuoli (ref_48) 2007; 208 Grivel (ref_27) 2012; 529 Tsilomelekis (ref_9) 2016; 18 ref_57 Sangregorio (ref_22) 2019; 171 Rasrendra (ref_2) 2013; 113 Alonso (ref_41) 2006; 122 Hoang (ref_17) 2015; 17 Schweizer (ref_5) 1937; 57 Patil (ref_12) 2012; 26 Sbirrazzuoli (ref_28) 1992; 38 Hoang (ref_16) 2013; 6 ref_61 Sbirrazzuoli (ref_29) 1997; 293 Sbirrazzuoli (ref_31) 2000; 54 Rabinowitch (ref_37) 1937; 33 Roudsari (ref_25) 2014; 2 Granado (ref_60) 2018; 667 Salla (ref_40) 1999; 56 Constant (ref_10) 2017; 5 Kenny (ref_24) 1994; 27 Filiciotto (ref_14) 2017; 19 Chernysheva (ref_21) 2018; 11 ref_23 Chiacchiarelli (ref_26) 2013; 574 Syamaladevi (ref_56) 2012; 88 ref_20 Wang (ref_63) 2005; 439 Vyazovkin (ref_35) 2000; 201 Sumerskii (ref_6) 2010; 83 Williams (ref_53) 1970; 66 Filiciotto (ref_4) 2018; 302 Patil (ref_7) 2011; 25 Muralidhara (ref_19) 2018; 6 Pascault (ref_59) 1990; 28 Sbirrazzuoli (ref_30) 2013; 564 Perez (ref_39) 2009; 487 Vyazovkin (ref_49) 1997; 49 ref_34 ref_33 Yoshioka (ref_55) 2001; 18 Cheng (ref_13) 2018; 20 Vyazovkin (ref_45) 2006; 27 Wang (ref_8) 2013; 6 Tosi (ref_15) 2018; 11 Friedman (ref_47) 1964; 6 Vyazovkin (ref_50) 2001; 22 He (ref_62) 2003; 87 Stolin (ref_36) 1979; 19 Vyazovkin (ref_32) 1996; 29 Anderssen (ref_54) 2004; 45 Cheng (ref_18) 2018; 11 ref_46 Vyazovkin (ref_42) 2011; 520 ref_44 ref_43 Sangregorio (ref_11) 2018; 11 Hale (ref_58) 1991; 24 Sbirrazzuoli (ref_51) 2003; 204 ref_3 Caes (ref_1) 2015; 3 Vyazovkin (ref_38) 1999; 20 Kohlrausch (ref_52) 1854; 167 |
| References_xml | – volume: 113 start-page: 1499 year: 2013 ident: ref_2 article-title: Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources publication-title: Chem. Rev. doi: 10.1021/cr300182k – volume: 19 start-page: 4423 year: 2017 ident: ref_14 article-title: Benign-by-design preparation of humin-based iron oxide catalytic nanocomposites publication-title: Green Chem. doi: 10.1039/C7GC01405H – volume: 27 start-page: 129 year: 1994 ident: ref_24 article-title: Application of modeling to the control and optimization of composites processing publication-title: Compos. Struct. doi: 10.1016/0263-8223(94)90074-4 – volume: 19 start-page: 1074 year: 1979 ident: ref_36 article-title: Non-Isothermal Phenomena in Polymer Engineering and Science: A Review. Part II: Non-Isothermal Phenomena in Polymer Deformation publication-title: Polym. Eng. Sci. doi: 10.1002/pen.760191503 – ident: ref_43 doi: 10.20944/preprints201804.0270.v1 – ident: ref_20 doi: 10.3390/su10061795 – ident: ref_57 doi: 10.1201/9780203908402 – volume: 564 start-page: 59 year: 2013 ident: ref_30 article-title: Determination of pre-exponential factors and of the mathematical functions f(α) or G(α) that describe the reaction mechanism in a model-free way publication-title: Thermochim. Acta doi: 10.1016/j.tca.2013.04.015 – volume: 45 start-page: 800 year: 2004 ident: ref_54 article-title: The Kohlrausch function: properties and applications publication-title: Anziam J. doi: 10.21914/anziamj.v45i0.924 – volume: 574 start-page: 88 year: 2013 ident: ref_26 article-title: Kinetic and chemorheological modeling of the vitrification effect of highly reactive poly(urethane-isocyanurate) thermosets publication-title: Thermochim. Acta doi: 