Photophysics and photochemistry of 1,2,3-triazole-based complexes

[Display omitted] •Triazole-based ‘click’ chemistry is a versatile tool in ligand design.•Triazole-based ligands enable access to rich coordination chemistry.•Facile tuning of photophysical luminescent properties through ‘click’ chemistry design.•Diverse applications from cellular imaging to light-e...

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Vydané v:Coordination chemistry reviews Ročník 350; s. 136 - 154
Hlavní autori: Scattergood, Paul A., Sinopoli, Alessandro, Elliott, Paul I.P.
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Elsevier B.V 01.11.2017
Predmet:
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ORTEP
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DMSO
dfppyH
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Phe
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LLCT
THF
DFT
phen
Gly
Cy
MRSA
Ph
DMAP
DOTA
DO3A
DMF
Fc
TD-DFT
Pr
IL
aNHC
Bn
CT
NMR
Sh
ILCT
dmbpy
Ala
LC
Mes
dmobpy
dfptzBn
ISSN:0010-8545, 1873-3840
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Popis
Shrnutí:[Display omitted] •Triazole-based ‘click’ chemistry is a versatile tool in ligand design.•Triazole-based ligands enable access to rich coordination chemistry.•Facile tuning of photophysical luminescent properties through ‘click’ chemistry design.•Diverse applications from cellular imaging to light-emitting and photovoltaic devices.•Triazole-based ligand enables access to highly novel photochemistry. The copper-catalysed cycloaddition of alkynes and azides to form 1,2,3-triazoles has emerged as a powerful tool in ligand design and the synthesis of novel transition metal complexes. In this review we focus on the photophysical properties of metal complexes bearing 1,2,3-triazole-based ligands with a particular emphasis on those of d6 metals including rhenium(I), iron(II), ruthenium(II), osmium(II) and iridium(III). We also highlight key examples of triazole complexes of platinum(II) and palladium(II) as well as the lanthanides and coinage metals.
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2017.06.017