Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2′-bipyridine and 1,10-phenanthroline complexes
Electronic absorption spectra of one-electron reduced and MLCT excited states of metal α-diimine complexes in the UV region are similar in appearance and a predominantly IL origin, whereas the visible absorption bands are of a different nature, mostly IL and LMCT, respectively. [Display omitted] ► R...
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| Vydané v: | Inorganica Chimica Acta Ročník 374; číslo 1; s. 578 - 585 |
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| Jazyk: | English |
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Elsevier B.V
01.08.2011
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| ISSN: | 0020-1693, 1873-3255 |
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| Abstract | Electronic absorption spectra of one-electron reduced and MLCT excited states of metal α-diimine complexes in the UV region are similar in appearance and a predominantly IL origin, whereas the visible absorption bands are of a different nature, mostly IL and LMCT, respectively. [Display omitted]
► Reduced and excited-state UV absorption spectra of diimine complexes are similar. ► Spectral similarities in the visible spectral region are largely coincidental. ► UV transitions of reduced and excited states have at least 50% IL character. ► Visible transitions are predominantly IL and LMCT for reduced and excited states, resp. ► Overlap of reduced- and excited-state spectra complicates electron transfer studies.
UV–Vis absorption spectra of one-electron reduction products and 3MLCT excited states of [ReICl(CO)3(N,N)] (N,N=2,2′-bipyridine, bpy; 1,10-phenanthroline, phen) have been measured by low-temperature spectroelectrochemistry and UV–Vis transient absorption spectroscopy, respectively, and assigned by open-shell TD-DFT calculations. The characters of the electronic transitions are visualized and analyzed using electron density redistribution maps. It follows that reduced and excited states can be approximately formulated as [ReICl(CO)3(N,N−)]− and ∗[ReIICl(CO)3(N,N−)], respectively. UV–Vis spectra of the reduced complexes are dominated by IL transitions, plus weaker MLCT contributions. Excited-state spectra show an intense band in the UV region of ∼50% IL origin mixed with LMCT (bpy, 373nm) or MLCT (phen, 307nm) excitations. Because of the significant IL contribution, this spectral feature is akin to the principal IL band of the anions. In contrast, the excited-state visible spectral pattern arises from predominantly LMCT transitions, any resemblance with the reduced-state visible spectra being coincidental. The Re complexes studied herein are representatives of a broad class of metal α-diimines, for which similar spectroscopic behavior can be expected. |
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| AbstractList | Electronic absorption spectra of one-electron reduced and MLCT excited states of metal α-diimine complexes in the UV region are similar in appearance and a predominantly IL origin, whereas the visible absorption bands are of a different nature, mostly IL and LMCT, respectively. [Display omitted]
► Reduced and excited-state UV absorption spectra of diimine complexes are similar. ► Spectral similarities in the visible spectral region are largely coincidental. ► UV transitions of reduced and excited states have at least 50% IL character. ► Visible transitions are predominantly IL and LMCT for reduced and excited states, resp. ► Overlap of reduced- and excited-state spectra complicates electron transfer studies.
