Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity

A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO syste...

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Vydané v:Chemical communications (Cambridge, England) Ročník 51; číslo 63; s. 12578
Hlavní autori: Lammert, Martin, Wharmby, Michael T, Smolders, Simon, Bueken, Bart, Lieb, Alexandra, Lomachenko, Kirill A, Vos, Dirk De, Stock, Norbert
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: England 14.08.2015
ISSN:1364-548X, 1364-548X
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Shrnutí:A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO system was successfully employed for the aerobic oxidation of benzyl alcohol.
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ISSN:1364-548X
1364-548X
DOI:10.1039/c5cc02606g