Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity

A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO syste...

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Bibliographic Details
Published in:	Chemical communications (Cambridge, England) Vol. 51; no. 63; p. 12578
Main Authors:	Lammert, Martin, Wharmby, Michael T, Smolders, Simon, Bueken, Bart, Lieb, Alexandra, Lomachenko, Kirill A, Vos, Dirk De, Stock, Norbert
Format:	Journal Article
Language:	English
Published:	England 14.08.2015
ISSN:	1364-548X, 1364-548X
Online Access:	Get more information
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Summary:	A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO system was successfully employed for the aerobic oxidation of benzyl alcohol.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1364-548X 1364-548X
DOI:	10.1039/c5cc02606g