When microplastics/plastics meet metal-organic frameworks: turning threats into opportunities

Significant efforts have been devoted to removal and recycling of microplastics (MPs; <5 mm) to address the environmental crises caused by their ubiquitous presence and improper treatment. Metal-organic frameworks (MOFs) demonstrate compatibility with MPs/plastics through adsorption, degradation,...

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Vydáno v:Chemical science (Cambridge) Ročník 15; číslo 43; s. 17781 - 17798
Hlavní autoři: Wu, Pengfei, Guo, Mengting, Zhang, Ran-Wei, Huang, Qing, Wang, Guibin, Lan, Ya-Qian
Médium: Journal Article
Jazyk:angličtina
Vydáno: England Royal Society of Chemistry 08.10.2024
The Royal Society of Chemistry
Témata:
Adsorption
Biochemical fuel cells
Chemical bonds
Chemistry
Glycolysis
Hydrophobicity
Interdisciplinary studies
Ligands
Metal-organic frameworks
Microorganisms
Particulate composites
Photocatalysis
Plastic pollution
Polymers
Scintillation counters
Threat evaluation
Van der Waals forces
ISSN:2041-6520, 2041-6539
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Shrnutí:Significant efforts have been devoted to removal and recycling of microplastics (MPs; <5 mm) to address the environmental crises caused by their ubiquitous presence and improper treatment. Metal-organic frameworks (MOFs) demonstrate compatibility with MPs/plastics through adsorption, degradation, or assembly with the MPs/plastic polymers. Above 90% of MPs/plastic particles can be adsorbed on MOF materials via the hydrophobic interaction, electrical attraction, π-π stacking, and van der Waals forces. Meanwhile, certain MOFs have successfully converted various types of plastics into high-valued small molecules through thermocatalysis and photocatalysis. In thermocatalysis, the primary process should be C-O bond cleavage, whereas in photocatalysis it ought to be the generation of reactive oxygen species (ROS). Moreover, the construction of novel MOFs using waste MPs/plastics as the ligands was mostly accomplished through three dominant ways, including glycolysis, hydrolysis and methanolysis. Once successfully composited, the MOF@plastic materials illustrated tremendous promise for interdisciplinary research in multifunctional applications, including sewage treatment, gas adsorption/separation, and the preparation of microbial fuel cells, plastic scintillators and other sensors. The review explicated the relationships between MPs/plastics and MOF materials, as well as the challenges and perspectives for their development. It can provide a deeper understanding of how MOFs remove/degrade MP/plastic particles, how MPs/plastics are recycled to prepare MOFs, and how to build multifunctional MOF@plastic composites. Overall, this analysis is anticipated to outline future prospects for turning the threats (MPs/plastics contamination) into opportunities ( e.g. , as ligands to prepare MOF or MOF@plastic materials for further applications). The study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.
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These authors contributed equally to the work.
ISSN:2041-6520
2041-6539
DOI:10.1039/d4sc05205f