Reversible SC‐SC Transformation involving [4+4] Cycloaddition of Anthracene: A Single‐Ion to Single‐Molecule Magnet and Yellow‐Green to Blue‐White Emission

In search of magneto‐optic materials, the mononuclear compounds LnIII(depma)(NO3)3(hmpa)2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single‐ion to a single‐molecule magnet w...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition Jg. 57; H. 28; S. 8577 - 8581
Hauptverfasser:	Huang, Xin‐Da, Xu, Yan, Fan, Kun, Bao, Song‐Song, Kurmoo, Mohamedally, Zheng, Li‐Min
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Germany Wiley Subscription Services, Inc 09.07.2018
Ausgabe:	International ed. in English
Schlagworte:	Anthracene Clean energy Cycloaddition Dimerization dysprosium Dysprosium compounds Emission Emissions Gadolinium Magnetic properties Molecular chains Optical materials Phosphonates photocycloaddition single-molecule magnets Smart materials Switches white light anthracene photocycloaddition dysprosium white light single-molecule magnets
ISSN:	1433-7851, 1521-3773
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Abstract	In search of magneto‐optic materials, the mononuclear compounds LnIII(depma)(NO3)3(hmpa)2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single‐ion to a single‐molecule magnet with doubling of the spin reversal barrier energy and from yellow‐green to blue‐white emission. The dimerization is reversed by heating at 100 °C or partially on light irradiating at 254 nm. The results suggest that lanthanide phosphonates with anthracene are promising smart materials displaying synergistic magneto‐optic property. Pairing up: The mononuclear compound DyIII(depma)(NO3)3(hmpa)2 (depma= 9‐diethylphosphono‐methylanthracene, hmpa=hexamethylphosphoramide) undergoes reversible [4+4] photodimerization in a single‐crystal‐to‐single‐crystal manner. This process is accompanied by a change from a single‐ion to a single‐molecule magnet and from yellow‐green to blue‐white emission.
AbstractList	In search of magneto‐optic materials, the mononuclear compounds LnIII(depma)(NO3)3(hmpa)2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single‐ion to a single‐molecule magnet with doubling of the spin reversal barrier energy and from yellow‐green to blue‐white emission. The dimerization is reversed by heating at 100 °C or partially on light irradiating at 254 nm. The results suggest that lanthanide phosphonates with anthracene are promising smart materials displaying synergistic magneto‐optic property. Pairing up: The mononuclear compound DyIII(depma)(NO3)3(hmpa)2 (depma= 9‐diethylphosphono‐methylanthracene, hmpa=hexamethylphosphoramide) undergoes reversible [4+4] photodimerization in a single‐crystal‐to‐single‐crystal manner. This process is accompanied by a change from a single‐ion to a single‐molecule magnet and from yellow‐green to blue‐white emission. In search of magneto‐optic materials, the mononuclear compounds Ln III (depma)(NO 3 ) 3 (hmpa) 2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single‐ion to a single‐molecule magnet with doubling of the spin reversal barrier energy and from yellow‐green to blue‐white emission. The dimerization is reversed by heating at 100 °C or partially on light irradiating at 254 nm. The results suggest that lanthanide phosphonates with anthracene are promising smart materials displaying synergistic magneto‐optic property. In search of magneto‐optic materials, the mononuclear compounds LnIII(depma)(NO3)3(hmpa)2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single‐ion to a single‐molecule magnet with doubling of the spin reversal barrier energy and from yellow‐green to blue‐white emission. The dimerization is reversed by heating at 100 °C or partially on light irradiating at 254 nm. The results suggest that lanthanide phosphonates with anthracene are promising smart materials displaying synergistic magneto‐optic property. In search of magneto-optic materials, the mononuclear compounds Ln (depma)(NO ) (hmpa) (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single-ion to a single-molecule magnet with doubling of the spin reversal barrier energy and from yellow-green to blue-white emission. The dimerization is reversed by heating at 100 °C or partially on light irradiating at 254 nm. The results suggest that lanthanide phosphonates with anthracene are promising smart materials displaying synergistic magneto-optic property.
