N-Based Polydentate Ligands and Corresponding Zn(II) Complexes: A Structural and Spectroscopic Study

Herein, the structural and photophysical features of two N-based polydentate ligands and the corresponding Zn(II) complexes are investigated. The obtained compounds were characterized using different spectroscopic techniques and their optical properties are discussed in relation to their chemical st...

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Bibliographic Details
Published in:Inorganics Vol. 11; no. 11; p. 435
Main Authors: Volpi, Giorgio, Zago, Stefano, Rabezzana, Roberto, Diana, Eliano, Priola, Emanuele, Garino, Claudio, Gobetto, Roberto
Format: Journal Article
Language:English
Published: Basel MDPI AG 01.11.2023
Subjects:
Asymmetry
Chelation
chelation therapy
Coordination compounds
Diffraction
Drugs
Ligands
Mass spectrometry
Mass spectroscopy
Mechanical properties
NMR
Nuclear magnetic resonance
Nuclear magnetic resonance spectroscopy
Optical properties
polydentate ligand
Single crystals
Spectrum analysis
Structure
Symmetry
X-ray diffraction
X-rays
Zinc
Zn(II) sensor
Italy
ISSN:2304-6740, 2304-6740
Online Access:Get full text
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Summary:Herein, the structural and photophysical features of two N-based polydentate ligands and the corresponding Zn(II) complexes are investigated. The obtained compounds were characterized using different spectroscopic techniques and their optical properties are discussed in relation to their chemical structure, defined by single-crystal X-ray diffraction and mass spectrometry. The spontaneous and quantitative complexation, investigated by UV-Vis, fluorescence, NMR, IR spectroscopies and mass spectrometry, makes these N-based polydentate ligands interesting candidates for possible applications in chelation therapy and in Zn(II) sensors.
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ISSN:2304-6740
2304-6740
DOI:10.3390/inorganics11110435