Sixty years of electrochemical optical spectroscopy: a retrospective
Sixty years ago, Reddy, Devanatan, and Bockris performed the first electrochemical ellipsometry experiment, which ushered in a new era in the study of electrochemistry, using optical spectroscopy. After six decades of development, electrochemical optical spectroscopy, particularly electrochemical vi...
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| Vydané v: | Chemical Society reviews Ročník 53; číslo 7; s. 3579 |
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| Hlavní autori: | , |
| Médium: | Journal Article |
| Jazyk: | English |
| Vydavateľské údaje: |
England
02.04.2024
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| ISSN: | 1460-4744, 1460-4744 |
| On-line prístup: | Zistit podrobnosti o prístupe |
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| Shrnutí: | Sixty years ago, Reddy, Devanatan, and Bockris performed the first
electrochemical ellipsometry experiment, which ushered in a new era in the study of electrochemistry, using optical spectroscopy. After six decades of development, electrochemical optical spectroscopy, particularly electrochemical vibrational spectroscopy, has advanced from a phase of immaturity with few methods and limited applications to a phase of maturity with excellent substrate generality and significantly improved resolutions. Here, we divide the development of electrochemical optical spectroscopy into four phases, focusing on the proof-of-concept of different electrochemical optical spectroscopy studies, the emergence of plasmonic enhancement-based electrochemical optical spectroscopic (in particular vibrational spectroscopic) methods, the realization of electrochemical vibrational spectroscopy on well-defined surfaces, and the efforts to achieve
spectroelectrochemical applications. Finally, we discuss the future development trend of electrochemical optical spectroscopy, as well as examples of new methodology and research paradigms for
spectroelectrochemistry. |
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| Bibliografia: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 ObjectType-Review-3 content type line 23 |
| ISSN: | 1460-4744 1460-4744 |
| DOI: | 10.1039/d3cs00734k |