Electrochemical synthesis of thin HKUST-1 layers on copper mesh

[Display omitted] ► HKUST-1 metal organic framework layers were grown on a porous support. ► Control over electrochemical synthesis parameters is needed to avoid structural damage. ► Crystal size strongly depends on water content of synthesis mixture. Metal-organic framework HKUST-1 was synthesized...

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Veröffentlicht in:Microporous and mesoporous materials Jg. 158; S. 209 - 213
Hauptverfasser: Van Assche, Tom R.C., Desmet, Gert, Ameloot, Rob, De Vos, Dirk E., Terryn, Herman, Denayer, Joeri F.M.
Format: Journal Article
Sprache:Englisch
Veröffentlicht: San Diego, CA Elsevier Inc 01.08.2012
Elsevier
Schlagworte:
Chemistry
Colloidal state and disperse state
Electrochemical synthesis
Electrochemistry
Exact sciences and technology
General and physical chemistry
HKUST-1
Mesh
Porous materials
Mesh
HKUST-1
Electrochemical synthesis
Metal organic framework
Synthesis
Support
Crystals
Water content
Electrochemistry
Transition metal
Copper
Porous material
ISSN:1387-1811, 1873-3093
Online-Zugang:Volltext
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Zusammenfassung:[Display omitted] ► HKUST-1 metal organic framework layers were grown on a porous support. ► Control over electrochemical synthesis parameters is needed to avoid structural damage. ► Crystal size strongly depends on water content of synthesis mixture. Metal-organic framework HKUST-1 was synthesized on a porous copper mesh using an electrochemical synthesis technique. By partially oxidizing the mesh in a controllable manner, thin crystal layers could be synthesized without structurally damaging the supporting mesh. Good control over the crystal size could be obtained by varying the water content of the synthesis mixture. This technique allows the formation of crystal layers overgrowing the porous copper support at mild temperatures and short synthesis times.
ISSN:1387-1811
1873-3093
DOI:10.1016/j.micromeso.2012.03.029