Solid‐state microcellular high temperature vulcanized (HTV) silicone rubber foam with carbon dioxide
ABSTRACT A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO2 as a physical blowing agent. Rheological properties, gas diffusive behavior, and foaming parameters of silicone rubber were investigated. The results show that saturation pressure has a...
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| Published in: | Journal of applied polymer science Vol. 134; no. 20; pp. np - n/a |
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| Main Authors: | , , , , , , , |
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20.05.2017
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| ISSN: | 0021-8995, 1097-4628 |
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| Abstract | ABSTRACT
A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO2 as a physical blowing agent. Rheological properties, gas diffusive behavior, and foaming parameters of silicone rubber were investigated. The results show that saturation pressure has a significant effect on the diffusivity of CO2 in HTV silicone rubber matrix. The gas concentration and diffusivity increase from 2.45 wt % to 3.24 wt %, and from 1.62 × 10−5 cm2/s to 7.83 × 10−5 cm2/s as the saturation pressure increases from 2 MPa to 5 MPa, respectively. The value of the gas diffusivity in HTV silicone rubber is almost 1000 times higher than that of the gas diffusivity in polyetherimide (PEI) matrix. Additionally, microcellular HTV silicone rubber foams with the smallest cell diameter of 9.8 μm and cell density exceeding 108 cells/cm3 are achieved. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44807. |
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| AbstractList | A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO2 as a physical blowing agent. Rheological properties, gas diffusive behavior, and foaming parameters of silicone rubber were investigated. The results show that saturation pressure has a significant effect on the diffusivity of CO2 in HTV silicone rubber matrix. The gas concentration and diffusivity increase from 2.45 wt % to 3.24 wt %, and from 1.62 × 10-5 cm2/s to 7.83 × 10-5 cm2/s as the saturation pressure increases from 2 MPa to 5 MPa, respectively. The value of the gas diffusivity in HTV silicone rubber is almost 1000 times higher than that of the gas diffusivity in polyetherimide (PEI) matrix. Additionally, microcellular HTV silicone rubber foams with the smallest cell diameter of 9.8 µm and cell density exceeding 108 cells/cm3 are achieved. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44807. A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO sub(2) as a physical blowing agent. Rheological properties, gas diffusive behavior, and foaming parameters of silicone rubber were investigated. The results show that saturation pressure has a significant effect on the diffusivity of CO sub(2) in HTV silicone rubber matrix. The gas concentration and diffusivity increase from 2.45 wt % to 3.24 wt %, and from 1.62 10 super(-5) cm super(2)/s to 7.83 10 super(-5) cm super(2)/s as the saturation pressure increases from 2 MPa to 5 MPa, respectively. The value of the gas diffusivity in HTV silicone rubber is almost 1000 times higher than that of the gas diffusivity in polyetherimide (PEI) matrix. Additionally, microcellular HTV silicone rubber foams with the smallest cell diameter of 9.8 mu m and cell density exceeding 10 super(8) cells/cm super(3) are achieved. J. Appl. Polym. Sci. 2017, 134, 44807. A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO 2 as a physical blowing agent. Rheological properties, gas diffusive behavior, and foaming parameters of silicone rubber were investigated. The results show that saturation pressure has a significant effect on the diffusivity of CO 2 in HTV silicone rubber matrix. The gas concentration and diffusivity increase from 2.45 wt % to 3.24 wt %, and from 1.62 × 10 −5 cm 2 /s to 7.83 × 10 −5 cm 2 /s as the saturation pressure increases from 2 MPa to 5 MPa, respectively. The value of the gas diffusivity in HTV silicone rubber is almost 1000 times higher than that of the gas diffusivity in polyetherimide (PEI) matrix. Additionally, microcellular HTV silicone rubber foams with the smallest cell diameter of 9.8 μm and cell density exceeding 10 8 cells/cm 3 are achieved. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 44807. ABSTRACT A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO2 as a physical blowing agent. Rheological properties, gas diffusive behavior, and foaming parameters of silicone rubber were investigated. The results show that saturation pressure has a significant effect on the diffusivity of CO2 in HTV silicone rubber matrix. The gas concentration and diffusivity increase from 2.45 wt % to 3.24 wt %, and from 1.62 × 10−5 cm2/s to 7.83 × 10−5 cm2/s as the saturation pressure increases from 2 MPa to 5 MPa, respectively. The value of the gas diffusivity in HTV silicone rubber is almost 1000 times higher than that of the gas diffusivity in polyetherimide (PEI) matrix. Additionally, microcellular HTV silicone rubber foams with the smallest cell diameter of 9.8 μm and cell density exceeding 108 cells/cm3 are achieved. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44807. |
| Author | Song, Lixian Lu, Ai Zhang, Fengshun Yang, Qian Lei, Yajie Luo, Shikai Liu, Tao Yu, Haitao |
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| Snippet | ABSTRACT
A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO2 as a physical blowing agent. Rheological... A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO 2 as a physical blowing agent. Rheological properties,... A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO2 as a physical blowing agent. Rheological properties,... A series of microcellular high temperature vulcanized (HTV) silicone rubber foams were prepared using CO sub(2) as a physical blowing agent. Rheological... |
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| SubjectTerms | Blowing agents Carbon dioxide Diffusivity Foaming Foams high temperature vulcanized silicone rubber Materials science microcellular foam Polyetherimides Polymers Saturation Silicone rubber |
| Title | Solid‐state microcellular high temperature vulcanized (HTV) silicone rubber foam with carbon dioxide |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fapp.44807 https://www.proquest.com/docview/1869826788 https://www.proquest.com/docview/1884102886 |
| Volume | 134 |
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