Author	Huang, Xin‐Da Xu, Yan Fan, Kun Zheng, Li‐Min Bao, Song‐Song Kurmoo, Mohamedally
Author_xml	– sequence: 1 givenname: Xin‐Da surname: Huang fullname: Huang, Xin‐Da organization: Nanjing University – sequence: 2 givenname: Yan surname: Xu fullname: Xu, Yan organization: Nanjing University – sequence: 3 givenname: Kun surname: Fan fullname: Fan, Kun organization: Nanjing University – sequence: 4 givenname: Song‐Song surname: Bao fullname: Bao, Song‐Song organization: Nanjing University – sequence: 5 givenname: Mohamedally surname: Kurmoo fullname: Kurmoo, Mohamedally organization: Universite de Strasbourg, CNRS-UMR7177 – sequence: 6 givenname: Li‐Min orcidid: 0000-0003-4437-1105 surname: Zheng fullname: Zheng, Li‐Min email: lmzheng@nju.edu.cn organization: Nanjing University
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/29757484$$D View this record in MEDLINE/PubMed
BookMark	eNqFkd9qFDEYxYNU7B-99VICXsqsSSbzz7t1WOtCq-BWRERCJvmmTckmNZnZsnc-Ql-iL-aTmN1tLQjiVRLO75xDvu8Q7TnvAKHnlEwoIey1dAYmjNCacErYI3RAC0azvKryvXTneZ5VdUH30WGMl4mva1I-QfusqYqK1_wA3X6CFYRoOgt40f76ebNo8VmQLvY-LOVgvMPGrbxdGXeOv_FX_Dtu18p6qbXZqr7HUzdcBKnAwRs8xYtEWkhJ86QO_uF96i2oMfWcynMHA5ZO469grb9O4nEA2OJv7biBv1yYAfBsaWJMLU_R417aCM_uziP0-d3srH2fnXw8nrfTk0ylH7OMqlqXpIOOyA5YqRtaac561tCmqvocFIWegsppzzRIJrmSUpdNoXsi844U-RF6ucu9Cv7HCHEQl34MLlUKRkpOy4JUPFEv7qixW4IWV8EsZViL-6kmgO8AFXyMAXqhzLAd5hCksYISsVme2CxP_Flesk3-st0n_9PQ7AzXxsL6P7SYfpjPHry_AbR5szw
CitedBy_id	crossref_primary_10_1039_D2RA02260E crossref_primary_10_1016_j_inoche_2025_114197 crossref_primary_10_1039_D2DT01710E crossref_primary_10_1021_jacs_9b13461 crossref_primary_10_1002_ange_202217054 crossref_primary_10_1002_anie_202204700 crossref_primary_10_1021_acs_cgd_5c00212 crossref_primary_10_1002_chem_202000353 crossref_primary_10_1002_ange_202306719 crossref_primary_10_1016_j_jre_2023_11_009 crossref_primary_10_1039_D5SC01302J crossref_primary_10_1002_adfm_202512361 crossref_primary_10_1002_aoc_5893 crossref_primary_10_1007_s11696_019_00799_6 crossref_primary_10_1016_j_cclet_2020_10_019 crossref_primary_10_1039_D0SC06017H crossref_primary_10_1039_D2QI01371A crossref_primary_10_1039_D2QI01761J crossref_primary_10_3390_magnetochemistry11090077 crossref_primary_10_1002_anie_202422557 crossref_primary_10_3390_magnetochemistry6040069 crossref_primary_10_1039_D5SC02327K crossref_primary_10_1002_anie_202424651 crossref_primary_10_1002_ejic_202100538 crossref_primary_10_1016_j_cclet_2024_110404 crossref_primary_10_1002_anie_202306719 crossref_primary_10_1002_ejic_202100138 crossref_primary_10_1080_00958972_2019_1608440 crossref_primary_10_1016_j_poly_2021_115173 crossref_primary_10_1002_cjoc_202300212 crossref_primary_10_1002_cjoc_202100783 crossref_primary_10_1039_D4QI02373K crossref_primary_10_1080_00958972_2021_1916001 crossref_primary_10_1016_j_molstruc_2023_137408 crossref_primary_10_1002_ange_202422557 crossref_primary_10_1002_chem_202500527 crossref_primary_10_1007_s10876_019_01723_4 crossref_primary_10_1039_C9QI01504C crossref_primary_10_1039_D0SC04851H crossref_primary_10_1002_ange_202424651 crossref_primary_10_1002_chem_202203454 crossref_primary_10_1039_D2SC06732C crossref_primary_10_6023_cjoc202409013 crossref_primary_10_1016_j_cclet_2024_110577 crossref_primary_10_1002_advs_202509088 crossref_primary_10_1002_anie_202300088 crossref_primary_10_1007_s11243_021_00448_6 crossref_primary_10_1016_j_ica_2020_119867 crossref_primary_10_1021_jacs_5c03704 crossref_primary_10_3390_molecules28227506 crossref_primary_10_1021_acs_langmuir_4c04860 crossref_primary_10_1039_D0QI00628A crossref_primary_10_1002_anie_202217054 crossref_primary_10_1016_j_molstruc_2021_131456 crossref_primary_10_1002_chem_201902096 crossref_primary_10_1007_s40242_021_1373_2 crossref_primary_10_1021_jacsau_4c00540 crossref_primary_10_1002_ange_202204700 crossref_primary_10_1039_D4QI02771J crossref_primary_10_1134_S0030400X19030044 crossref_primary_10_1134_S0030400X20030054 crossref_primary_10_1021_acs_inorgchem_5c02219 crossref_primary_10_1021_acs_inorgchem_5c02857 crossref_primary_10_1002_ange_202300088 crossref_primary_10_1002_app_54723 crossref_primary_10_1039_D0QI00785D
