High-Resolution Single-Turnover Mapping Reveals Intraparticle Diffusion Limitation in Ti-MCM-41-Catalyzed Epoxidation
Shedding light on catalysis: For the first time, transport phenomena and their influence on catalysis are directly observed for individual catalytic particles by single‐turnover mapping using high‐resolution fluorescence microscopy. The Thiele modulus could be measured with just one experiment, prov...
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| Published in: | Angewandte Chemie International Edition Vol. 49; no. 5; pp. 908 - 911 |
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| Main Authors: | , , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH Verlag
25.01.2010
WILEY-VCH Verlag WILEY‐VCH Verlag Wiley |
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| ISSN: | 1433-7851, 1521-3773, 1521-3773 |
| Online Access: | Get full text |
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| Abstract | Shedding light on catalysis: For the first time, transport phenomena and their influence on catalysis are directly observed for individual catalytic particles by single‐turnover mapping using high‐resolution fluorescence microscopy. The Thiele modulus could be measured with just one experiment, proving the existence of diffusional limitations for the Ti‐MCM‐41 catalyzed epoxidation of a fluorescent reporter molecule (see picture; TBHP=tert‐butylhydroperoxide). |
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| AbstractList | Shedding light on catalysis: For the first time, transport phenomena and their influence on catalysis are directly observed for individual catalytic particles by single‐turnover mapping using high‐resolution fluorescence microscopy. The Thiele modulus could be measured with just one experiment, proving the existence of diffusional limitations for the Ti‐MCM‐41 catalyzed epoxidation of a fluorescent reporter molecule (see picture; TBHP=tert‐butylhydroperoxide). |
| Author | Roeffaers, Maarten B. J. Sels, Bert F. Bartholomeeusen, Evelyne Lin, Kaifeng Hofkens, Johan Pescarmona, Paolo P. Dedecker, Peter De Cremer, Gert Jacobs, Pierre A. De Vos, Dirk E. |
| Author_xml | – sequence: 1 fullname: De Cremer, Gert – sequence: 2 fullname: Roeffaers, Maarten B.J – sequence: 3 fullname: Bartholomeeusen, Evelyne – sequence: 4 fullname: Lin, Kaifeng – sequence: 5 fullname: Dedecker, Peter – sequence: 6 fullname: Pescarmona, Paolo P – sequence: 7 fullname: Jacobs, Pierre A – sequence: 8 fullname: De Vos, Dirk E – sequence: 9 fullname: Hofkens, Johan – sequence: 10 fullname: Sels, Bert F |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/20029861$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Keywords | LOCALIZATION diffusion SELECTIVE OXIDATION heterogeneous catalysis MOLECULE FLUORESCENCE SPECTROSCOPY MICROSCOPY MESOPOROUS MATERIALS fluorescent probes single-molecule studies PROBES epoxidation INTRACRYSTALLINE DIFFUSION TI-MCM-41 NANOPARTICLES CRYSTALS CATALYTIC-ACTIVITY |
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| Notes | http://dx.doi.org/10.1002/anie.200905039 ark:/67375/WNG-5XJB898Q-M ArticleID:ANIE200905039 FWO (Fonds voor Wetenschappelijk Onderzoek) G.D.C., P.D., and M.B.J.R. thank the FWO (Fonds voor Wetenschappelijk Onderzoek) for two doctoral fellowships and a postdoctoral fellowship, respectively. This work was performed within the framework of the IAP-VI program "Supramolecular Chemistry and Catalysis" of the Belgian Federal government and of GOA-2/01. We also gratefully acknowledge financial support from a long-term structural funding "Methusalem" by the Flemish government and from K.U. Leuven in the framework of the Centre of Excellence CECAT. istex:3AE58AE2A4883EC9E0C9B93B831B2201D02C27C7 G.D.C., P.D., and M.B.J.R. thank the FWO (Fonds voor Wetenschappelijk Onderzoek) for two doctoral fellowships and a postdoctoral fellowship, respectively. This work was performed within the framework of the IAP‐VI program “Supramolecular Chemistry and Catalysis” of the Belgian Federal government and of GOA‐2/01. We also gratefully acknowledge financial support from a long‐term structural funding “Methusalem” by the Flemish government and from K.U. Leuven in the framework of the Centre of Excellence CECAT. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| SubjectTerms | Boron Compounds - chemistry Catalysis Chemistry Chemistry, Multidisciplinary Diffusion epoxidation Fluorescent Dyes - chemistry fluorescent probes heterogeneous catalysis Microscopy, Fluorescence Peroxides - chemistry Physical Sciences Science & Technology Silicon Dioxide - chemistry single-molecule studies Titanium - chemistry |
| Title | High-Resolution Single-Turnover Mapping Reveals Intraparticle Diffusion Limitation in Ti-MCM-41-Catalyzed Epoxidation |
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