UV–Vis absorption spectra of one-electron reduction products and 3MLCT excited states of [ReICl(CO)3(N,N)] (N,N=2,2′-bipyridine, bpy; 1,10-phenanthroline, phen) have been measured by low-temperature spectroelectrochemistry and UV–Vis transient absorption spectroscopy, respectively, and assigned by open-shell TD-DFT calculations. The characters of the electronic transitions are visualized and analyzed using electron density redistribution maps. It follows that reduced and excited states can be approximately formulated as [ReICl(CO)3(N,N−)]− and ∗[ReIICl(CO)3(N,N−)], respectively. UV–Vis spectra of the reduced complexes are dominated by IL transitions, plus weaker MLCT contributions. Excited-state spectra show an intense band in the UV region of ∼50% IL origin mixed with LMCT (bpy, 373nm) or MLCT (phen, 307nm) excitations. Because of the significant IL contribution, this spectral feature is akin to the principal IL band of the anions. In contrast, the excited-state visible spectral pattern arises from predominantly LMCT transitions, any resemblance with the reduced-state visible spectra being coincidental. The Re complexes studied herein are representatives of a broad class of metal α-diimines, for which similar spectroscopic behavior can be expected. |
| Author | Záliš, Stanislav Nahhas, Amal El Chergui, Majed Hartl, František Cannizzo, Andrea Consani, Cristina Vlček, Antonín |
| Author_xml | – sequence: 1 givenname: Stanislav surname: Záliš fullname: Záliš, Stanislav email: zalis@jh-inst.cas.cz organization: J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, CZ-182 23 Prague, Czech Republic – sequence: 2 givenname: Cristina surname: Consani fullname: Consani, Cristina organization: Laboratoire de Spectroscopie Ultrarapide, ISIC, FSB-BSP, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne-Dorigny, Switzerland – sequence: 3 givenname: Amal El surname: Nahhas fullname: Nahhas, Amal El organization: Laboratoire de Spectroscopie Ultrarapide, ISIC, FSB-BSP, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne-Dorigny, Switzerland – sequence: 4 givenname: Andrea surname: Cannizzo fullname: Cannizzo, Andrea organization: Laboratoire de Spectroscopie Ultrarapide, ISIC, FSB-BSP, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne-Dorigny, Switzerland – sequence: 5 givenname: Majed surname: Chergui fullname: Chergui, Majed email: Majed.Chergui@epfl.ch organization: Laboratoire de Spectroscopie Ultrarapide, ISIC, FSB-BSP, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne-Dorigny, Switzerland – sequence: 6 givenname: František surname: Hartl fullname: Hartl, František email: f.hartl@reading.ac.uk organization: Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, United Kingdom – sequence: 7 givenname: Antonín surname: Vlček fullname: Vlček, Antonín email: a.vlcek@qmul.ac.uk organization: J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, CZ-182 23 Prague, Czech Republic |
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| Cites_doi | 10.1021/ic0614768 10.1063/1.478522 10.1021/ic961328p 10.1039/DT9930002977 10.1021/jp101999m 10.1039/C39800000261 10.1021/ja00053a029 10.1021/ja00324a057 10.1016/0010-8545(85)80042-4 10.1021/jp9927754 10.1529/biophysj.103.036236 10.1021/ic102324p 10.1135/cccc20031687 10.1039/dt9910000849 10.1021/ja00415a007 10.1021/ar030111d 10.1016/0009-2614(81)85323-7 10.1021/ja00509a066 10.1021/ja00811a008 10.1021/ic9601091 10.1002/chem.200500482 10.1021/ja00486a033 10.1021/jp037096e 10.1021/ja00342a077 10.1366/0003702944027787 10.1002/9783527618248.ch28 10.1021/ic9509802 10.1021/ic011015g 10.1016/S0010-8545(98)00132-5 10.1021/ic00335a031 10.1021/jp0445829 10.1021/ja010782b 10.1021/jp044114z 10.1021/ic00093a009 10.1021/j100400a008 10.1007/BF01114537 10.1039/c39810000287 10.1021/ic020400i 10.1016/S0010-8545(02)00019-X 10.1021/om00003a013 10.1021/ic00063a013 10.1021/ic035471b 10.1002/anie.200902728 10.1016/j.ccr.2006.05.021 10.1021/cr9904009 10.1021/ja710763w 10.1021/jp0509212 10.1103/PhysRevLett.77.3865 10.1039/DT9830001801 10.1016/j.ccr.2010.12.027 10.1021/om960044+ 10.1021/jp0366320 10.1039/f29868202401 10.1021/ja00390a022 10.1021/ja970511u 10.1063/1.1337864 10.1021/jp980659f 10.1063/1.464303 10.1016/0022-0728(91)85183-P 10.1063/1.438955 |