Cites_doi	10.1021/ja300538s 10.1039/C5CC07073B 10.6023/A15060376 10.1002/anie.201205376 10.1002/ange.200461946 10.1016/S0010-8545(00)82068-8 10.1039/C8CC00220G 10.1002/anie.201706391 10.1038/nchem.2707 10.1002/anie.201410523 10.1021/jacs.6b02638 10.1016/j.mencom.2011.11.005 10.1021/acs.accounts.5b00296 10.1038/nature23447 10.1021/ic9804925 10.1039/B905604C 10.1038/nchem.2007 10.1039/C5SC03201F 10.1002/chem.201300299 10.1002/adma.201604005 10.1364/AO.11.000533 10.1002/adfm.200304352 10.1039/c2cs35271k 10.1002/chem.201601244 10.1002/ange.201705426 10.1039/C4QI00242C 10.1002/ange.19971092415 10.1039/c0ce00739k 10.1002/ange.201410523 10.1021/acs.joc.6b00134 10.1038/35079036 10.1002/ange.201503902 10.1063/1.1750906 10.1002/anie.199727791 10.1039/c0dt00979b 10.1002/ange.200390067 10.1002/anie.201705426 10.1039/b006013p 10.1246/cl.1995.751 10.1086/172610 10.1021/ja404351p 10.1002/ijch.197100066 10.1039/C6CC01993E 10.1039/C5DT03897A 10.1002/ange.201511444 10.1063/1.1669893 10.1002/anie.201503902 10.1016/j.ccr.2013.10.023 10.1038/35079225 10.1021/ja501569t 10.1002/ange.201205376 10.1002/anie.200461946 10.1039/C4DT03093A 10.1002/ange.201706391 10.1038/ncomms8954 10.1021/cr400018q 10.1021/acs.chemrev.6b00040 10.1039/C7TC03229C 10.1002/anie.200390099 10.1021/cr00017a008 10.1021/acsami.6b00704 10.1002/anie.201511444 10.1021/ja201925p 10.1039/c1cc15087a
ContentType	Journal Article
Copyright	2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Copyright_xml	– notice: 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim – notice: 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
DBID	AAYXX CITATION NPM 7TM K9.
DOI	10.1002/anie.201804102
DatabaseName	CrossRef PubMed Nucleic Acids Abstracts ProQuest Health & Medical Complete (Alumni)
DatabaseTitle	CrossRef PubMed ProQuest Health & Medical Complete (Alumni) Nucleic Acids Abstracts
DatabaseTitleList	CrossRef ProQuest Health & Medical Complete (Alumni) PubMed
Database_xml	– sequence: 1 dbid: NPM name: PubMed url: http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	1521-3773
Edition	International ed. in English
EndPage	8581
ExternalDocumentID	29757484 10_1002_anie_201804102 ANIE201804102
Genre	shortCommunication Research Support, Non-U.S. Gov't Journal Article
GrantInformation_xml	– fundername: National Natural Science Foundation of China funderid: 21731003; 11774178 – fundername: National Key R&D Program of China funderid: 2017YFA0303203
GroupedDBID	--- -DZ -~X .3N .GA 05W 0R~ 10A 1L6 1OB 1OC 1ZS 23M 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5RE 5VS 66C 6TJ 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AAHQN AAMNL AANLZ AAONW AASGY AAXRX AAYCA AAZKR ABCQN ABCUV ABEML ABIJN ABLJU ABPPZ ABPVW ACAHQ ACCFJ ACCZN ACFBH ACGFS ACIWK ACNCT ACPOU ACPRK ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN ADZOD AEEZP AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFFNX AFFPM AFGKR AFPWT AFRAH AFWVQ AFZJQ AHBTC AHMBA AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN ALVPJ AMBMR AMYDB ATUGU AUFTA AZBYB AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BTSUX BY8 CS3 D-E D-F D0L DCZOG DPXWK DR1 DR2 DRFUL DRSTM EBS EJD F00 F01 F04 F5P G-S G.N GNP GODZA H.T H.X HBH HGLYW HHY HHZ HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES M53 MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2P P2W P2X P4D PQQKQ Q.N Q11 QB0 QRW R.K RNS ROL RWI RX1 RYL SUPJJ TN5 UB1 UPT V2E VQA W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XPP XSW XV2 YZZ ZZTAW ~IA ~KM ~WT AAYXX ABDBF ABJNI ABUFD AEYWJ AGHNM AGYGG CITATION O8X NPM 7TM K9.
