Unexpected Supremacy of Non‐Dysprosium Single‐Ion Magnets within a Series of Isomorphic Lanthanide Cyanocobaltate(III) Complexes

Slow relaxation of magnetization has been studied for a series of stable isomorphic 3D‐polynuclear Ln‐Co complexes comprising hexadentate [Co(CN)6]3– linkers, namely {[Ln(H2O)2][Co(CN)6]·2H2O}n where Ln = Tb (1), Dy (2), Er (3) and Yb (4). While 1 and 4 behave as field‐induced single‐ion magnets (SI...

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Bibliographic Details

Published in:	European journal of inorganic chemistry Vol. 2020; no. 46; pp. 4380 - 4390
Main Authors:	Babeshkin, Konstantin A., Gavrikov, Andrey V., Petrosyants, Svetlana P., Ilyukhin, Andrey B., Belova, Ekaterina V., Efimov, Nikolay N.
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 13.12.2020
Subjects:	Cyanometallate‐bridged complexes Demagnetization Dysprosium Erbium Inorganic chemistry Lanthanides Magnetic properties Magnets Single‐ion magnets Single‐molecule magnets Virtual reality Ytterbium
ISSN:	1434-1948, 1099-0682
Online Access:	Get full text
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