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| Keywords | Diimine Excited states TDDFT Spectroelectrochemistry Rhenium complexes |
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| References | DeArmond, Hanck, Wertz (b0090) 1985; 64 McCusker (b0145) 2003; 36 El Nahhas, Consani, Blanco-Rodríguez, Lancaster, Braem, Cannizzo, Towrie, Clark, Záliš, Chergui, Vlček (b0135) 2011; 50 Turki, Daniel, Záliš, Vlček, van Slageren, Stufkens (b0110) 2001; 123 Tomasi, Mennucci, Cammi (b0305) 2005; 105 Berger (b0095) 1990; 29 Hartl, Luyten, Nieuwenhuis, Schoemaker (b0250) 1994; 48 Smothers, Wrighton (b0050) 1983; 105 Worl, Duesing, Chen, Della Ciana, Meyer (b0180) 1991 Martin, Sundermann (b0300) 2001; 114 Walters, Kim, Hupp (b0230) 2002; 41 Consani, Prémont-Schwarz, El Nahhas, Bressler, van Mourik, Cannizzo, Chergui (b0320) 2009; 48 Turró, Chung, Leventis, Kuchenmeister, Wagner, Leroi (b0100) 1996; 35 Chen, Omberg, Kavaliunas, Treadway, Palmer, Meyer (b0085) 1997; 36 Damrauer, McCusker (b0080) 1999; 103 Luong, Nadjo, Wrighton (b0150) 1978; 100 Adamo, Barone (b0280) 1999; 110 Mahabiersing, Luyten, Nieuwendam, Hartl (b0255) 2003; 68 Wrighton, Morse (b0175) 1974; 96 Vlček, Záliš (b0235) 2005; 109 Frisch, Trucks, Schlegel, Scuseria, Robb, Cheeseman, Scalmani, Barone, Mennucci, Petersson, Nakatsuji, Caricato, Li, Hratchian, Izmaylov, Bloino, Zheng, Sonnenberg, Hada, Ehara, Toyota, Fukuda, Hasegawa, Ishida, Nakajima, Honda, Kitao, Nakai, Vreven, Montgomery, Peralta, Ogliaro, Bearpark, Heyd, Brothers, Kudin, Staroverov, Kobayashi, Normand, Raghavachari, Rendell, Burant, Iyengar, Tomasi, Cossi, Rega, Millam, Klene, Knox, Cross, Bakken, Adamo, Jaramillo, Gomperts, Stratmann, Yazyev, Austin, Cammi, Pomelli, Ochterski, Martin, Morokuma, Zakrzewski, Voth, Salvador, Dannenberg, Dapprich, Daniels, Farkas, Foresman, Ortiz, Cioslowski, Fox (b0270) 2009 Elliott (b0035) 1980 Tait, MacQueen, Donohoe, De Armond, Hanck, Wertz (b0060) 1986; 90 A. Vlček Jr., in: V. Balzani, D. Astruc (Eds.), Electron Transfer in Chemistry, Wiley-VCH, Weinheim, 2001, p. 804. Rossenaar, Stufkens, Vlček (b0195) 1996; 35 Vlček (b0005) 1993; 5 Blanco-Rodríguez, Gabrielsson, Motevalli, Matousek, Towrie, Šebera, Záliš, Vlček (b0210) 2005; 109 Dattelbaum, Omberg, Schoonover, Martin, Meyer (b0220) 2002; 41 Wallin, Davidsson, Modin, Hammarström (b0140) 2005; 109 Stor, Hartl, van Outersterp, Stufkens (b0165) 1995; 14 Gamelin, George, Glyn, Grevels, Johnson, Klotzbücher, Morrison, Russell, Schaffner, Turner (b0190) 1994; 33 Braterman, Harriman, Heath, Yellowlees (b0010) 1983 Angel, DeArmond, Donohoe, Hanck, Wertz (b0055) 1984; 106 Bradley, Kress, Hornberger, Dallinger, Woodruff (b0045) 1981; 103 Gabrielsson, Busby, Matousek, Towrie, Hevia, Cuesta, Perez, Záliš, Vlček (b0215) 2006; 45 El Nahhas, Cannizzo, van Mourik, Blanco-Rodríguez, Záliš, Vlček, Chergui (b0130) 2010; 114 Elliott, Hershenhart (b0025) 1982; 104 Raghavachari, Binkley, Seeger, Pople (b0285) 1980; 72 Omberg, Schoonover, Treadway, Leasure, Dyer, Meyer (b0065) 1997; 119 Vlček, Záliš (b0120) 2007; 251 Busby, Gabrielsson, Matousek, Towrie, Di Bilio, Gray, Vlček (b0205) 2004; 43 Víchová, Hartl, Vlček (b0070) 1992; 114 Liard, Busby, Matousek, Towrie, Vlček (b0200) 2004; 108 Lindsay, Vlček, Langford (b0075) 1993; 32 Paolucci, Marcaccio, Paradisi, Roffia, Bignozzi, Amatore (b0155) 1998; 102 