ID	FETCH-LOGICAL-c3772-1c8d60beb0abe26d917d42f291977f3ec1ef1ec31f2dea2a4caad695df0a3b053
IEDL.DBID	DRFUL
ISICitedReferencesCount	125
ISICitedReferencesURI	http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000437668700037&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
ISSN	1433-7851
IngestDate	Mon Nov 24 15:11:24 EST 2025 Thu Apr 03 06:58:08 EDT 2025 Sat Nov 29 03:44:24 EST 2025 Tue Nov 18 21:59:53 EST 2025 Wed Jan 22 16:45:17 EST 2025
IsPeerReviewed	true
IsScholarly	true
Issue	28
Keywords	anthracene photocycloaddition dysprosium white light single-molecule magnets
Language	English
License	2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-c3772-1c8d60beb0abe26d917d42f291977f3ec1ef1ec31f2dea2a4caad695df0a3b053
Notes	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14
ORCID	0000-0003-4437-1105
PMID	29757484
PQID	2064165074
PQPubID	946352
PageCount	5
ParticipantIDs	proquest_journals_2064165074 pubmed_primary_29757484 crossref_citationtrail_10_1002_anie_201804102 crossref_primary_10_1002_anie_201804102 wiley_primary_10_1002_anie_201804102_ANIE201804102
PublicationCentury	2000
PublicationDate	July 9, 2018
PublicationDateYYYYMMDD	2018-07-09
PublicationDate_xml	– month: 07 year: 2018 text: July 9, 2018 day: 09
PublicationDecade	2010
PublicationPlace	Germany
PublicationPlace_xml	– name: Germany – name: Weinheim
PublicationTitle	Angewandte Chemie International Edition
PublicationTitleAlternate	Angew Chem Int Ed Engl
PublicationYear	2018
Publisher	Wiley Subscription Services, Inc
Publisher_xml	– name: Wiley Subscription Services, Inc
References	1993; 408 2017; 5 1941; 9 2015; 73 2003; 13 2011; 13 2017; 9 2014; 136 2013 2013; 52 125 2013; 19 1971; 9 1979; 27 2015; 48 2012; 134 1995; 24 2015; 44 2015 2015; 54 127 2005 2005; 44 117 2011; 21 2013; 113 1997 1997; 36 109 2016; 116 2016; 81 1972; 11 2014; 6 2001; 411 2016; 45 2015; 2 2015; 6 1968; 49 2015; 51 2010; 39 2013; 42 2011; 40 2016; 52 2017; 29 2003 2003; 42 115 2017 2017; 56 129 2014; 273 2011; 133 2017; 548 1998; 37 2016; 7 2016 2016; 55 128 1993; 93 2017 2013; 135 2016; 138 2011; 47 2018; 54 2016; 8 2001; 30 2016; 22 e_1_2_2_24_2 e_1_2_2_4_2 e_1_2_2_49_1 e_1_2_2_6_2 e_1_2_2_22_1 e_1_2_2_20_2 e_1_2_2_2_2 e_1_2_2_62_1 e_1_2_2_41_2 e_1_2_2_64_2 e_1_2_2_28_3 e_1_2_2_28_2 e_1_2_2_43_2 e_1_2_2_66_2 e_1_2_2_8_1 e_1_2_2_45_1 e_1_2_2_26_2 e_1_2_2_24_3 e_1_2_2_47_1 e_1_2_2_68_1 e_1_2_2_60_2 e_1_2_2_13_2 e_1_2_2_11_3 e_1_2_2_59_1 e_1_2_2_11_2 e_1_2_2_38_2 e_1_2_2_51_2 e_1_2_2_74_2 e_1_2_2_74_3 e_1_2_2_19_2 e_1_2_2_30_2 e_1_2_2_17_3 e_1_2_2_32_1 e_1_2_2_53_1 e_1_2_2_17_2 e_1_2_2_55_2 e_1_2_2_34_2 e_1_2_2_57_2 e_1_2_2_15_1 e_1_2_2_36_1 e_1_2_2_72_1 e_1_2_2_70_2 e_1_2_2_3_2 e_1_2_2_48_1 e_1_2_2_5_1 e_1_2_2_23_2 e_1_2_2_69_2 e_1_2_2_21_2 e_1_2_2_1_1 e_1_2_2_40_2 e_1_2_2_61_2 e_1_2_2_40_3 e_1_2_2_42_1 e_1_2_2_65_1 e_1_2_2_29_2 e_1_2_2_63_2 e_1_2_2_7_2 e_1_2_2_44_2 e_1_2_2_9_3 e_1_2_2_27_1 e_1_2_2_46_1 e_1_2_2_9_2 e_1_2_2_25_2 e_1_2_2_67_2 e_1_2_2_37_2 e_1_2_2_58_2 e_1_2_2_10_3 e_1_2_2_12_1 e_1_2_2_10_2 e_1_2_2_39_2 Jia J.-H. (e_1_2_2_31_2) 2017 e_1_2_2_52_1 e_1_2_2_75_1 e_1_2_2_50_2 e_1_2_2_73_2 e_1_2_2_18_1 e_1_2_2_56_1 e_1_2_2_16_2 e_1_2_2_33_2 e_1_2_2_54_2 e_1_2_2_14_2 e_1_2_2_35_2 e_1_2_2_71_2 e_1_2_2_71_1