10.1016/j.tca.2013.08.011 – volume: 293 start-page: 25 year: 1997 ident: ref_29 article-title: Simulations for evaluation of kinetic methods in differential scanning calorimetry. Part 3—Peak maximum evolution methods and isoconversional methods publication-title: Thermochim. Acta doi: 10.1016/S0040-6031(97)00023-3 – volume: 18 start-page: 1983 year: 2016 ident: ref_9 article-title: Molecular structure, morphology and growth mechanisms and rates of 5-hydroxymethyl furfural (HMF) derived humins publication-title: Green Chem. doi: 10.1039/C5GC01938A – volume: 20 start-page: 997 year: 2018 ident: ref_13 article-title: Structural analysis of humins formed in the Brønsted acid catalyzed dehydration of fructose publication-title: Green Chem. doi: 10.1039/C7GC03054A – volume: 26 start-page: 5281 year: 2012 ident: ref_12 article-title: Comparison of Structural Features of Humins Formed Catalytically from Glucose, Fructose, and 5-Hydroxymethylfurfuraldehyde publication-title: Energy Fuels doi: 10.1021/ef3007454 – volume: 6 start-page: 183 year: 1964 ident: ref_47 article-title: Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic publication-title: J. Polym. Sci. Part C doi: 10.1002/polc.5070060121 – ident: ref_61 doi: 10.3390/molecules24091683 – ident: ref_23 doi: 10.1039/C9GC03620B – volume: 11 start-page: 4246 year: 2018 ident: ref_11 article-title: Humins from biorefineries as thermo-reactive macromolecular systems publication-title: ChemSusChem doi: 10.1002/cssc.201802066 – volume: 24 start-page: 2610 year: 1991 ident: ref_58 article-title: Glass transition temperature as a function of conversion in thermosetting polymers publication-title: Macromolecules doi: 10.1021/ma00009a072 – volume: 20 start-page: 387 year: 1999 ident: ref_38 article-title: Isoconversional method to explore the mechanism and kinetics of multi-step epoxy cures publication-title: Macromol. Rapid Commun. doi: 10.1002/(SICI)1521-3927(19990701)20:7<387::AID-MARC387>3.0.CO;2-S – volume: 17 start-page: 959 year: 2015 ident: ref_17 article-title: Humin based by-products from biomass processing as a potential carbonaceous source for synthesis gas production publication-title: Green Chem. doi: 10.1039/C4GC01324G – volume: 87 start-page: 433 year: 2003 ident: ref_62 article-title: Model-free kinetics: Curing behavior of phenol formaldehyde resins by differential scanning calorimetry publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.11378 – volume: 83 start-page: 320 year: 2010 ident: ref_6 article-title: Humin-like substances formed under the conditions of industrial hydrolysis of wood publication-title: Russ. J. Appl. Chem. doi: 10.1134/S1070427210020266 – volume: 667 start-page: 185 year: 2018 ident: ref_60 article-title: Kinetic regimes in the curing process of epoxy-phenol composites publication-title: Thermochim. Acta doi: 10.1016/j.tca.2018.07.019 – volume: 439 start-page: 68 year: 2005 ident: ref_63 article-title: Comparison of model-free kinetic methods for modeling the cure kinetics of commercial phenol–formaldehyde resins publication-title: Thermochim. Acta doi: 10.1016/j.tca.2005.09.001 – ident: ref_3 – volume: 88 start-page: 223 year: 2012 ident: ref_56 article-title: Influence of