N-Based Polydentate Ligands and Corresponding Zn(II) Complexes: A Structural and Spectroscopic Study

Herein, the structural and photophysical features of two N-based polydentate ligands and the corresponding Zn(II) complexes are investigated. The obtained compounds were characterized using different spectroscopic techniques and their optical properties are discussed in relation to their chemical st...

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Vydáno v:Inorganics Ročník 11; číslo 11; s. 435
Hlavní autoři: Volpi, Giorgio, Zago, Stefano, Rabezzana, Roberto, Diana, Eliano, Priola, Emanuele, Garino, Claudio, Gobetto, Roberto
Médium: Journal Article
Jazyk:angličtina
Vydáno: Basel MDPI AG 01.11.2023
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ISSN:2304-6740, 2304-6740
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Abstract Herein, the structural and photophysical features of two N-based polydentate ligands and the corresponding Zn(II) complexes are investigated. The obtained compounds were characterized using different spectroscopic techniques and their optical properties are discussed in relation to their chemical structure, defined by single-crystal X-ray diffraction and mass spectrometry. The spontaneous and quantitative complexation, investigated by UV-Vis, fluorescence, NMR, IR spectroscopies and mass spectrometry, makes these N-based polydentate ligands interesting candidates for possible applications in chelation therapy and in Zn(II) sensors.
AbstractList Herein, the structural and photophysical features of two N-based polydentate ligands and the corresponding Zn(II) complexes are investigated. The obtained compounds were characterized using different spectroscopic techniques and their optical properties are discussed in relation to their chemical structure, defined by single-crystal X-ray diffraction and mass spectrometry. The spontaneous and quantitative complexation, investigated by UV-Vis, fluorescence, NMR, IR spectroscopies and mass spectrometry, makes these N-based polydentate ligands interesting candidates for possible applications in chelation therapy and in Zn(II) sensors.
Audience Academic
Author Priola, Emanuele
Zago, Stefano
Rabezzana, Roberto
Diana, Eliano
Volpi, Giorgio
Gobetto, Roberto
Garino, Claudio
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  surname: Gobetto
  fullname: Gobetto, Roberto
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CitedBy_id crossref_primary_10_1016_j_molstruc_2025_143609
crossref_primary_10_1016_j_ica_2025_122914
crossref_primary_10_3390_molecules29112668
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Snippet Herein, the structural and photophysical features of two N-based polydentate ligands and the corresponding Zn(II) complexes are investigated. The obtained...
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SubjectTerms Asymmetry
Chelation
chelation therapy
Coordination compounds
Diffraction
Drugs
Ligands
Mass spectrometry
Mass spectroscopy
Mechanical properties
NMR
Nuclear magnetic resonance
Nuclear magnetic resonance spectroscopy
Optical properties
polydentate ligand
Single crystals
Spectrum analysis
Structure
Symmetry
X-ray diffraction
X-rays
Zinc
Zn(II) sensor
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Title N-Based Polydentate Ligands and Corresponding Zn(II) Complexes: A Structural and Spectroscopic Study
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