References_xml	– volume: 9 start-page: 341 year: 1941 end-page: 351 publication-title: J. Chem. Phys. – volume: 135 start-page: 14134 year: 2013 end-page: 14141 publication-title: J. Am. Chem. Soc. – volume: 134 start-page: 9644 year: 2012 publication-title: J. Am. Chem. Soc. – volume: 52 start-page: 7356 year: 2016 end-page: 7359 publication-title: Chem. Commun. – volume: 19 start-page: 8769 year: 2013 end-page: 8773 publication-title: Chem. Eur. J. – volume: 273 start-page: 76 year: 2014 end-page: 86 publication-title: Coord. Chem. Rev. – volume: 40 start-page: 2092 year: 2011 end-page: 2098 publication-title: Dalton Trans. – volume: 13 start-page: 4376 year: 2011 end-page: 4381 publication-title: CrystEngComm – volume: 55 128 start-page: 7073 7189 year: 2016 2016 end-page: 7076 7192 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 93 start-page: 145 year: 1993 end-page: 172 publication-title: Chem. Rev. – volume: 13 start-page: 398 year: 2003 end-page: 402 publication-title: Adv. Funct. Mater. – volume: 408 start-page: 530 year: 1993 end-page: 538 publication-title: Astrophys. J. – volume: 27 start-page: 223 year: 1979 end-page: 273 publication-title: Coord. Chem. Rev. – volume: 54 127 start-page: 2236 2264 year: 2015 2015 end-page: 2240 2268 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 36 109 start-page: 2779 2878 year: 1997 1997 end-page: 2781 2881 publication-title: Angew. Chem. Int. Ed. Engl. Angew. Chem. – volume: 48 start-page: 2834 year: 2015 end-page: 2842 publication-title: Acc. Chem. Res. – volume: 81 start-page: 2106 year: 2016 end-page: 2112 publication-title: J. Org. Chem. – volume: 54 start-page: 3278 year: 2018 end-page: 3281 publication-title: Chem. Commun. – volume: 42 115 start-page: 268 278 year: 2003 2003 end-page: 297 309 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 411 start-page: 565 year: 2001 end-page: 568 publication-title: Nature – volume: 45 start-page: 2974 year: 2016 end-page: 2982 publication-title: Dalton Trans. – volume: 8 start-page: 9431 year: 2016 end-page: 9439 publication-title: ACS Appl. Mater. Interfaces – volume: 51 start-page: 15358 year: 2015 end-page: 15361 publication-title: Chem. Commun. – volume: 411 start-page: 539 year: 2001 end-page: 541 publication-title: Nature – volume: 136 start-page: 6056 year: 2014 end-page: 6068 publication-title: J. Am. Chem. Soc. – volume: 73 start-page: 1091 year: 2015 end-page: 1113 publication-title: Acta Chim. Sinica – volume: 47 start-page: 11035 year: 2011 end-page: 11037 publication-title: Chem. Commun. – volume: 133 start-page: 12569 year: 2011 end-page: 12575 publication-title: J. Am. Chem. Soc. – volume: 22 start-page: 7371 year: 2016 end-page: 7375 publication-title: Chem. Eur. J. – year: 2017 publication-title: Coord. Chem. Rev. – volume: 5 start-page: 10061 year: 2017 end-page: 10067 publication-title: J. Mater. Chem. C – volume: 42 start-page: 143 year: 2013 end-page: 155 publication-title: Chem. Soc. Rev. – volume: 138 start-page: 5441 year: 2016 end-page: 5450 publication-title: J. Am. Chem. Soc. – volume: 9 start-page: 449 year: 1971 end-page: 462 publication-title: Isr. J. Chem. – volume: 29 start-page: 1604005 year: 2017 publication-title: Adv. Mater. – volume: 6 start-page: 779 year: 2014 end-page: 784 publication-title: Nat. Chem. – volume: 7 start-page: 451 year: 2016 end-page: 456 publication-title: Chem. Sci. – volume: 9 start-page: 552 year: 2017 end-page: 557 publication-title: Nat. Chem. – volume: 