molecular weight on enthalpy relaxation and fragility of amorphous carbohydrates publication-title: Carbohydr. Polym. doi: 10.1016/j.carbpol.2011.11.088 – ident: ref_34 – volume: 302 start-page: 2 year: 2018 ident: ref_4 article-title: Catalytic insights into the production of biomass-derived side products methyl levulinate, furfural and humins publication-title: Catal. Today doi: 10.1016/j.cattod.2017.03.008 – volume: 28 start-page: 85 year: 1990 ident: ref_59 article-title: Glass transition temperature versus conversion relationships for thermosetting polymers publication-title: J. Polym. Sci. Part B Polym. Phys. doi: 10.1002/polb.1990.090280107 – volume: 6 start-page: 16692 year: 2018 ident: ref_19 article-title: Insights on Thermal and Fire Hazards of Humins in Support of Their Sustainable Use in Advanced Biorefineries publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.8b03971 – volume: 11 start-page: 3609 year: 2018 ident: ref_18 article-title: Catalytic Hydrotreatment of Humins to Bio-Oil in Methanol over Supported Metal Catalysts publication-title: ChemSusChem doi: 10.1002/cssc.201801535 – volume: 29 start-page: 1867 year: 1996 ident: ref_32 article-title: Mechanism and Kinetics of Epoxy−Amine Cure Studied by Differential Scanning Calorimetry publication-title: Macromolecules doi: 10.1021/ma951162w – volume: 167 start-page: 179 year: 1854 ident: ref_52 article-title: Theorie des elektrischen Rückstandes in der Leidner Flasche publication-title: Ann. Phys. Chem. doi: 10.1002/andp.18541670203 – volume: 11 start-page: 2797 year: 2018 ident: ref_15 article-title: Auto-crosslinked rigid foams derived from biorefinery by-products publication-title: ChemSusChem doi: 10.1002/cssc.201800778 – volume: 529 start-page: 29 year: 2012 ident: ref_27 article-title: Study on the non-isothermal curing kinetics of a polyfurfuryl alcohol bioresin by DSC using different amounts of catalyst publication-title: Thermochim. Acta doi: 10.1016/j.tca.2011.11.018 – volume: 520 start-page: 1 year: 2011 ident: ref_42 article-title: ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data publication-title: Thermochim. Acta doi: 10.1016/j.tca.2011.03.034 – volume: 5 start-page: 965 year: 2017 ident: ref_10 article-title: Quantification and Classification of Carbonyls in Industrial Humins and Lignins by 19F NMR. ACS Sustain publication-title: Chem. Eng. – volume: 171 start-page: 70 year: 2019 ident: ref_22 article-title: All ‘green’ composites comprising flax fibres and humins’ resins publication-title: Compos. Sci. Technol. doi: 10.1016/j.compscitech.2018.12.008 – volume: 57 start-page: 345 year: 1937 ident: ref_5 article-title: Caramel and humin. A contribution to the knowledge of the decomposition products of sugars publication-title: Rec. Trav. Chim. doi: 10.1002/recl.19380570402 – volume: 38 start-page: 1509 year: 1992 ident: ref_28 article-title: Different kinetic equations analysis publication-title: J. Therm. Anal. Calorim. doi: 10.1007/BF01975082 – volume: 25 start-page: 4745 year: 2011 ident: ref_7 article-title: Formation and Growth of Humins via Aldol Addition and Condensation during Acid-Catalyzed Conversion of 5-Hydroxymethylfurfural publication-title: Energy Fuels doi: 