Johnson, George, Hartl, Turner (b0160) 1996; 15 George, Johnson, Westwell, Hodges, Turner (b0185) 1993 Helbing, Bonacina, Pietri, Bredenbeck, Hamm, van Mourik, Chaussard, Gonzalez-Gonzalez, Chergui, Ramos-Alvarez, Ruiz, Lopez-Garriga (b0260) 2004; 87 Dattelbaum, Omberg, Hay, Gebhart, Martin, Schoonover, Meyer (b0225) 2004; 108 Stufkens, Vlček (b0105) 1998; 177 Baková, Chergui, Daniel, Vlček, Záliš (b0245) 2011; 255 Cannizzo, Blanco-Rodríguez, Nahhas, Šebera, Záliš, Vlček, Chergui (b0240) 2008; 130 Woon, Dunning (b0290) 1993; 98 Krejčík, Vlček (b0310) 1991; 313 Heath, Yellowlees, Braterman (b0030) 1981 Woodruff, Dallinger (b0040) 1979; 101 Daniel (b0115) 2002; 230 Charlot, Pellegrin, Quaranta, Leibl, Aukauloo (b0125) 2006; 12 Perdew, Burke, Ernzerhof (b0275) 1996; 77 Forster, Hester (b0015) 1981; 81 Kalyanasundaram (b0020) 1986; 2 Andrae, Häussermann, Dolg, Stoll, Preuss (b0295) 1990; 77 Cannizzo (10.1016/j.ica.2011.02.084_b0240) 2008; 130 Charlot (10.1016/j.ica.2011.02.084_b0125) 2006; 12 Hartl (10.1016/j.ica.2011.02.084_b0250) 1994; 48 El Nahhas (10.1016/j.ica.2011.02.084_b0135) 2011; 50 10.1016/j.ica.2011.02.084_b0315 Worl (10.1016/j.ica.2011.02.084_b0180) 1991 Kalyanasundaram (10.1016/j.ica.2011.02.084_b0020) 1986; 2 Turró (10.1016/j.ica.2011.02.084_b0100) 1996; 35 Elliott (10.1016/j.ica.2011.02.084_b0025) 1982; 104 Martin (10.1016/j.ica.2011.02.084_b0300) 2001; 114 Heath (10.1016/j.ica.2011.02.084_b0030) 1981 Woon (10.1016/j.ica.2011.02.084_b0290) 1993; 98 Víchová (10.1016/j.ica.2011.02.084_b0070) 1992; 114 Berger (10.1016/j.ica.2011.02.084_b0095) 1990; 29 Daniel (10.1016/j.ica.2011.02.084_b0115) 2002; 230 Wallin (10.1016/j.ica.2011.02.084_b0140) 2005; 109 Rossenaar (10.1016/j.ica.2011.02.084_b0195) 1996; 35 Liard (10.1016/j.ica.2011.02.084_b0200) 2004; 108 Dattelbaum (10.1016/j.ica.2011.02.084_b0225) 2004; 108 Vlček (10.1016/j.ica.2011.02.084_b0235) 2005; 109 Raghavachari (10.1016/j.ica.2011.02.084_b0285) 1980; 72 Turki (10.1016/j.ica.2011.02.084_b0110) 2001; 123 Johnson (10.1016/j.ica.2011.02.084_b0160) 1996; 15 Wrighton (10.1016/j.ica.2011.02.084_b0175) 1974; 96 Stufkens (10.1016/j.ica.2011.02.084_b0105) 1998; 177 Helbing (10.1016/j.ica.2011.02.084_b0260) 2004; 87 Andrae (10.1016/j.ica.2011.02.084_b0295) 1990; 77 Gabrielsson (10.1016/j.ica.2011.02.084_b0215) 2006; 45 Tait (10.1016/j.ica.2011.02.084_b0060) 1986; 90 Vlček (10.1016/j.ica.2011.02.084_b0005) 1993; 5 Chen (10.1016/j.ica.2011.02.084_b0085) 1997; 36 Dattelbaum (10.1016/j.ica.2011.02.084_b0220) 2002; 41 Luong (10.1016/j.ica.2011.02.084_b0150) 1978; 100 Frisch (10.1016/j.ica.2011.02.084_b0270) 2009 Damrauer (10.1016/j.ica.2011.02.084_b0080) 1999; 103 Omberg (10.1016/j.ica.2011.02.084_b0065) 1997; 119 El Nahhas (10.1016/j.ica.2011.02.084_b0130) 2010; 114 Busby (10.1016/j.ica.2011.02.084_b0205) 2004; 43 Elliott (10.1016/j.ica.2011.02.084_b0035) 1980 George (10.1016/j.ica.2011.02.084_b0185) 1993 Adamo (10.1016/j.ica.2011.02.084_b0280) 1999; 110 Braterman (10.1016/j.ica.2011.02.084_b0010) 1983 Woodruff (10.1016/j.ica.2011.02.084_b0040) 1979; 101 DeArmond (10.1016/j.ica.2011.02.084_b0090) 1985; 64 Krejčík (10.1016/j.ica.2011.02.084_b0310) 1991; 313 Vlček (10.1016/j.ica.2011.02.084_b0120) 2007; 251 Baková (10.1016/j.ica.2011.02.084_b0245) 2011; 255 Blanco-Rodríguez (10.1016/j.ica.2011.02.084_b0210) 2005; 109 Walters (10.1016/j.ica.2011.02.084_b0230) 2002; 41 Forster (10.1016/j.ica.2011.02.084_b0015) 1981; 81 Paolucci (10.1016/j.ica.2011.02.084_b0155) 1998; 102 Stor (10.1016/j.ica.2011.02.084_b0165) 1995; 14 Angel (10.1016/j.ica.2011.02.084_b0055) 1984; 106 Mahabiersing (10.1016/j.ica.2011.02.084_b0255) 2003; 68 McCusker (10.1016/j.ica.2011.02.084_b0145) 2003; 36 Perdew (10.1016/j.ica.2011.02.084_b0275) 1996; 77 Consani (10.1016/j.ica.2011.02.084_b0320) 2009; 48 Smothers (10.1016/j.ica.2011.02.084_b0050) 1983; 105 Lindsay (10.1016/j.ica.2011.02.084_b0075) 1993; 32 Bradley (10.1016/j.ica.2011.02.084_b0045) 1981; 103 Gamelin (10.1016/j.ica.2011.02.084_b0190) 1994; 33 Tomasi (10.1016/j.ica.2011.02.084_b0305) 2005; 105 |