44 117 start-page: 1072 1096 year: 2005 2005 end-page: 1075 1099 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 37 start-page: 5575 year: 1998 end-page: 5582 publication-title: Inorg. Chem. – volume: 116 start-page: 9914 year: 2016 end-page: 9993 publication-title: Chem. Rev. – volume: 49 start-page: 4424 year: 1968 end-page: 4442 publication-title: J. Chem. Phys. – volume: 113 start-page: 5110 year: 2013 end-page: 5148 publication-title: Chem. Rev. – volume: 30 start-page: 248 year: 2001 end-page: 263 publication-title: Chem. Soc. Rev. – volume: 52 125 start-page: 655 683 year: 2013 2013 end-page: 659 687 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 2 start-page: 558 year: 2015 end-page: 566 publication-title: Inorg. Chem. Front. – volume: 56 129 start-page: 13416 13601 year: 2017 2017 end-page: 13420 13605 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 11 start-page: 533 year: 1972 end-page: 548 publication-title: Appl. Opt. – volume: 6 start-page: 7954 year: 2015 publication-title: Nat. Commun. – volume: 24 start-page: 751 year: 1995 end-page: 752 publication-title: Chem. Lett. – volume: 44 start-page: 5996 year: 2015 end-page: 6002 publication-title: Dalton Trans. – volume: 56 129 start-page: 11445 11603 year: 2017 2017 end-page: 11449 11607 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 21 start-page: 309 year: 2011 end-page: 331 publication-title: Mendeleev Commun. – volume: 548 start-page: 439 year: 2017 end-page: 442 publication-title: Nature – volume: 54 127 start-page: 8704 8828 year: 2015 2015 end-page: 8707 8831 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 39 start-page: 189 year: 2010 end-page: 227 publication-title: Chem. Soc. Rev. – ident: e_1_2_2_21_2 doi: 10.1021/ja300538s – ident: e_1_2_2_35_2 doi: 10.1039/C5CC07073B – ident: e_1_2_2_38_2 doi: 10.6023/A15060376 – ident: e_1_2_2_10_2 doi: 10.1002/anie.201205376 – ident: e_1_2_2_9_3 doi: 10.1002/ange.200461946 – ident: e_1_2_2_32_1 – ident: e_1_2_2_57_2 doi: 10.1016/S0010-8545(00)82068-8 – ident: e_1_2_2_33_2 doi: 10.1039/C8CC00220G – ident: e_1_2_2_74_2 doi: 10.1002/anie.201706391 – ident: e_1_2_2_20_2 doi: 10.1038/nchem.2707 – ident: e_1_2_2_28_2 doi: 10.1002/anie.201410523 – ident: e_1_2_2_41_2 doi: 10.1021/jacs.6b02638 – ident: e_1_2_2_25_2 doi: 10.1016/j.mencom.2011.11.005 – ident: e_1_2_2_62_1 – year: 2017 ident: e_1_2_2_31_2 publication-title: Coord. Chem. Rev. – ident: e_1_2_2_29_2 doi: 10.1021/acs.accounts.5b00296 – ident: e_1_2_2_39_2 doi: 10.1038/nature23447 – ident: e_1_2_2_45_1 doi: 10.1021/ic9804925 – ident: e_1_2_2_66_2 doi: 10.1039/B905604C – ident: e_1_2_2_15_1 – ident: e_1_2_2_68_1 – ident: e_1_2_2_43_2 doi: 10.1038/nchem.2007 – ident: e_1_2_2_44_2 doi: 10.1039/C5SC03201F – ident: e_1_2_2_70_2 doi: 10.1002/chem.201300299 – ident: e_1_2_2_7_2 doi: 10.1002/adma.201604005 – ident: e_1_2_2_13_2 doi: 10.1364/AO.11.000533 – ident: e_1_2_2_23_2 doi: 10.1002/adfm.200304352 – ident: e_1_2_2_36_1 – ident: e_1_2_2_6_2 doi: 10.1039/c2cs35271k – ident: e_1_2_2_69_2 doi: 10.1002/chem.201601244 – ident: e_1_2_2_40_3 doi: 10.1002/ange.201705426 – ident: e_1_2_2_60_2 doi: 10.1039/C4QI00242C – ident: e_1_2_2_24_3 doi: 10.1002/ange.19971092415 – ident: e_1_2_2_22_1 – ident: e_1_2_2_46_1 doi: 10.1039/c0ce00739k – ident: e_1_2_2_28_3 doi: 10.1002/ange.201410523 – ident: e_1_2_2_47_1 