10.1021/ef2010157 – volume: 54 start-page: 53 year: 2000 ident: ref_31 article-title: Comparison of several computational procedures for evaluating the kinetics of thermally stimulated condensed phase reactions publication-title: Chemom. Intell. Lab. Syst. doi: 10.1016/S0169-7439(00)00103-9 – volume: 201 start-page: 199 year: 2000 ident: ref_35 article-title: Effect of viscosity on the kinetics of initial cure stages publication-title: Macromol. Chem. Phys. doi: 10.1002/(SICI)1521-3935(20000201)201:2<199::AID-MACP199>3.0.CO;2-N – volume: 208 start-page: 1592 year: 2007 ident: ref_48 article-title: Is the Friedman method applicable to transformations with temperature dependent reaction heat? publication-title: Macromol. Chem. Phys. doi: 10.1002/macp.200700100 – volume: 3 start-page: 2591 year: 2015 ident: ref_1 article-title: Biomass to Furanics: Renewable Routes to Chemicals and Fuels publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.5b00473 – volume: 6 start-page: 1745 year: 2013 ident: ref_8 article-title: Formation, Molecular Structure, and Morphology of Humins in Biomass Conversion: Influence of Feedstock and Processing Conditions publication-title: ChemSusChem doi: 10.1002/cssc.201300332 – ident: ref_44 doi: 10.1007/978-3-319-14175-6 – volume: 2 start-page: 2111 year: 2014 ident: ref_25 article-title: Study of the Curing Kinetics of Epoxy Resins with Biobased Hardener and Epoxidized Soybean Oil publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/sc500176z – ident: ref_33 – volume: 33 start-page: 1225 year: 1937 ident: ref_37 article-title: Collision, co-ordination, diffusion and reaction velocity in condensed systems publication-title: Trans. Faraday Soc. doi: 10.1039/tf9373301225 – volume: 56 start-page: 771 year: 1999 ident: ref_40 article-title: Thermoset Cure Kinetics by Isoconversional Methods publication-title: J. Therm. Anal. Calorim doi: 10.1023/A:1010158223347 – volume: 22 start-page: 178 year: 2001 ident: ref_50 article-title: Modification of the Integral Isoconversional Method to Account for Variation in the Activation Energy publication-title: J. Comput. Chem. doi: 10.1002/1096-987X(20010130)22:2<178::AID-JCC5>3.0.CO;2-# – volume: 18 start-page: 256 year: 2001 ident: ref_55 article-title: Usefulness of the Kohlrausch-Williams-Watts stretched exponential function to describe protein aggregation in lyophilized formulations and the temperature dependence near the glass transition temperature publication-title: Pharm. Res. doi: 10.1023/A:1011082309058 – ident: ref_46 – volume: 6 start-page: 1651 year: 2013 ident: ref_16 article-title: Valorization of Humin-Based Byproducts from Biomass Processing-A Route to Sustainable Hydrogen publication-title: ChemSusChem doi: 10.1002/cssc.201300446 – volume: 487 start-page: 39 year: 2009 ident: ref_39 article-title: Cure kinetics of lignin–novolac resins studied by isoconversional methods publication-title: Thermochim. Acta doi: 10.1016/j.tca.2009.01.005 – volume: 49 start-page: 1493 year: 1997 ident: ref_49 article-title: Advanced isoconversional method publication-title: J. Therm. Anal. doi: 10.1007/BF01983708 – volume: 27 start-page: 1515 year: 2006 ident: ref_45 article-title: Isoconversional Kinetic