Reversible SC‐SC Transformation involving [4+4] Cycloaddition of Anthracene: A Single‐Ion to Single‐Molecule Magnet and Yellow‐Green to Blue‐White Emission

In search of magneto‐optic materials, the mononuclear compounds LnIII(depma)(NO3)3(hmpa)2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single‐ion to a single‐molecule magnet w...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 57; no. 28; pp. 8577 - 8581
Main Authors:	Huang, Xin‐Da, Xu, Yan, Fan, Kun, Bao, Song‐Song, Kurmoo, Mohamedally, Zheng, Li‐Min
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 09.07.2018
Edition:	International ed. in English
Subjects:	Anthracene Clean energy Cycloaddition Dimerization dysprosium Dysprosium compounds Emission Emissions Gadolinium Magnetic properties Molecular chains Optical materials Phosphonates photocycloaddition single-molecule magnets Smart materials Switches white light anthracene photocycloaddition dysprosium white light single-molecule magnets
ISSN:	1433-7851, 1521-3773
Online Access:	Get full text
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