doi: 10.1021/acs.joc.6b00134 – ident: e_1_2_2_55_2 doi: 10.1038/35079036 – ident: e_1_2_2_11_3 doi: 10.1002/ange.201503902 – ident: e_1_2_2_73_2 doi: 10.1063/1.1750906 – ident: e_1_2_2_24_2 doi: 10.1002/anie.199727791 – ident: e_1_2_2_34_2 doi: 10.1039/c0dt00979b – ident: e_1_2_2_71_2 doi: 10.1002/ange.200390067 – ident: e_1_2_2_49_1 – ident: e_1_2_2_40_2 doi: 10.1002/anie.201705426 – ident: e_1_2_2_52_1 doi: 10.1039/b006013p – ident: e_1_2_2_1_1 – ident: e_1_2_2_48_1 doi: 10.1246/cl.1995.751 – ident: e_1_2_2_12_1 – ident: e_1_2_2_50_2 doi: 10.1086/172610 – ident: e_1_2_2_51_2 doi: 10.1021/ja404351p – ident: e_1_2_2_2_2 doi: 10.1002/ijch.197100066 – ident: e_1_2_2_27_1 – ident: e_1_2_2_63_2 doi: 10.1039/C6CC01993E – ident: e_1_2_2_61_2 doi: 10.1039/C5DT03897A – ident: e_1_2_2_65_1 – ident: e_1_2_2_17_3 doi: 10.1002/ange.201511444 – ident: e_1_2_2_42_1 – ident: e_1_2_2_58_2 doi: 10.1063/1.1669893 – ident: e_1_2_2_11_2 doi: 10.1002/anie.201503902 – ident: e_1_2_2_67_2 doi: 10.1016/j.ccr.2013.10.023 – ident: e_1_2_2_18_1 – ident: e_1_2_2_54_2 doi: 10.1038/35079225 – ident: e_1_2_2_75_1 doi: 10.1021/ja501569t – ident: e_1_2_2_10_3 doi: 10.1002/ange.201205376 – ident: e_1_2_2_56_1 – ident: e_1_2_2_53_1 – ident: e_1_2_2_9_2 doi: 10.1002/anie.200461946 – ident: e_1_2_2_30_2 doi: 10.1039/C4DT03093A – ident: e_1_2_2_74_3 doi: 10.1002/ange.201706391 – ident: e_1_2_2_72_1 – ident: e_1_2_2_19_2 doi: 10.1038/ncomms8954 – ident: e_1_2_2_59_1 – ident: e_1_2_2_8_1 – ident: e_1_2_2_37_2 doi: 10.1021/cr400018q – ident: e_1_2_2_4_2 doi: 10.1021/acs.chemrev.6b00040 – ident: e_1_2_2_5_1 – ident: e_1_2_2_64_2 doi: 10.1039/C7TC03229C – ident: e_1_2_2_71_1 doi: 10.1002/anie.200390099 – ident: e_1_2_2_3_2 doi: 10.1021/cr00017a008 – ident: e_1_2_2_14_2 doi: 10.1021/acsami.6b00704 – ident: e_1_2_2_17_2 doi: 10.1002/anie.201511444 – ident: e_1_2_2_16_2 doi: 10.1021/ja201925p – ident: e_1_2_2_26_2 doi: 10.1039/c1cc15087a
SSID	ssj0028806
Score	2.5861566
Snippet	In search of magneto‐optic materials, the mononuclear compounds LnIII(depma)(NO3)3(hmpa)2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4]... In search of magneto‐optic materials, the mononuclear compounds Ln III (depma)(NO 3 ) 3 (hmpa) 2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo... In search of magneto-optic materials, the mononuclear compounds Ln (depma)(NO ) (hmpa) (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4]...
SourceID	proquest pubmed crossref wiley
SourceType	Aggregation Database Index Database Enrichment Source Publisher
StartPage	8577
SubjectTerms	Anthracene Clean energy Cycloaddition Dimerization dysprosium Dysprosium compounds Emission Emissions Gadolinium Magnetic properties Molecular chains Optical materials Phosphonates photocycloaddition single-molecule magnets Smart materials Switches white light
Title	Reversible SC‐SC Transformation involving [4+4] Cycloaddition of Anthracene: A Single‐Ion to Single‐Molecule Magnet and Yellow‐Green to Blue‐White Emission
URI	https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201804102 https://www.ncbi.nlm.nih.gov/pubmed/29757484 https://www.proquest.com/docview/2064165074
Volume	57
WOSCitedRecordID	wos000437668700037&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