Analysis of Thermally Stimulated Processes in Polymers publication-title: Macromol. Rapid Commun. doi: 10.1002/marc.200600404 – volume: 66 start-page: 80 year: 1970 ident: ref_53 article-title: Non-symmetrical dielectric relaxation behavior arising from a simple empirical decay function publication-title: Trans. Faraday Soc. doi: 10.1039/tf9706600080 – volume: 122 start-page: 159 year: 2006 ident: ref_41 article-title: Gelation and isoconversional kinetic analysis of lignin–phenol–formaldehyde resol resins cure publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2006.06.008 – volume: 11 start-page: 3599 year: 2018 ident: ref_21 article-title: Sustainable Utilization of Biomass Refinery Wastes for Accessing Activated Carbons and Supercapacitor Electrode Materials publication-title: ChemSusChem doi: 10.1002/cssc.201801757 – volume: 204 start-page: 1815 year: 2003 ident: ref_51 article-title: A Study of Epoxy-Amine Cure Kinetics by Combining Isoconversional Analysis with Temperature Modulated DSC and Dynamic Rheometry publication-title: Macromol. Chem. Phys. doi: 10.1002/macp.200350051 |
| SSID | ssj0000456617 |
| Score | 2.3394723 |
| Snippet | Humins is a biomass-derived material, co-product of the acid-catalyzed conversion of cellulose and hemicellulose to platform chemicals. This work presents a... |
| SourceID | pubmedcentral hal proquest pubmed crossref |
| SourceType | Open Access Repository Aggregation Database Index Database Enrichment Source |
| StartPage | 1804 |
| SubjectTerms | Acids Chemical reactions Chemical Sciences Conversion Crosslinking Curing Energy Experiments Heat Initiators Kinetics Lignocellulose Material chemistry Mathematical functions Rheology Temperature Temperature effects Viscosity |
| Title | Kinetics and Chemorheological Analysis of Cross-Linking Reactions in Humins |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/31684112 https://www.proquest.com/docview/2550245013 https://www.proquest.com/docview/2312279164 https://hal.science/hal-02460099 https://pubmed.ncbi.nlm.nih.gov/PMC6918444 |
| Volume | 11 |
| WOSCitedRecordID | wos000503279200077&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| journalDatabaseRights | – providerCode: PRVHPJ databaseName: ROAD: Directory of Open Access Scholarly Resources customDbUrl: eissn: 2073-4360 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000456617 issn: 2073-4360 databaseCode: M~E dateStart: 20090101 isFulltext: true titleUrlDefault: https://road.issn.org providerName: ISSN International Centre – providerCode: PRVPQU databaseName: Materials Science Database customDbUrl: eissn: 2073-4360 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000456617 issn: 2073-4360 databaseCode: KB. dateStart: 20090101 isFulltext: true titleUrlDefault: http://search.proquest.com/materialsscijournals providerName: ProQuest – providerCode: PRVPQU databaseName: ProQuest Central (subscription) customDbUrl: eissn: 2073-4360 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000456617 issn: 2073-4360 databaseCode: BENPR dateStart: 20090101 isFulltext: true titleUrlDefault: https://www.proquest.com/central providerName: ProQuest – providerCode: PRVPQU databaseName: Publicly Available Content