Mechanism of visible-light photoisomerization of a rhenium(I) carbonyl-diimine complex
The mechanism of photoisomerization of a Re(I) carbonyl-diimine complex under visible-light irradiation is deciphered by means of ab initio calculations. By highlighting the key role of triplet states as well as spin-orbit and vibronic couplings, we provide a clear picture of this complicated multi-...
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| Vydané v: | Chemical communications (Cambridge, England) Ročník 46; číslo 43; s. 8225 |
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| Hlavní autori: | , , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
England
21.11.2010
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| ISSN: | 1364-548X, 1364-548X |
| On-line prístup: | Zistit podrobnosti o prístupe |
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| Shrnutí: | The mechanism of photoisomerization of a Re(I) carbonyl-diimine complex under visible-light irradiation is deciphered by means of ab initio calculations. By highlighting the key role of triplet states as well as spin-orbit and vibronic couplings, we provide a clear picture of this complicated multi-step process. |
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| Bibliografia: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ISSN: | 1364-548X 1364-548X |
| DOI: | 10.1039/c0cc02661a |