Polymers of Intrinsic Microporosity (PIMs)

Based on cumulative research from the past two decades, this personal perspective defines the structurally unique features of Polymers of Intrinsic Microporosity (PIMs), which result in a distinct combination of properties, including solution-processability and microporosity, providing organic mater...

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Vydané v:Polymer (Guilford) Ročník 202; s. 122736
Hlavný autor: McKeown, Neil B.
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Kidlington Elsevier Ltd 12.08.2020
Elsevier BV
Predmet:
Fabrication
Microporosity
Organic materials
Polymers
ISSN:0032-3861, 1873-2291
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Shrnutí:Based on cumulative research from the past two decades, this personal perspective defines the structurally unique features of Polymers of Intrinsic Microporosity (PIMs), which result in a distinct combination of properties, including solution-processability and microporosity, providing organic materials suitable for the fabrication of membranes that perform efficient molecular sieving. [Display omitted] •Personal reflection on the development of Polymers of Intrinsic Microporosity (PIMs).•Explanation of why PIMs form a distinct class of polymer and microporous material.•Re-definition of PIMs based on their method of synthesis, structure and properties.•Rigidity and sub-nanometre pore size combine to make PIM membranes selective.•Free volume is largely interconnected but only for the transport of small gases.
Bibliografia:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2020.122736