Database customDbUrl: eissn: 2073-4360 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0000456617 issn: 2073-4360 databaseCode: PIMPY dateStart: 20090101 isFulltext: true titleUrlDefault: http://search.proquest.com/publiccontent providerName: ProQuest |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1bb9MwFD6iGxK8cIcFxmQQ4okwp3Hs-Alt1aahjqqaQCpPkWM7aqUtKU03iX_POc0FCoIXHn1R4vic2N_x5fsA3sQiUQZtG5rEpaEwMgm1ISLXyMtU6VRKZTdiE2oySWczPW0X3Or2WGU3Jm4GaldZWiM_ROhLu4SIWD4sv4WkGkW7q62ExgB2iakM_Xz3-GQyvehXWQiw4BzdkGvGGN8fLqvL71c0TkRpK87WTUaDOR2F_BNn_n5c8pf55_T-_7b8AdxrkSc7alzlIdzy5SO4M-oE3x7DeIyIk1ibmSkdo4JqNffd4Mg6-hJWFWxEnxOeN7oL7MI3tyNqtigZ-seirJ_Al9OTz6OzsNVaCK0Qeh0abxR3XueR4nmaFC513ks1tMMkt4XEOMJINHciLWXniRFxPuRFYrh2XPI4fgo7ZVX6PWBcxzLlueCFdcTdozU-riiMciK3StkA3nWdntmWiJz0MC4zDEjIRtmWjQJ421dfNgwcf6v4Gi3Y1yHe7LOj84zysP8lYeGbKID9zkhZ-7fW2U8LBfCqL8bep80TU_rqGuvEEZEtYnQZwLPGH_pXkfiXQOAagNrylK22bJeUi_mGy1tqDLGFeP7vZr2AuwjU9OYO5HAfdtara_8Sbtub9aJeHcBAzdKD1vUxNT5-j6npx0_Trz8AbkkRAg |
| linkProvider | ProQuest |
| linkToHtml | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V1bb9MwGP00OqTxwh0WGGAQ8ES0XBw7fkBoKkyt2lUVGtJ4Co7jqJVG0jXd0P4Uv5Hvay5QELztgVfbysU-_nx8OwfgZcgjqbFtXR1lscu1iFylScjVtyKWKhZCmrXZhJxM4pMTNd2C7-1dGDpW2cbEdaDOSkNr5PtIfWmXEBnLu8WZS65RtLvaWmjUsBjZy284ZaveDt9j-74KgsMPx_2B27gKuIZztXK11dLLrEp96aVxlGdxZq2QgQmi1OQCGbMW-GORMJScRpqHaeDlkfZU5gmPFkAx5G9zAnsPtqfDo-nnblWHCBJyglrMMwyVt78oTy-_Ulzy48YMrh38rs3o6OWfvPb345m_jHeHt_63mroNNxtmzQ7qrnAHtmxxF3b6raHdPRiNkFGTKjXTRcYoo1zObBv8WSvPwsqc9an63HHtK8E-2vr2R8XmBUP8z4vqPny6kn95AL2iLOwuME-FIvZS7uUmI20ipfBxea5lxlMjpXHgTdvIiWmE1snv4zTBCRdhItnAhAOvu-KLWmHkbwVfIGK6MqQLPjgYJ5SG7S2I61_4Duy1oEiaaFQlPxHhwPMuG2ufNod0YctzLBP6JCaJs2cHHtb4615F5mYcibkDcgOZG9-ymVPMZ2utcqH8mHP-6N-f9Qx2BsdH42Q8nIweww0kpWp93zPYg95qeW6fwHVzsZpXy6dNh2Pw5aqR-wM7mW0c |
| linkToPdf | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V3LjtMwFL0aOgjY8H4EBjAIWBE1D8eOFwiNOlRTtVQVAmlmFRzHUSsNSWk6g-bX-DrubR5QEOxmwda28rCPr49f5wC8CHkkNbatq6MsdrkWkas0Cbn6VsRSxUJIszGbkNNpfHSkZjvwvb0LQ8cq25i4CdRZaWiNvI_Ul3YJkbH08-ZYxOxg-Hb51SUHKdppbe00aoiM7fk3nL5Vb0YH2NYvg2D47uPg0G0cBlzDuVq72mrpZValvvTSOMqzOLNWyMAEUWpygexZC_zJSBhKTiPNwzTw8kh7KvOER4uhGP53kZLzoAe7s9H72XG3wkNkCflBLewZhsrrL8uT8y8Uo_y4MYZrB8JLczqG-SfH_f2o5i9j3_DG_1xrN-F6w7jZft1FbsGOLW7D1UFrdHcHxmNk2qRWzXSRMcooV3PbDgqslW1hZc4GVJXupPabYB9sfSukYouCYb9YFNVd-HQh_3IPekVZ2AfAPBWK2Eu5l5uMNIuUwsfluZYZT42UxoHXbYMnphFgJx-QkwQnYoSPZAsfDrzqii9r5ZG_FXyO6OnKkF744f4koTRse0FzgDPfgb0WIEkTparkJzoceNZlY-3TppEubHmKZUKfRCZxVu3A_RqL3avI9IwjYXdAbqF061u2c4rFfKNhLpQfc84f_vuznsIVhGsyGU3Hj-AaclW1uQYa7EFvvTq1j-GyOVsvqtWTpu8x-HzRwP0BdVJ13A |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Kinetics+and+Chemorheological+Analysis+of+Cross-Linking+Reactions+in+Humins&rft.jtitle=Polymers&rft.au=Sangregorio%2C+Anna&rft.au=Guigo%2C+Nathana%C3%ABl&rft.au=Jong%2C+Ed+de&rft.au=Sbirrazzuoli%2C+Nicolas&rft.date=2019-11-02&rft.eissn=2073-4360&rft.volume=11&rft.issue=11&rft_id=info:doi/10.3390%2Fpolym11111804&rft_id=info%3Apmid%2F31684112&rft.externalDocID=31684112 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2073-4360&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2073-4360&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2073-4360&client=summon |