Tunable Endo/Exo Selectivity in Direct Catalytic Asymmetric 1,3‐Dipolar Cycloadditions with Polyfunctional Lewis Acid / Azolium–Aryloxide Catalysts

Catalytic asymmetric 1,3‐dipolar cycloadditions (1,3‐DCA) using iminoesters as ylide precursors offer a powerful approach to accessing stereochemically complex, biologically relevant pyrrolidines. Although previous studies have already achieved impressive stereoselectivities, catalytic productivity...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 64; no. 34; pp. e202508024 - n/a
Main Authors:	Bürstner, Adrian, Becker, Patrick M., Allgaier, Alexander, Pfitzer, Lucca, Wanner, Daniel M., Dollinger, Johanna, Willig, Felix, Herrmann, Justin, Miskov‐Pajic, Vukoslava, Hans, Andreas C., Frey, Wolfgang, Slageren, Joris, Kästner, Johannes, Peters, René
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 18.08.2025 John Wiley and Sons Inc
Edition:	International ed. in English
Subjects:	3‐dipolar cycloadditions Asymmetric catalysis Asymmetry Catalysts Cycloaddition DFT Hydrogen bonding Lewis acid Polyfunctional catalysis Productivity Pyrrolidines Selectivity Stereoselectivity Pyrrolidines DFT 3‐dipolar cycloadditions Asymmetric catalysis Polyfunctional catalysis
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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