| References_xml | – volume: 114 start-page: 3408 year: 2001 ident: b0300 publication-title: J. Chem. Phys. – volume: 45 start-page: 9789 year: 2006 ident: b0215 publication-title: Inorg. Chem. – volume: 87 year: 2004 ident: b0260 publication-title: Biophys. J. – volume: 251 start-page: 258 year: 2007 ident: b0120 publication-title: Coord. Chem. Rev. – volume: 15 start-page: 3374 year: 1996 ident: b0160 publication-title: Organometallics – volume: 64 start-page: 65 year: 1985 ident: b0090 publication-title: Coord. Chem. Rev. – volume: 104 start-page: 7519 year: 1982 ident: b0025 publication-title: J. Am. Chem. Soc. – volume: 102 start-page: 4759 year: 1998 ident: b0155 publication-title: J. Phys. Chem. B – volume: 43 start-page: 4994 year: 2004 ident: b0205 publication-title: Inorg. Chem. – volume: 68 start-page: 1687 year: 2003 ident: b0255 publication-title: Coll. Czech. Chem. Commun. – reference: A. Vlček Jr., in: V. Balzani, D. Astruc (Eds.), Electron Transfer in Chemistry, Wiley-VCH, Weinheim, 2001, p. 804. – volume: 109 start-page: 2991 year: 2005 ident: b0235 publication-title: J. Phys. Chem. A – volume: 130 start-page: 8967 year: 2008 ident: b0240 publication-title: J. Am. Chem. Soc. – volume: 119 start-page: 7013 year: 1997 ident: b0065 publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 1522 year: 1994 ident: b0250 publication-title: Appl. Spectrosc. – volume: 109 start-page: 4697 year: 2005 ident: b0140 publication-title: J. Phys. Chem. A – volume: 313 start-page: 243 year: 1991 ident: b0310 publication-title: J. Electroanal. Chem. – volume: 105 start-page: 1067 year: 1983 ident: b0050 publication-title: J. Am. Chem. Soc. – volume: 32 start-page: 2269 year: 1993 ident: b0075 publication-title: Inorg. Chem. – volume: 106 start-page: 3688 year: 1984 ident: b0055 publication-title: J. Am. Chem. Soc. – volume: 77 start-page: 3865 year: 1996 ident: b0275 publication-title: Phys. Rev. Lett. – volume: 98 start-page: 1358 year: 1993 ident: b0290 publication-title: J. Chem. Phys. – volume: 72 start-page: 650 year: 1980 ident: b0285 publication-title: J. Chem. Phys. – volume: 108 start-page: 2363 year: 2004 ident: b0200 publication-title: J. Phys. Chem. A – volume: 105 start-page: 2999 year: 2005 ident: b0305 publication-title: Chem. Rev. – volume: 5 start-page: 1 year: 1993 ident: b0005 publication-title: Chemtracts – Inorg. Chem. – volume: 41 start-page: 2909 year: 2002 ident: b0230 publication-title: Inorg. Chem. – volume: 108 start-page: 3527 year: 2004 ident: b0225 publication-title: J. Phys. Chem. A – start-page: 261 year: 1980 ident: b0035 publication-title: J.C.S. Chem. Commun. – volume: 114 start-page: 6361 year: 2010 ident: b0130 publication-title: J. Phys. Chem. A – volume: 48 start-page: 7184 year: 2009 end-page: 7187 ident: b0320 publication-title: Angew. Chem., Int. Ed. – volume: 230 start-page: 65 year: 2002 ident: b0115 publication-title: Coord. Chem. Rev. – volume: 12 start-page: 796 year: 2006 ident: b0125 publication-title: Chem. Eur. J. – volume: 33 start-page: 3246 year: 1994 ident: b0190 publication-title: Inorg. Chem. – volume: 81 start-page: 42 year: 1981 ident: b0015 publication-title: Chem. Phys. Lett. – volume: 36 start-page: 954 year: 1997 ident: b0085 publication-title: Inorg. Chem. – volume: 103 start-page: 8440 year: 1999 ident: b0080 publication-title: J. Phys. Chem. A – volume: 123 start-page: 11431 year: 2001 ident: b0110 publication-title: J. Am. Chem. Soc. – volume: 100 start-page: 5790 year: 1978 ident: b0150 publication-title: J. Am. Chem. Soc. – year: 2009 ident: b0270 article-title: 09, Revision A.02 – volume: 77 start-page: 123 year: 1990 ident: b0295 publication-title: Theor. Chim. Acta – volume: 35 start-page: 2902 year: 1996 ident: b0195 publication-title: Inorg. Chem. – volume: 109 start-page: 5016 year: 2005 ident: b0210 publication-title: J. Phys. Chem. A – start-page: 1801 year: 1983 ident: b0010 publication-title: J. Chem. Soc., Dalton Trans. – start-page: 849 year: 1991 ident: b0180 publication-title: J. Chem. Soc., Dalton Trans. – volume: 177 start-page: 127 year: 1998 ident: b0105 publication-title: Coord. Chem. Rev. – volume: 41 start-page: 6071 year: 2002 ident: b0220 publication-title: Inorg. Chem. – volume: 90 start-page: 1766 year: 1986 ident: b0060 publication-title: J. Phys. Chem. – volume: 110 start-page: 6158 year: 1999 ident: b0280 publication-title: J. Chem. Phys. – volume: 36 start-page: 876 year: 2003 ident: b0145 publication-title: Acc. Chem. Res. – volume: 114 start-page: 10903 year: 1992 ident: b0070 publication-title: J. Am. Chem. Soc. – volume: 35 start-page: 5104 year: 1996 ident: b0100 publication-title: Inorg. Chem. – volume: 255 start-page: 975 year: 2011 ident: b0245 publication-title: Coord. Chem. Rev. – start-page: 2977 year: 1993 ident: b0185 publication-title: J. Chem. Soc., Dalton Trans. – volume: 103 start-page: 7441 year: 1981 ident: b0045 publication-title: J. Am. Chem. Soc. – volume: 96 start-page: 998 year: 1974 ident: b0175 publication-title: J. Am. Chem. Soc. – start-page: 287 year: 1981 ident: b0030 publication-title: J.C.S. Chem. Commun. – volume: 14 start-page: 1115 year: 1995 ident: b0165 publication-title: Organometallics – volume: 101 start-page: 4391 year: 1979 ident: b0040 publication-title: J. Am. Chem. Soc. – volume: 29 start-page: 1920 year: 1990 ident: b0095 publication-title: Inorg. Chem. – volume: 50 start-page: 2932 year: 2011 ident: b0135 publication-title: Inorg. Chem. – volume: 2 start-page: 2401 year: 1986 ident: b0020 publication-title: J. Chem. Soc., Faraday Trans. – volume: 45 start-page: 9789 year: 2006 ident: 10.1016/j.ica.2011.02.084_b0215 publication-title: Inorg. Chem. doi: 10.1021/ic0614768 – volume: 110 start-page: 6158 year: 1999 ident: 10.1016/j.ica.2011.02.084_b0280 publication-title: J. Chem. Phys. doi: 10.1063/1.478522 – volume: 36 start-page: 954 year: 1997 ident: 10.1016/j.ica.2011.02.084_b0085 publication-title: Inorg. Chem. doi: 10.1021/ic961328p – start-page: 2977 year: 1993 ident: 10.1016/j.ica.2011.02.084_b0185 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/DT9930002977 – volume: 114 start-page: 6361 year: 2010 ident: 10.1016/j.ica.2011.02.084_b0130 publication-title: J. Phys. Chem. A doi: 10.1021/jp101999m – start-page: 261 year: 1980 ident: 10.1016/j.ica.2011.02.084_b0035 publication-title: J.C.S. Chem. Commun. doi: 10.1039/C39800000261 – volume: 114 start-page: 10903 year: 1992 ident: 10.1016/j.ica.2011.02.084_b0070 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00053a029 – volume: 5 start-page: 1 year: 1993 ident: 10.1016/j.ica.2011.02.084_b0005 publication-title: Chemtracts – Inorg. Chem. – volume: 106 start-page: 3688 year: 1984 ident: 10.1016/j.ica.2011.02.084_b0055 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00324a057 – volume: 64 start-page: 65 year: 1985 ident: 10.1016/j.ica.2011.02.084_b0090 publication-title: Coord. Chem. Rev. doi: 10.1016/0010-8545(85)80042-4 – volume: 103 start-page: 8440 year: 1999 ident: 10.1016/j.ica.2011.02.084_b0080 publication-title: J. Phys. Chem. A doi: 10.1021/jp9927754 – volume: 87 year: 2004 ident: 10.1016/j.ica.2011.02.084_b0260 publication-title: