Intramolecular Charge Transfer in Ruthenium Complexes [Ru(acac)2(ciq)] with Ambidentate Camphoriminoquinone (ciq) Ligands

Reaction of [Ru(acac)2(MeCN)2], acac−=acetylacetonate, with N‐phenylcamphoriminoquinone (pciq) or the new N‐(2‐thiomethylphenyl)‐camphoriminoquinone (tciq) produces complexes [Ru(acac)2(pciq)] and [Ru(acac)2(tciq)] with N,O or N,S coordination and E or Z configuration at the C=N bond, respectively....

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Bibliographic Details

Published in:	Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 647; no. 5; pp. 525 - 533
Main Authors:	Filippou, Vasileios, Blickle, Svenja, Bubrin, Martina, Kaim, Wolfgang
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 11.03.2021
Subjects:	Camphor ligands Charge transfer Coordination ambivalence Ligands Oxidation Ruthenium complexes Ruthenium compounds Spectroelectrochemistry Structure Valence
ISSN:	0044-2313, 1521-3749
Online Access:	Get full text
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