journalDatabaseRights	– providerCode: PRVWIB databaseName: Wiley Online Library - Journals customDbUrl: eissn: 1521-3773 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0028806 issn: 1433-7851 databaseCode: DRFUL dateStart: 19980101 isFulltext: true titleUrlDefault: https://onlinelibrary.wiley.com providerName: Wiley-Blackwell
link	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1fa9RAEF_kKuiLtv49bcs-CD5IaLKbpIlvZ3pHC-0hvRYqImH_zEohJNK7Kr75EfwSfjE_iTObXNpDSkHfsuxkCbszs7_dzPyGsVc2scRyRsjNZUFsHflB7QKjDOQqTEwInsT1cHc6zc7O8vfXsvhbfoj-wo0sw_trMnCl5ztXpKGUgU2hWUSgQ2ySawKVNx6wtb3jyelhf-hC_WwzjKQMqBD9krgxFDurI6xuTH-hzVXw6nefycP__-519qBDnnzUqsoGuwP1I3avWBZ8e8x-HYOP0dAV8Fnx-8fPWcFPruHapubnNXozuoLgH-M38SdefDdVQyFJvrdx3NddwAWo4S0f8RlKVoAjHWDvorlqH7VFeYEfqc81LLiqLf9Av4G-YacPBSLxd9UlCfsafnyMn0k3e0_Y6WR8UuwHXRWHwEiE7kFkMpuGGnSoNIjU4vnQxsKJPELo6SSYCFwERkZOWFBCxUYpm-aJdaGSGn3EUzaomxqeM45wI0tNtmtyiadKDXhUS0Nj4yQRLtRSDlmwXMLSdBTnVGmjKltyZlHS5Jf95A_Z617-S0vucaPk5lIjys7I59ibIpxFQB0P2bNWS_phKGGZaFqHTHhluGX8cjQ9GPetF__y0kt2n559KHG-yQaLi0vYYnfN18X5_GK7M4s_x8cS7w
linkProvider	Wiley-Blackwell
linkToHtml	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1fa9RAEF_kKtQXa_1Tr9a6D4IPEprsJmni2xnv6OHdIb0rVETCZndWCiGR9qr45kfwS_jF-kk6s8mlHiKC-LjZyRB2Z2d_O5n9DWPPTWSI5YyQm0280Fjyg4X1tNKQKj_SPjgS18nhbJacnqbv2mxCugvT8EN0ATdaGc5f0wKngPTBDWsoXcGm3Cxi0CE6yY0QbSnqsY03x6OTSXfqQgNtrhhJ6VEl-hVzoy8O1jWs70y_wc119Oq2n9HWf_jwe-xuiz35oDGWbXYLqvtsM1uVfHvAfh6Dy9IoSuDz7Or7j3nGF78g27riZxX6MwpC8A_hy_Ajz77psqakJNdbW-4qL-AUVPCKD_gcJUtATWPsXdY37WlTlhf4VH2qYMlVZfh7-hH0FTtdMhCJvy4vSdhV8eND_EyK7T1kJ6PhIjvy2joOnpYI3r1AJyb2Cyh8VYCIDZ4QTSisSAMEn1aCDsAGoGVghQElVKiVMnEaGesrWaCXeMR6VV3BY8YRcCSxTg51KvFcWQAe1mJfmzCKhPULKfvMW81hrluSc6q1UeYNPbPIafDzbvD77EUn_7mh9_ij5N7KJPJ2mV9gb4yAFiF12Gc7jZl0aujKMhG19plw1vAX_flgNh52rd1_eekZ2zxaTCf5ZDx7-4TdoecusTjdY73l-SU8Zbf1l-XZxfl-u0auAS7TFt8
linkToPdf	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1fa9RAEF9KW7Qvtf6pPW11HwQfJDTZTdLEtzO9w8PrUXotVETCZndWCiEp7bWlb34Ev4RfzE_izCaXeogI4uNmJ0vYnZn97WbmN4y9MpEhljNCbjbxQmPJDxbW00pDqvxI--BIXMd7k0lyepoettGElAvT8EN0F25kGc5fk4HDubG7d6yhlIJNsVnEoEN0kithlMZomyv7R8OTcXfqQgVtUoyk9KgS_Zy50Re7iyMs7ky_wc1F9Oq2n-GD__DhG2y9xZ683yjLQ7YE1SN2P5uXfHvMvh-Bi9IoSuDT7MfXb9OMH_-CbOuKn1Xoz-gSgn8K34SfeXary5qCklxvbbmrvIBLUMFb3udTlCwBRxph76y-ax80ZXmBH6gvFcy4qgz_SD-CbrDTBQOR-LvyioRdFT8-wM-ku70n7GQ4OM7ee20dB09LBO9eoBMT-wUUvipAxAZPiCYUVqQBgk8rQQdgA9AysMKAEirUSpk4jYz1lSzQS2yy5aquYItxBBxJrJM9nUo8VxaAh7XY1yaMImH9Qsoe8-ZrmOuW5JxqbZR5Q88scpr8vJv8HnvdyZ839B5_lNyeq0Temvkl9sYIaBFShz32tFGTbhhKWSai1h4TThv-Mn7en4wGXevZv7z0kt073B_m49Hkw3O2Ro9dXHG6zZZnF1eww1b19ezs8uJFayI_AZm8Flo
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Reversible+SC%E2%80%90SC+Transformation+involving+%5B4%2B4%5D+Cycloaddition+of+Anthracene%3A+A+Single%E2%80%90Ion+to+Single%E2%80%90Molecule+Magnet+and+Yellow%E2%80%90Green+to+Blue%E2%80%90White+Emission&rft.jtitle=Angewandte+Chemie+International+Edition&rft.au=Huang%2C+Xin%E2%80%90Da&rft.au=Xu%2C+Yan&rft.au=Fan%2C+Kun&rft.au=Bao%2C+Song%E2%80%90Song&rft.date=2018-07-09&rft.issn=1433-7851&rft.eissn=1521-3773&rft.volume=57&rft.issue=28&rft.spage=8577&rft.epage=8581&rft_id=info:doi/10.1002%2Fanie.201804102&rft.externalDBID=10.1002%252Fanie.201804102&rft.externalDocID=ANIE201804102
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1433-7851&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1433-7851&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1433-7851&client=summon