Biophys. J. doi: 10.1529/biophysj.103.036236 – volume: 50 start-page: 2932 year: 2011 ident: 10.1016/j.ica.2011.02.084_b0135 publication-title: Inorg. Chem. doi: 10.1021/ic102324p – volume: 68 start-page: 1687 year: 2003 ident: 10.1016/j.ica.2011.02.084_b0255 publication-title: Coll. Czech. Chem. Commun. doi: 10.1135/cccc20031687 – start-page: 849 year: 1991 ident: 10.1016/j.ica.2011.02.084_b0180 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/dt9910000849 – volume: 103 start-page: 7441 year: 1981 ident: 10.1016/j.ica.2011.02.084_b0045 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00415a007 – volume: 36 start-page: 876 year: 2003 ident: 10.1016/j.ica.2011.02.084_b0145 publication-title: Acc. Chem. Res. doi: 10.1021/ar030111d – volume: 81 start-page: 42 year: 1981 ident: 10.1016/j.ica.2011.02.084_b0015 publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(81)85323-7 – volume: 101 start-page: 4391 year: 1979 ident: 10.1016/j.ica.2011.02.084_b0040 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00509a066 – volume: 96 start-page: 998 year: 1974 ident: 10.1016/j.ica.2011.02.084_b0175 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00811a008 – volume: 35 start-page: 5104 year: 1996 ident: 10.1016/j.ica.2011.02.084_b0100 publication-title: Inorg. Chem. doi: 10.1021/ic9601091 – volume: 12 start-page: 796 year: 2006 ident: 10.1016/j.ica.2011.02.084_b0125 publication-title: Chem. Eur. J. doi: 10.1002/chem.200500482 – volume: 100 start-page: 5790 year: 1978 ident: 10.1016/j.ica.2011.02.084_b0150 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00486a033 – volume: 108 start-page: 3527 year: 2004 ident: 10.1016/j.ica.2011.02.084_b0225 publication-title: J. Phys. Chem. A doi: 10.1021/jp037096e – volume: 105 start-page: 1067 year: 1983 ident: 10.1016/j.ica.2011.02.084_b0050 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00342a077 – volume: 48 start-page: 1522 year: 1994 ident: 10.1016/j.ica.2011.02.084_b0250 publication-title: Appl. Spectrosc. doi: 10.1366/0003702944027787 – ident: 10.1016/j.ica.2011.02.084_b0315 doi: 10.1002/9783527618248.ch28 – volume: 35 start-page: 2902 year: 1996 ident: 10.1016/j.ica.2011.02.084_b0195 publication-title: Inorg. Chem. doi: 10.1021/ic9509802 – volume: 41 start-page: 2909 year: 2002 ident: 10.1016/j.ica.2011.02.084_b0230 publication-title: Inorg. Chem. doi: 10.1021/ic011015g – volume: 177 start-page: 127 year: 1998 ident: 10.1016/j.ica.2011.02.084_b0105 publication-title: Coord. Chem. Rev. doi: 10.1016/S0010-8545(98)00132-5 – volume: 29 start-page: 1920 year: 1990 ident: 10.1016/j.ica.2011.02.084_b0095 publication-title: Inorg. Chem. doi: 10.1021/ic00335a031 – volume: 109 start-page: 2991 year: 2005 ident: 10.1016/j.ica.2011.02.084_b0235 publication-title: J. Phys. Chem. A doi: 10.1021/jp0445829 – volume: 123 start-page: 11431 year: 2001 ident: 10.1016/j.ica.2011.02.084_b0110 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja010782b – volume: 109 start-page: 5016 year: 2005 ident: 10.1016/j.ica.2011.02.084_b0210 publication-title: J. Phys. Chem. A doi: 10.1021/jp044114z – volume: 33 start-page: 3246 year: 1994 ident: 10.1016/j.ica.2011.02.084_b0190 publication-title: Inorg. Chem. doi: 10.1021/ic00093a009 – volume: 90 start-page: 1766 year: 1986 ident: 10.1016/j.ica.2011.02.084_b0060 publication-title: J. Phys. Chem. doi: 10.1021/j100400a008 – volume: 77 start-page: 123 year: 1990 ident: 10.1016/j.ica.2011.02.084_b0295 publication-title: Theor. Chim. Acta doi: 10.1007/BF01114537 – start-page: 287 year: 1981 ident: 10.1016/j.ica.2011.02.084_b0030 publication-title: J.C.S. Chem. Commun. doi: 10.1039/c39810000287 – volume: 41 start-page: 6071 year: 2002 ident: 10.1016/j.ica.2011.02.084_b0220 publication-title: