Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids

Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) Jg. 48; H. 99; S. 12088
Hauptverfasser:	Kurtikyan, Tigran S, Hayrapetyan, Vardan A, Martirosyan, Garik G, Ghazaryan, Robert K, Iretskii, Alexei V, Zhao, Hailiang, Pierloot, Kristine, Ford, Peter C
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	England 25.12.2012
Schlagworte:	Coordination Complexes - chemistry Isomerism Manganese - chemistry Nitric Oxide - chemistry Spectroscopy, Fourier Transform Infrared Temperature
ISSN:	1364-548X, 1364-548X
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Beschreibung
Zusammenfassung:	Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.
Bibliographie:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1364-548X 1364-548X
DOI:	10.1039/c2cc37337h