Radical Brook Rearrangements: Concept and Recent Developments
The Brook rearrangement has already become established as one of the most important molecular rearrangements in synthetic chemistry and has been applied in the generation of complexes, drug discovery, material science, and natural products synthesis. Compared to the widely known ionic mechanism, the...
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| Veröffentlicht in: | Angewandte Chemie International Edition Jg. 61; H. 37; S. e202205671 - n/a |
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| Format: | Journal Article |
| Sprache: | Englisch |
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Wiley Subscription Services, Inc
12.09.2022
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| Ausgabe: | International ed. in English |
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| ISSN: | 1433-7851, 1521-3773, 1521-3773 |
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| Abstract | The Brook rearrangement has already become established as one of the most important molecular rearrangements in synthetic chemistry and has been applied in the generation of complexes, drug discovery, material science, and natural products synthesis. Compared to the widely known ionic mechanism, the radical Brook rearrangement is less explored because of the difficulty in generating alkoxyl radical species. This Minireview summarizes the early developments and general concept of the radical Brook rearrangement and highlights recent advances in photocatalytic reactions and transition‐metal‐catalyzed cross‐coupling reactions involving radical Brook rearrangements. We hope this survey will inspire further developments in this emerging area.
The radical Brook rearrangement is a unique molecular arrangement, but it is not highly explored in synthetic chemistry. This Minireview summarizes the early developments and general concept of radical Brook rearrangements and highlights the recent advances in photocatalytic reactions and transition‐metal catalyzed cross‐coupling reactions involving radical Brook rearrangements. |
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| AbstractList | The Brook rearrangement has already become established as one of the most important molecular rearrangements in synthetic chemistry and has been applied in the generation of complexes, drug discovery, material science, and natural products synthesis. Compared to the widely known ionic mechanism, the radical Brook rearrangement is less explored because of the difficulty in generating alkoxyl radical species. This Minireview summarizes the early developments and general concept of the radical Brook rearrangement and highlights recent advances in photocatalytic reactions and transition‐metal‐catalyzed cross‐coupling reactions involving radical Brook rearrangements. We hope this survey will inspire further developments in this emerging area. The Brook rearrangement has already become established as one of the most important molecular rearrangements in synthetic chemistry and has been applied in the generation of complexes, drug discovery, material science, and natural products synthesis. Compared to the widely known ionic mechanism, the radical Brook rearrangement is less explored because of the difficulty in generating alkoxyl radical species. This Minireview summarizes the early developments and general concept of the radical Brook rearrangement and highlights recent advances in photocatalytic reactions and transition‐metal‐catalyzed cross‐coupling reactions involving radical Brook rearrangements. We hope this survey will inspire further developments in this emerging area. The radical Brook rearrangement is a unique molecular arrangement, but it is not highly explored in synthetic chemistry. This Minireview summarizes the early developments and general concept of radical Brook rearrangements and highlights the recent advances in photocatalytic reactions and transition‐metal catalyzed cross‐coupling reactions involving radical Brook rearrangements. The Brook rearrangement has already become established as one of the most important molecular rearrangements in synthetic chemistry and has been applied in the generation of complexes, drug discovery, material science, and natural products synthesis. Compared to the widely known ionic mechanism, the radical Brook rearrangement is less explored because of the difficulty in generating alkoxyl radical species. This Minireview summarizes the early developments and general concept of the radical Brook rearrangement and highlights recent advances in photocatalytic reactions and transition-metal-catalyzed cross-coupling reactions involving radical Brook rearrangements. We hope this survey will inspire further developments in this emerging area.The Brook rearrangement has already become established as one of the most important molecular rearrangements in synthetic chemistry and has been applied in the generation of complexes, drug discovery, material science, and natural products synthesis. Compared to the widely known ionic mechanism, the radical Brook rearrangement is less explored because of the difficulty in generating alkoxyl radical species. This Minireview summarizes the early developments and general concept of the radical Brook rearrangement and highlights recent advances in photocatalytic reactions and transition-metal-catalyzed cross-coupling reactions involving radical Brook rearrangements. We hope this survey will inspire further developments in this emerging area. |
| Author | Huang, Huan‐Ming Zhang, Ying Chen, Jun‐Jie |
| Author_xml | – sequence: 1 givenname: Ying surname: Zhang fullname: Zhang, Ying organization: ShanghaiTech University – sequence: 2 givenname: Jun‐Jie surname: Chen fullname: Chen, Jun‐Jie organization: ShanghaiTech University – sequence: 3 givenname: Huan‐Ming orcidid: 0000-0001-9461-6508 surname: Huang fullname: Huang, Huan‐Ming email: huanghm@shanghaitech.edu.cn organization: ShanghaiTech University |
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| SubjectTerms | Brook Rearrangement Chemical reactions Cross coupling Cross-Coupling Reactions Natural products Photoredox Chemistry Radicals Transition-Metal Catalysis |
| Title | Radical Brook Rearrangements: Concept and Recent Developments |
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