Inorg. Chem. doi: 10.1021/ic020400i – volume: 230 start-page: 65 year: 2002 ident: 10.1016/j.ica.2011.02.084_b0115 publication-title: Coord. Chem. Rev. doi: 10.1016/S0010-8545(02)00019-X – volume: 14 start-page: 1115 year: 1995 ident: 10.1016/j.ica.2011.02.084_b0165 publication-title: Organometallics doi: 10.1021/om00003a013 – volume: 32 start-page: 2269 year: 1993 ident: 10.1016/j.ica.2011.02.084_b0075 publication-title: Inorg. Chem. doi: 10.1021/ic00063a013 – volume: 43 start-page: 4994 year: 2004 ident: 10.1016/j.ica.2011.02.084_b0205 publication-title: Inorg. Chem. doi: 10.1021/ic035471b – volume: 48 start-page: 7184 year: 2009 ident: 10.1016/j.ica.2011.02.084_b0320 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200902728 – volume: 251 start-page: 258 year: 2007 ident: 10.1016/j.ica.2011.02.084_b0120 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2006.05.021 – volume: 105 start-page: 2999 year: 2005 ident: 10.1016/j.ica.2011.02.084_b0305 publication-title: Chem. Rev. doi: 10.1021/cr9904009 – volume: 130 start-page: 8967 year: 2008 ident: 10.1016/j.ica.2011.02.084_b0240 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja710763w – volume: 109 start-page: 4697 year: 2005 ident: 10.1016/j.ica.2011.02.084_b0140 publication-title: J. Phys. Chem. A doi: 10.1021/jp0509212 – volume: 77 start-page: 3865 year: 1996 ident: 10.1016/j.ica.2011.02.084_b0275 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.77.3865 – start-page: 1801 year: 1983 ident: 10.1016/j.ica.2011.02.084_b0010 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/DT9830001801 – volume: 255 start-page: 975 year: 2011 ident: 10.1016/j.ica.2011.02.084_b0245 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2010.12.027 – volume: 15 start-page: 3374 year: 1996 ident: 10.1016/j.ica.2011.02.084_b0160 publication-title: Organometallics doi: 10.1021/om960044+ – volume: 108 start-page: 2363 year: 2004 ident: 10.1016/j.ica.2011.02.084_b0200 publication-title: J. Phys. Chem. A doi: 10.1021/jp0366320 – volume: 2 start-page: 2401 issue: 82 year: 1986 ident: 10.1016/j.ica.2011.02.084_b0020 publication-title: J. Chem. Soc., Faraday Trans. doi: 10.1039/f29868202401 – volume: 104 start-page: 7519 year: 1982 ident: 10.1016/j.ica.2011.02.084_b0025 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00390a022 – volume: 119 start-page: 7013 year: 1997 ident: 10.1016/j.ica.2011.02.084_b0065 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja970511u – volume: 114 start-page: 3408 year: 2001 ident: 10.1016/j.ica.2011.02.084_b0300 publication-title: J. Chem. Phys. doi: 10.1063/1.1337864 – volume: 102 start-page: 4759 year: 1998 ident: 10.1016/j.ica.2011.02.084_b0155 publication-title: J. Phys. Chem. B doi: 10.1021/jp980659f – year: 2009 ident: 10.1016/j.ica.2011.02.084_b0270 – volume: 98 start-page: 1358 year: 1993 ident: 10.1016/j.ica.2011.02.084_b0290 publication-title: J. Chem. Phys. doi: 10.1063/1.464303 – volume: 313 start-page: 243 year: 1991 ident: 10.1016/j.ica.2011.02.084_b0310 publication-title: J. Electroanal. Chem. doi: 10.1016/0022-0728(91)85183-P – volume: 72 start-page: 650 year: 1980 ident: 10.1016/j.ica.2011.02.084_b0285 publication-title: J. Chem. Phys. doi: 10.1063/1.438955 |
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| Snippet | Electronic absorption spectra of one-electron reduced and MLCT excited states of metal α-diimine complexes in the UV region are similar in appearance and a... |
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| SubjectTerms | Diimine Excited states Rhenium complexes Spectroelectrochemistry TDDFT |
| Title | Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2′-bipyridine and 1,10-phenanthroline complexes |
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